Corrosion-resistant oil-water separation mesh membrane as well as preparation method and applications thereof

An oil-water separation membrane and corrosion-resistant technology, applied in separation methods, filtration separation, liquid separation, etc., can solve the problems of complex oil-water system, unreported, inability to withstand various acids and alkaline solutions, etc., and achieve technological process Simple and easy-to-operate effects

Inactive Publication Date: 2012-10-17
BEIHANG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The Chinese invention patent application with the publication number CN102225273A discloses a method for preparing a superhydrophobic and superoleophilic paper-based separation material. The paper-based separation material is obtained by immersing the filter paper in a silane-modified nanoparticle solution and drying it naturally. This material can resist acid and organic solvent, and can remove the oil floating on the water surface simultaneously, carry out oil-water separation, repeat many times; However, the paper-based separation material prepared by this method is not resistant to various acids (such as concentrated sulfuric acid) and alkaline solutions, Therefore, it cannot meet the various application requirements of the industry.
[0005] The Chinese invention patent with the publication number CN102029079A discloses an oil-water separation membrane with underwater superoleophobic properties and its preparation method and application. Oleophobic properties, and the contact angle of the material to oil droplets under water is greater than 150°, and has the characteristics of low adhesion to oil droplets; however, the material is also not resistant to various acids and alkaline solutions
[0006] Because in the actual oil-water separation process, the oil-water system is usually more complicated, and often contains corrosive strong acid, strong alkali or salt solutions, therefore, there is an urgent need for an oil-water separation membrane resistant to acid, alkali, or salt systems, but until now So far, no oil-water separation omentum with resistance to acid, alkali, or salt system has been reported.

Method used

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  • Corrosion-resistant oil-water separation mesh membrane as well as preparation method and applications thereof
  • Corrosion-resistant oil-water separation mesh membrane as well as preparation method and applications thereof
  • Corrosion-resistant oil-water separation mesh membrane as well as preparation method and applications thereof

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Embodiment 1

[0039] In this example, each mole part is 1 mole.

[0040] The preparation method of the corrosion-resistant oil-water separation omentum of the present embodiment comprises the following steps:

[0041] Step 1: Alternately immerse the 300-mesh metal iron fiber woven net in deionized water and absolute ethanol for ultrasonic cleaning, and dry it at room temperature;

[0042] Step 2: Prepare conductive polymer precursor solution and ultrasonically disperse it into emulsion;

[0043] Wherein, the conductive polymer precursor solution is composed of 1 molar part of 3,4-ethylenedioxythiophene, 1 molar part of sodium p-styrenesulfonate, 2 molar parts of ferric nitrate, 1 molar part of ethanol and 2 The water composition of molar part; Here, 3,4-ethylenedioxythiophene is conductive polymer monomer; Sodium p-styrene sulfonate is dopant; Ferric nitrate is oxidant;

[0044] Step 3: Immerse the metal iron fiber braided net cleaned in step 1 into the emulsion described in step 2. After...

Embodiment 2

[0050] The preparation method of the corrosion-resistant oil-water separation omentum of the present embodiment comprises the following steps:

[0051]Step 1: Alternately immerse the 200-mesh metal copper fiber braided mesh in deionized water and absolute ethanol for ultrasonic cleaning, and dry it at room temperature;

[0052] Step 2: Prepare conductive polymer precursor solution and ultrasonically disperse it into emulsion;

[0053] Wherein, the conductive polymer precursor solution is composed of 10 molar parts of thiophene, 7 molar parts of sodium p-styrenesulfonate, 50 molar parts of ferric chloride, 10 molar parts of ethanol and 20 molar parts of water; Here, thiophene is a conductive polymer monomer; sodium p-styrenesulfonate is a dopant; ferric chloride is an oxidizing agent;

[0054] Step 3: immerse the metal copper fiber braided mesh cleaned in step 1 into the emulsion described in step 2, and after 2 minutes, take it out and stand for 30 hours for polymerization to...

Embodiment 3

[0058] The preparation method of the corrosion-resistant oil-water separation omentum of the present embodiment comprises the following steps:

[0059] Step 1: Alternately immerse the 100-mesh metal stainless steel fiber woven mesh in deionized water and absolute ethanol for ultrasonic cleaning, and dry it at room temperature;

[0060] Step 2: Prepare conductive polymer precursor solution and ultrasonically disperse it into emulsion;

[0061] Wherein, the conductive polymer precursor solution is composed of 4 molar parts of aniline, 2 molar parts of p-styrenesulfonic acid, 28 molar parts of cerium chloride, 6 molar parts of ethanol and 15 molar parts of water; here, Aniline is a conductive polymer monomer; p-styrenesulfonic acid is a dopant; cerium chloride is an oxidant;

[0062] Step 3: Immerse the metal stainless steel fiber braided mesh cleaned in step 1 into the emulsion described in step 2. After 4 minutes, take it out and stand for 28 hours to polymerize to obtain a me...

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Abstract

The invention discloses a corrosion-resistant oil-water separation mesh membrane as well as a preparation method and application thereof. The corrosion-resistant oil-water separation mesh membrane is a fiber braiding mesh coated with conducting polymer aquogel which is one or a mixture of some of polypyrrole, poly thiophene, polyaniline, polyparaphenylene, poly-m-toluidine,poly (1-methylene-2-methyl naphthalene) -N-pyrrole, poly ethylene dioxy thiophene, poly 3-ethyl thiophene, poly 3-hexyl thiophene and poly 2, 5-dimethoxy aniline; and the fiber braiding mesh is one of a metal fiber braiding mesh, an inorganic fiber braiding mesh and an organic fiber braiding mesh. The corrosion-resistant oil-water separation mesh membrane not only can implement the effective separation of different types of water and oil, but also has the favorable characteristics of salt resistance, strong acid resistance and strong alkaline resistance.

Description

technical field [0001] The invention relates to the technical field of oil-water separation, in particular to a corrosion-resistant oil-water separation mesh, a preparation method and application thereof. Background technique [0002] With the rise of petrochemical, petroleum exploration, petroleum transportation, machinery manufacturing and other industries, a large amount of oily wastewater will inevitably be produced. If these oily wastewater is directly discharged, it will not only waste resources, but also cause serious pollution to the environment. In addition, if the oil contains free water, it will affect the quality of the oil and cause corrosion to mechanical equipment. [0003] At present, oil-water separators with complex equipment and high energy consumption are widely used in the field of oil-water separation technology. On this basis, the recently emerging micro / nano oil-water separation material technology is an environmentally friendly and economical purifi...

Claims

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Application Information

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IPC IPC(8): B01D17/022B01D39/00
Inventor 朱英滕超刘欢鹿现永江雷
Owner BEIHANG UNIV
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