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Waterborne aluminium foil adhesive and preparation method thereof

A water-based technology for aluminum foil glue, applied in adhesive types, monocarboxylic acid ester copolymer adhesives, ester copolymer adhesives, etc., can solve the problems of high efficiency, low glue bonding strength, comprehensive Poor performance and other problems, to achieve the effect of low cost, good film hardness, creep resistance and deformation resistance

Inactive Publication Date: 2013-02-27
BEIJING COMENS NEW MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the aluminum foil glue used for compounding aluminum foil paper mostly uses polyvinyl acetate (PVAc) white latex or starch glue. This kind of glue has low bonding strength, poor peel strength, poor folding resistance of composite products, and poor overall performance. good with flaws
In addition, due to its high viscosity, poor leveling, inconvenient use, and extremely difficult cleaning, it is difficult to meet the high efficiency requirements of users.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] This embodiment provides a water-based aluminum foil adhesive, which can be used for the bonding of aluminum foil and paper to prepare aluminum foil paper; the adhesive is based on monomers, emulsifiers, protective glue, initiators, buffers, deionized water, pH regulators Water-based additives are used as raw materials, and the compound glue with a solid content of 40-50% is prepared through the steps of pre-emulsification, seed reaction, polymerization reaction and compounding;

[0022] Wherein, said monomer comprises hard monomer, soft monomer and functional monomer; Hard monomer can be made up of vinyl acetate (VAc) and methyl acrylate (MA); Soft monomer is made up of butyl acrylate (BA) and acrylic acid Composed of ethyl ester (EA); the functional monomer is composed of any one of acrylic acid (AA) or methacrylic acid (MAA) and N-methylol acrylamide (NMA); the total weight of each raw material of the monomer is 100% Calculated, the weight percentage of each raw mate...

Embodiment 2

[0038] This embodiment provides a water-based aluminum foil glue, which can be used for bonding aluminum foil and paper to prepare aluminum foil paper. The aluminum foil glue includes the following raw materials:

[0039] Raw material formula parts by weight

[0040] Deionized water 100

[0041] Vinyl acetate 32

[0042] Methyl acrylate 12

[0043] Ethyl acrylate 39

[0044] Butyl acrylate 10

[0045] Methacrylic acid 4

[0046] N-Hydroxyacrylamide 3

[0047] Alkyl ether ammonium sulfate (emulsifier) ​​1.8

[0048] Alkylphenol polyoxyethylene ether (emulsifier) ​​0.9

[0049] Polyvinyl alcohol (protective glue) 1.5

[0050] Ammonium persulfate (initiator) 0.5

[0051] Sodium bicarbonate (buffer) 0.12

[0052] Ammonia (pH regulator) 1.2

[0053] Dibutyl phthalate (plasticizer) 2.5

[0054] Water-based wetting agent (OT-75, Cytec company product) 0.35

[0055] Water-based leveling agent (BL200, Cognis company product) 0.1

[0056] Water-based preservative (A-26, prod...

Embodiment 3

[0063] This embodiment provides a water-based aluminum foil glue, which can be used for bonding aluminum foil and paper to prepare aluminum foil paper. The aluminum foil glue includes the following raw materials:

[0064] Raw material formula parts by weight

[0065] Deionized water 135

[0066] Vinyl acetate 35

[0067] Methyl acrylate 15

[0068] Ethyl acrylate 28

[0069] Butyl acrylate 15

[0070] Acrylic 4.5

[0071] N-methylolacrylamide 2.5

[0072] Alkyl ether ammonium sulfate (emulsifier) ​​2.4

[0073] Alkylphenol polyoxyethylene ether (emulsifier) ​​1.2

[0074] Polyvinyl alcohol (protective glue) 2.0

[0075] Ammonium persulfate (initiator) 0.6

[0076] Ammonium bicarbonate (buffer) 0.18

[0077] Ammonia (pH regulator) 1.6

[0078] Dioctyl phthalate (plasticizer) 4

[0079] Water-based wetting agent (OT-75, Cytec company product) 0.25

[0080] Water-based leveling agent (BL200, Cognis company product) 0.3

[0081] Water-based preservative (A-26, produc...

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PUM

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Abstract

The invention discloses a waterborne aluminium foil adhesive and a preparation method thereof and belongs to the field of adhesives. The aluminium foil adhesive is a composite adhesive with solid content of 40 to 50 percent, which is prepared by using monomers, an emulsifier, protective colloid, an initiator, a buffer, a pH (potential of hydrogen) regulator, a plasticizer, a waterborne assistant and deionized water as the raw materials through pre-emulsification, seed reaction, polymerization reaction and compounding. The monomers in the raw materials comprise hard monomers, soft monomers and functional monomers, wherein the hard monomers adopt vinylacetate and methyl acrylate; the soft monomers adopt ethyl acrylate and butyl acrylate; and the functional monomers adopt any one of acrylic acid or methacrylic acid and N-hydroxymethyl acrylamide. The waterborne aluminium foil adhesive has the advantages of low cost, high stripping strength and good leveling property and is simple and convenient to operate.

Description

technical field [0001] The invention belongs to the field of adhesive production, in particular to a water-based aluminum foil adhesive and a preparation method thereof. Background technique [0002] Aluminum foil paper has good moisture-proof, fresh-keeping, taste-keeping and decorative properties. It is widely used in cigarettes, candy and other packaging. Products using this composite process have a strong metallic texture, bright colors, tough and light texture, and are stretchable. Strong, gradually become the choice of many users. [0003] Aluminum foil glue is mainly used for bonding aluminum foil and paper to prepare aluminum foil paper, which is widely used in the packaging material industry. At present, the aluminum foil glue used for compounding aluminum foil paper mostly uses polyvinyl acetate (PVAc) white latex or starch glue. This kind of glue has low bonding strength, poor peel strength, poor folding resistance of composite products, and poor overall performa...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J131/04C09J133/08C08F218/08C08F220/14C08F220/18C08F220/06C08F220/58C08F2/30C08F2/26
Inventor 陈小锋沈峰邓煜东
Owner BEIJING COMENS NEW MATERIALS
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