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Moisture absorption product with high salt resistance and high water absorbency

A technology with high water absorption and salt tolerance, applied in applications, absorbent pads, medical science, etc., can solve problems such as dryness reduction, urine leakage, and impact on application performance, so as to reduce usage, improve salt tolerance, and improve The effect of social and economic benefits

Active Publication Date: 2012-12-05
宜兴丹森科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, although polyacrylic acid (salt) superabsorbent resins have the advantages of fast water absorption, high water absorption ratio, and good heat resistance compared with other synthetic superabsorbent resins, polyacrylic acid (salt) superabsorbent resins are highly absorbent. Molecular electrolyte, poor salt resistance, seriously affects its application performance
[0010] However, the composition of human body fluids is complex. For example, human urine is mainly composed of urea and various inorganic salt ions, such as Cl - 、Na + 、K + , SO 4 2- Wait
Since the superabsorbent resin is a polymer electrolyte, various ionic components will have the same ion effect on its water absorption process. Therefore, these components have a serious impact on the water absorption capacity of the superabsorbent resin, which is manifested as the liquid absorption of the superabsorbent resin. The magnification is greatly reduced, resulting in a decrease in the absorption of urine by the absorbent core of the sanitary product, which affects the performance of the sanitary product. For example, when the sanitary product is worn by a child, urine leakage is likely to occur. At the same time, the surface of the sanitary product is rewet. The amount increases, the dryness decreases, and it is easy to cause rashes on the skin of children, etc.

Method used

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  • Moisture absorption product with high salt resistance and high water absorbency
  • Moisture absorption product with high salt resistance and high water absorbency
  • Moisture absorption product with high salt resistance and high water absorbency

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0050] At present, the superabsorbent resin (SAP) used in the sanitation industry mainly includes IM-930 and IM-701H type SAP produced by Sanya Company, AB60SX type SAP produced by Sumitomo Company, etc. The IM produced by Sanya Company is used in the embodiment of the present invention. -930 type SAP; and the fluff pulp fiber mainly has the NB480 type fluff pulp produced by Huihao Company, and the NB480 type fluff pulp produced by Huihao Company is used in the embodiment of the present invention.

[0051] Adopt strong-acid styrene type cation-exchange resin in the example of the present invention, add 100 kilograms of polyether triols by 10 kilograms of stearic acid polyethylene glycol esters, 25 kilograms of strong-acidity cation-exchange resins and stir and mix, next, add 1.0 successively Kg of silicone foam stabilizer (commercially available product silicone oil), 0.3 kg of bis-β (3-tert-butyl-5-methyl-4-hydroxyphenyl) triethylene glycol propionate (antioxidant), 3.5 kg de...

Embodiment 2

[0055] Adopt weakly basic styrene type cation exchange resin in the example of the present invention, add 100 kilograms of polyether triols and stir and mix by 12 kilograms of glyceryl monostearate and 30 kilograms of weakly basic cation exchange resin, and then, successively Add 1.0 kg of silicone foam stabilizer (commercially available CGY-3), 0.3 kg of triethylene glycol bis-β(3-tert-butyl-5-methyl-4-hydroxyphenyl)propionate (an antioxidant ), 4.5 kg of deionized water, and mix well, again, add 0.25 kg of organotin (dibutyltin dilaurate), 0.20 kg of organic amine (triethanolamine), 10 kg of cyclopentane blowing agent and fully Stirring, the temperature of the raw materials is controlled at 50°C throughout the reaction process, the stirring speed is 1500r / min, and the stirring is uniform for 0.5 hours. Finally, 50 kg of diisocyanate (specifically, diphenylmethane diisocyanate) is added and stirred rapidly for 15 seconds. After continuing to stir evenly Place it in a mold for...

Embodiment 3

[0059] Adopt chelation type ion exchange resin in the example of the present invention, add 100 kilograms of polyether triols and mix by 15 kilograms of polyoxyethylene lauryl ether, 28 kilograms of chelation type ion exchange resins, next, add 1.0 kilograms successively The commercially available silicone foam stabilizer QBH, 0.3 kg of bis-β (3-tert-butyl-5-methyl-4-hydroxyphenyl) triethylene glycol propionate (antioxidant), 4 kg of deionized water, and mix well, again, add 0.25 kg of organotin (dibutyltin dilaurate), 0.20 kg of organic amine (triethanolamine), 12 kg of cyclopentane foaming agent and fully stir, the whole reaction process controls the raw materials The temperature is 50°C, the stirring speed is 1500r / min, stir evenly for 0.5 hours, finally, add 48kg of diisocyanate (specifically 2,4-toluene diisocyanate) and stir rapidly for 15s, continue to stir evenly and place it in the mold for foaming Molding and aging for 3 hours, and cutting into specifications of 400m...

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Abstract

The invention discloses a moisture absorption product with high salt resistance and high water absorbency. The moisture absorption product comprises a liquid-permeable surface layer, a flow guide layer, a liquid-tight bottom layer and an absorption core disposed between the liquid-permeable surface layer and the liquid-tight bottom layer. A hydrophilic polyurethane flexible foam layer with a function of ion exchange is disposed between the liquid-permeable surface layer and the liquid-tight bottom layer. The density of the hydrophilic polyurethane flexible foam layer is 0.01-0.12g / cm<3>, mass percent of ion exchange resin is 0-60%, and ion exchange capacity is 0-6.0mmlo / g. The moisture absorption appliance includes sanitary napkins, infant paper diapers, adult paper diapers or pet pads. The ion exchange resin is one or more of positive ion exchange resin, negative ion exchange resin, chelate ion exchange resin. Accordingly, water absorption capacity of super absorbent resin in the absorption core can be improved greatly, and salt resistance and liquid permeability of the super absorbent resin are also improved.

Description

technical field [0001] The invention relates to a hygroscopic article, in particular to a hygroscopic article containing soft hydrophilic polyurethane foam material with ion exchange function. Background technique [0002] The full name of polyurethane is polyurethane, which is a general term for macromolecular compounds containing repeated carbamate groups (-NHCOO-) in the main chain. It is formed by addition polymerization of organic diisocyanate or polyisocyanate and dihydroxy or polyhydroxy compound. The unit is formed by the reaction of isocyanate group and hydroxyl group. The reaction formula is as follows: —N=C=O + HO — → —NH-COO—. [0003] As a new type of polymer synthetic material, polyurethane flexible foam material is mostly open-cell structure with certain elasticity and softness. Therefore, it has the properties of low density, good elastic recovery, sound absorption, breathability, heat preservation, etc. It is mainly used as cushion materials such as furnit...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): A61F13/15A61F13/53A61L15/26
Inventor 周丕严杭渊洪锡全裴小苏
Owner 宜兴丹森科技有限公司
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