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Halogen-free flame-retardant composite material and preparation method thereof

A technology of flame-retardant composite materials and flame retardants, applied in chemical instruments and methods, synthetic resin layered products, layered products, etc., can solve the problem of affecting the bond strength of aluminum plates, the corrosion of aluminum plates, and the decline in material yields, etc. problems, to achieve good synergistic flame retardant effect, good hot-pressing bonding performance, and outstanding flame retardant effect

Active Publication Date: 2013-06-05
FOSHAN SANSHUI JINGE NEW MATERIALS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the aluminum-plastic composite board core material with these flame retardant synergists has good flame retardant performance, ammonium polyphosphate, copper nitrate, etc. have certain water solubility, especially in humid environmental conditions, they are easy to migrate to the substrate. The surface of the material affects the bond strength with the aluminum plate, and even the ammonium polyphosphate may have deamination phenomenon during processing, resulting in bubbles and affecting the physical properties of the material. At the same time, there are acid sites on the main chain, which are corrosive to the aluminum plate and cause The yield of materials decreases and the total manufacturing cost increases

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] The percentages of high-density polyethylene (HDPE 7200) and ethylene-vinyl acetate copolymer (EVA R5011) in total weight are 22.5% and 13.5% respectively, and the percentages of other components in total weight are: hydrogen Magnesium Oxide 55%, Melamine Polyphosphate 5%, Oxidized Polyethylene Wax 4%.

[0031] Test results: the tensile strength is 12.9MPa, the elongation at break is 15%, the bending strength is 14.7MPa, and the notched impact strength is 10.9KJ / m 2 , the Vicat softening point is 81°C, the vertical combustion is V-0 (4mm), and the limiting oxygen index is 37.

Embodiment 2

[0033] The percentages of high-density polyethylene (HDPE 7200) and ethylene-vinyl acetate copolymer (EVA R5011) in total weight are 27.5% and 16.5% respectively, and the percentages of other components in total weight are: hydrogen Magnesium Oxide 45%, Melamine Polyphosphate 10%, Zinc Stearate 1%.

[0034] Test results: the tensile strength is 13.9MPa, the elongation at break is 17%, the bending strength is 14.9MPa, and the notched impact strength is 11.3KJ / m 2 , Vicat softening point is 82°C, vertical combustion is V-0 (4mm), limiting oxygen index: 39.

Embodiment 3

[0036] The percentages of high-density polyethylene (HDPE 7200) and ethylene-vinyl acetate copolymer (EVA R5011) in total weight are 27.5% and 16.5% respectively, and the percentages of other components in total weight are: hydrogen Magnesium Oxide 40%, Melamine Polyphosphate 15%, Calcium Stearate 1%.

[0037] Test results: the tensile strength is 13.1MPa, the elongation at break is 16%, the bending strength is 15.1MPa, and the notched impact strength is 11.5KJ / m 2 , Vicat softening point is 83°C, vertical combustion is V-0 (4mm), limiting oxygen index: 40.

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Abstract

The invention provides a halogen-free flame-retardant composite material and a preparation method thereof, and the halogen-free flame-retardant composite material comprises 10%-40% (by weight) of polyethylene, 4.5%-20% (by weight) of elastomer, 40%-70% (by weight) of halogen-free flame retardant, 0.5%-15% (by weight) of flame-retardant synergist and 1%-5%( by weight) of lubricant according to thetotal weight of the composite material, wherein the flame-retardant synergist is selected from one or more of melamine, melamine cyanurate and melamine high molecular weight phosphate. The preparation method comprises the step of carrying out melt compounding on the polyethylene, the elastomer, the halogen-free flame retardant, the flame-retardant synergist and the lubricant through an extruding machine. The halogen-free flame-retardant composite material has the advantage of novel property, environmental protection, safety, excellent flame retardance, good anti-melt droplet effect, good toughness, excellent molding and processing performance and the like, and can achieve the UL-94V-0 (the plate thickness is 4mm) flame retardant level, thereby being particularly applicable to preparing halogen-free flame-retardant aluminum-plastic composite plates.

Description

technical field [0001] The invention relates to a halogen-free flame-retardant composite material and a preparation method thereof, in particular to a halogen-free flame-retardant composite polymer material for preparing aluminum-plastic composite boards and a preparation method thereof. Background technique [0002] Aluminum-plastic composite board is a new type of building decoration material, which has the advantages of light weight, good strength, smooth surface, rich and bright colors, and convenient construction. It is widely used in airports, hotels, stations, large entertainment venues and high-end high-rise buildings. Curtain wall, indoor and outdoor decoration and other occasions are indispensable elements of modern architecture. At present, countries all over the world have higher and higher requirements for the safety of building materials, and fire performance is one of the most important indicators of safety. However, the currently commonly used polymer compos...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/06C08L23/08C08K3/22C08K5/3492C08K5/098B32B15/085B32B27/18
Inventor 姜宏伟靳晓雨董亮亮
Owner FOSHAN SANSHUI JINGE NEW MATERIALS CO LTD
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