Hydrophobic organic and inorganic acrylate polymer emulsion with high silicon content and preparation method and application thereof
A polymer emulsion and acrylate technology, which is applied in the field of hydrophobic organic-inorganic high-silicon-content acrylate polymer emulsion and its preparation, can solve the problems of easy agglomeration, coating film hardness and insufficient hydrophobicity, etc., and achieve excellent scrub resistance , good storage stability, good appearance and stability
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Embodiment 1
[0039] (1) In parts by mass, add 2 parts of methanol, 3 parts of isopropanol, and 1 part of tridecafluorooctyltrimethoxysilane to 30 parts of silica sol, stir and react at 25°C for 6 hours, and obtain fluorine-containing modification Sexual silica sol;
[0040] (2) Mix 15 parts of methyl methacrylate and 15 parts of butyl acrylate to make monomer I, take 10% of mixed monomer I and 2 parts of 2-hydroxyethyl acrylate to make monomer II;
[0041] (3) Mix 60% of 40 parts of water, 50% of 0.1 part of octylphenol polyoxyethylene ether OP-10 and 0.1 part of sodium dodecylbenzenesulfonate (LAS), and 50% of 0.1 part of potassium persulfate Add the fluorine-containing modified silica sol reaction kettle obtained in step (1), stir for 15 minutes and then raise the temperature to 75 ° C, then slowly add the monomer I into the reaction kettle dropwise, drop it in 2 hours, and keep it warm for 15 minutes after the addition is completed. Minutes to get the emulsion;
[0042] (4) Continuous...
Embodiment 2
[0045] (1) In terms of parts by mass, add 4 parts of ethanol, 4 parts of isobutanol, and 2.5 parts of heptadecylfluorodecyltrimethoxysilane to 40 parts of silica sol, and stir and react at 30°C for 12 hours to obtain fluorine-containing modification Sexual silica sol;
[0046] (2) Mix 15 parts of ethyl methacrylate, 5 parts of butyl methacrylate and 25 parts of methyl acrylate to make monomer I, take 15% of mixed monomer I and 3 parts of 3-hydroxypropyl acrylate Mixed to make monomer II;
[0047] (3) 65% of 50 parts of water, 0.4 parts of octylphenol polyoxyethylene ether OP-15 and 0.2 parts of disodium dodecyl diphenyl ether sulfonate (DSB) mixture of 60%, 0.3 parts of sodium persulfate Add 60% of the fluorine-containing modified silica sol reaction kettle obtained in step (1), stir for 20 minutes and then raise the temperature to 77 °C, then slowly add monomer I into the reaction kettle dropwise, and drop it in 2.5 hours. After being incubated for 20 minutes, the emulsion ...
Embodiment 3
[0051] (1) In terms of parts by mass, add 6 parts of methanol, 6 parts of tert-butanol, and 3.5 parts of tridecafluorooctyltriethoxysilane to 50 parts of silica sol, and stir and react at 40°C for 18 hours to obtain fluorine-containing Modified silica sol;
[0052] (2) Mix 25 parts of propyl methacrylate with 15 parts of ethyl acrylate and 15 parts of propyl acrylate to make monomer I, take 20% of mixed monomer I and mix it with 4 parts of 5-hydroxypentyl acrylate to make into monomer Ⅱ;
[0053] (3) Add 70% of 65 parts of water, 65% of 0.8 parts of octylphenol polyoxyethylene ether OP-30 and 0.4 parts of sodium dodecyl sulfate (SDS) mixture, and 65% of 0.6 parts of ammonium persulfate to the step (1) In the obtained fluorine-containing modified silica sol reaction kettle, after stirring for 15 minutes, the temperature was raised to 78 ° C, and then the monomer I was slowly added dropwise to the reaction kettle, and the drop was completed in 3 hours, and kept for 25 minutes a...
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