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Bullet-resistant glass and fireproof glass for insulating heat and resisting radiation, as well as compound glass thereof

A bulletproof glass, fireproof glass technology, applied in glass/slag layered products, chemical instruments and methods, layered products, etc., can solve the problems of glass bonding strength, hardening of plasticizers, inability to absorb, etc. , to prevent damage to the optic nerve, prevent rain and dew atomization, and prevent accidents.

Inactive Publication Date: 2010-08-11
何海波
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Existing laminated safety glass, such as laminated safety glass used for windshields of automobiles, laminated safety window glass of high-rise buildings and laminated furniture glass, etc., although the light transmittance is high, they cannot play the role of heat insulation, bulletproof and fire prevention. , cannot prevent rain and dew atomization and ice and snow adhesion, nor can it absorb glare and 200-380nm ultraviolet rays, let alone absorb 780-1500nm near-infrared rays
Because the existing laminated safety glass is prepared by the following formula technology: (1) Polyvinyl butyral film method: Cut polyvinyl butyral into the required film base, sandwich it between two layers of glass It is made by heating and pressing with a heat-sealing machine. This method has very high requirements for the film, that is, the film must be free from scratches and defects, and the thickness must be very uniform. The cost of raw materials is high, and the investment in equipment is huge.
(2) Thermal polymerization glue filling method: pour the prepared prepolymer into the middle of the two layers of glass that have been sealed, and gradually heat up in the heating furnace to make it heat and solidify. The production cycle of this method is as long as 24~ 36 hours, the temperature is required to be 80-100°C, and the cost is quite high
The laminated safety glass produced by the light-curing adhesive method has the following disadvantages: (1) It is easy to age, the bonding strength is not high, and it is easy to fail and fall off after a long time, causing accidents
(2) The adhesive cannot adapt to changes in ambient temperature and has a greater impact on the bonding strength of the glass. The plasticizers DBP and DOP used will harden and become brittle over time
(3) After the laminated safety glass is impacted and broken, the retention rate of the fragments is only about 60%, which is not safe
(4) It cannot prevent the atomization of rain and dew, and cannot prevent the adhesion of ice and snow
(5) Can not absorb ultraviolet light from 200 to 380nm and near-infrared light from 780 to 1500nm

Method used

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  • Bullet-resistant glass and fireproof glass for insulating heat and resisting radiation, as well as compound glass thereof
  • Bullet-resistant glass and fireproof glass for insulating heat and resisting radiation, as well as compound glass thereof
  • Bullet-resistant glass and fireproof glass for insulating heat and resisting radiation, as well as compound glass thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0047] Embodiment 1: Preparation of laminated safety glass

[0048] Weigh each component of the organic interlayer adhesive material according to the following weight percentages:

[0049] Main material 60.0%~70.0%; Modifier 10.0%~15.0%; Modifier 3.0%~5.0%;

[0050] Crosslinking agent 0.1% ~ 1.5%; coupling agent 0.5% ~ 1.5%; thickener 1.0% ~ 3.0%;

[0051] Photoinitiator 0.5%~2.5%; Catalyst 1.0%~5.0%; Anti-impact agent 3.0%~5.0%;

[0052] Excipient 0.5%~2.0%; UV-IR optical protection material 0.5%~5%.

[0053] Among them, the main material is methyl methacrylate; the modifier is selected from methacrylic acid, n-butyl methacrylate, n-butyl acrylate or a mixture of two or more; the modifier is selected from hydroxypropyl acrylate One or two mixtures of esters and hydroxypropyl methacrylate; the crosslinking agent is selected from one or two mixtures of glycidyl methacrylate and allyl methacrylate; the coupling agent is selected from A mixture of one or two of self-coupling ...

Embodiment 2

[0057] Embodiment two: the preparation of bulletproof glass

[0058] Take three pieces of silicate glass with a thickness of 2 mm to 5 mm, wash and dry them; make a mold frame according to the method described in Example 1, wherein, from the inside to the outside, the first interlayer is an organic interlayer adhesive material layer, and its The filling thickness is controlled at 0.5 mm to 3 mm; the second interlayer is a bulletproof rubber layer, and its filling thickness is controlled at 3 mm to 8 mm.

[0059] The organic interlayer adhesive material prepolymerized slurry was prepared according to the method described in Example 1.

[0060] Weigh each component of bulletproof rubber according to the following weight percentages, and carry out pre-polymerization pulping:

[0061] n-butyl methacrylate 65.0%~70.0%; fluorene 10.0%~12.0%;

[0062] Butyl acrylate 8.0%~10.0%; vinyl siloxane coupling agent 3.0%~5.0%;

[0063] Vinyl acetate 2.0%~3.0%; Lithium thphenoyltrioxydiacet...

Embodiment 3

[0069] Embodiment three: preparation of fireproof glass

[0070] Get two pieces of silicate glass with a thickness of 2 mm to 5 mm and a piece of cesium potassium glass with a thickness of 3 mm to 5 mm, wash and dry; make a mold frame according to the method described in Example 1, wherein the cesium potassium glass is arranged on the outermost Layers; from inside to outside, the first interlayer is an organic interlayer adhesive material layer, and its filling thickness is controlled at 0.5mm-3mm; the second interlayer is a flame-retardant adhesive layer, and its filling thickness is controlled at 2mm-4mm.

[0071] The organic interlayer adhesive material prepolymerized slurry was prepared according to the method described in Example 1.

[0072] Weigh each component of the flame-retardant rubber according to the following weight percentages for pre-polymerization pulping:

[0073] Vinyl bromide 25.0%~30.0%; Halogenated polyphosphate 18.0%~20.0%;

[0074]Methyl methacrylate ...

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Abstract

The invention respectively discloses bullet-resistant glass and fireproof glass for insulating heat and resisting radiation, as well as and compound glass thereof, which respectively comprise laminated safety glass, bullet-resistent glue and / or fire-retardant glue and an outer-layer glass substrate, wherein the outer-layer glass substrate is bonded on the surface of the laminated safety glass by the bullet-resisting glue and / or the fire-retardant glue; and the laminated safety glass comprises two inner-layer glass substrates and an organic laminated adhesive material which is arranged between the two inner-layer glass substrates. The bullet-resistant glass and the fireproof glass not only can resist bullets and fire, but also can absorb ultraviolet rays, near infrared rays and strong dazzling light to insulate heat, prevent freeze, resist bright light, strong heat, the penetration of harmful radiant rays for human bodies, and the like, can prevent rain pulverization, snow adhesion and self-pulverization of glass under strong shock waves, realize self protection, and the like.

Description

technical field [0001] The invention belongs to the technical field of glass, and more specifically, the invention relates to bulletproof glass, fireproof glass and composite glass with functions of heat insulation and radiation protection. Background technique [0002] Existing laminated safety glass, such as laminated safety glass used for windshields of automobiles, laminated safety window glass of high-rise buildings and laminated furniture glass, etc., although the light transmittance is high, they cannot play the role of heat insulation, bulletproof and fire prevention. , can not prevent rain and dew atomization and ice and snow adhesion, nor can it absorb glare and 200-380nm ultraviolet rays, let alone absorb 780-1500nm near-infrared rays. Because the existing laminated safety glass is prepared by the following formula technology: (1) polyvinyl butyral film method: cut polyvinyl butyral into the required film base, sandwich it between two layers of glass It is made b...

Claims

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Application Information

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IPC IPC(8): C03C27/12B32B17/10
Inventor 何海波高云秋卢中坚何开生
Owner 何海波
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