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Thermal treatment method suitable for magnetism alloy with age-hardening property

A heat treatment method and aging hardening technology, applied in the field of metal heat treatment, can solve the problems of difficult to observe aging strengthening, reduction of solute supersaturation, reduction of volume fraction of strengthening phase, etc. Effect of Volume Precipitation Fraction

Inactive Publication Date: 2013-01-16
YANSHAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, this traditional T6 heat treatment method has the following disadvantages: 1. Because the atomic radius of alloying elements is too large and the diffusion rate is slow, the temperature is generally set above 180°C during aging, and when it is lower than 180°C due to time If it is too long, it is difficult to observe the aging strengthening phenomenon; 2. Due to the high aging temperature, the supersaturation degree of the solute is reduced, so the volume fraction of the precipitation strengthening phase is reduced, and the strengthening effect is weakened; 3. Since magnesium has a hexagonal structure, so , most of the coherent or semi-coherent precipitates in the aging process are acicular phases or flakes, and it is difficult to obtain spherical strengthening phases, which significantly reduces the plasticity of the alloy; 4. The temperature of the traditional aging process is too high and the time is too long , time-consuming and energy-consuming
However, this heat treatment method has a certain solid solution temperature, a certain solid solution alloying element, and the aging temperature is basically unchanged, and the volume fraction of the strengthening phase that can be precipitated is constant, so the strengthening effect is limited.

Method used

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  • Thermal treatment method suitable for magnetism alloy with age-hardening property
  • Thermal treatment method suitable for magnetism alloy with age-hardening property
  • Thermal treatment method suitable for magnetism alloy with age-hardening property

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] Take Mg-5Zn-0.6Zr-0.2Mn (wt.%, mass percentage) alloy, solid solution at 0.85Tm (520 ℃) ​​in an isobaric external field of 0.5GPa, and the solution time is 2 hours. Remove the pressure after treatment. It is directly cooled with hot water at 60℃, and then aged at room temperature under an external stress of 30MPa and a pulsed electric field of 1kV / cm. When the aging time is 50,000 pulses and the pulse interval is 1 second, the peak hardness can be reached and the highest mechanical performance can be obtained. The Vickers hardness reaches 125 HV (load 50 g, load time 15s).

[0023] The above alloy is treated with traditional T6 (Solid Solution and Aging). The solution temperature is 520℃, the solution time is 8 hours, the aging temperature is 200 ℃, the aging time is 24 hours, and the maximum hardness after treatment is 95 HV (Load 50 g, load time 15s).

[0024] Such as figure 1 As shown, the hardness of the Mg-5Zn-0.6Zr-0.2Mn alloy treated with the low-temperature pulse in...

Embodiment 2

[0026] Take Mg-10Sn-0.6Zr-0.2Mn (wt.%, mass percentage) alloy, and solid solution at 0.7Tm (310 ℃) under an isobaric field of 1GPa. The solution time is 4 hours. After treatment, release the pressure and directly Cooled with hot water at 80℃, then aged at room temperature under an external stress of 50MPa and a pulsed electric field of 10 kV / cm. When the aging time is 10,000 pulses and the pulse interval is 1 second, the peak hardness can be reached and the highest mechanical performance can be obtained. The Vickers hardness is 93HV (load 50g, bearing time 15s).

[0027] The above alloys are treated with traditional T6 (Solid Solution and Aging). The solution temperature is 310℃, the solution time is 8 hours, the aging temperature is 180 ℃, the aging time is 48 hours, and the maximum hardness is 82 HV (load 50 g, bearing time 15s).

[0028] Such as figure 2 As shown, there are a large number of square particles in the Mg-10Sn-0.6Zr-0.2Mn alloy after T6 solution treatment. Due to...

Embodiment 3

[0030] Take Mg-16Pb-2Sm-2Nd-0.6Zr-0.2Mn (wt.%, mass percentage) alloy and solid solution at 0.8Tm (525 ℃) under an equal pressure field of 0.75GPa. The solution time is 3 hours. After treatment Relieve the pressure, directly cool with 70℃ hot water, and then aging at room temperature under an external stress of 40MPa and a pulsed electric field of 8 kV / cm. When the aging time is 30,000 pulses and the pulse interval is 1 second, the peak hardness can be reached. The highest mechanical performance, the highest Vickers hardness is 118HV (load 50 g, load time 15s).

[0031] The above alloy is treated with traditional T6 (Solid Solution and Aging), the solution temperature is 525℃, the solution time is 24 hours, the aging temperature is 210 ℃, the aging time is 36 hours, and the maximum hardness is 96 HV (load 50 g, bearing time 15s).

[0032] Such as image 3 As shown, compared with the traditional T6 treatment method, the precipitated phase composition of the Mg-16Pb-2Sm-2Nd-0.6Zr-0....

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Abstract

The invention discloses a thermal treatment method suitable for magnetism alloy with an age-hardening property. The magnetism alloy with the age-hardening property is Mg-xM-0.6Zr-0.2Mn based alloy, M contains Sn, Pb, Zn and rare earth, and x ranges from 5 to 20 wt%. When multiple kinds of rare earth elements are included, the contents of all rare earth elements are same. Solid solution is carried out on the magnetism alloy under an isobaric outer field of 0.5 to 1GPa and 0.7 to 0.85 Tm (Tm: the melting point of the alloy), and the time of solid solution ranges from 2 to 4 hours. Pressure is removed after the treatment; the hot water ranges from 60 to 80 DEG C is directly used for cooling; under the external stress of 30 to 50 MPa and the pulse electric field of 1 to 10 Kv / cm, room temperature aging is carried out for 10 to 50 thousands of pulses per hour, and the pulse interval is 1 second; and the peak hardness can be acquired. The thermal treatment method suitable for the magnetism alloy with the age-hardening property has the advantages of simplicity in operation technology, short aging time, low aging temperature, low energy consumption and the like.

Description

technical field [0001] The invention relates to the field of metal heat treatment, in particular to a magnesium alloy heat treatment method. Background technique [0002] Solid solution strengthening, fine grain strengthening and aging precipitation strengthening are the three main strengthening methods of magnesium alloys. Among the three main strengthening methods, the effect of aging precipitation strengthening is particularly significant. The final mechanical properties of magnesium alloys are closely related to the heat treatment process of the alloys. In recent years, different types of heat treatment processes have been developed for different types of magnesium alloys. Such as graded solid solution, double aging, vibration heat treatment and strain heat treatment, etc. have appeared one after another. To sum up, the purpose of all the above heat treatment processes is to increase the volume fraction of the aging precipitation strengthening phase and optimize the m...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22F3/00C22F1/06
Inventor 彭秋明田永君
Owner YANSHAN UNIV
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