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Modified triethanolamine, preparation method and application thereof

A technology of triethanolamine and modification, applied in the field of high-efficiency grinding aid and reinforcing agent for cement, can solve the problems of unsatisfactory application effect of grinding aid, inability to improve the early strength of cement, and high cost of grinding aid, and achieve low cost and good grinding aid. effect, the effect of reducing clinker consumption

Inactive Publication Date: 2009-01-07
SHANDONG SHANSHUI CEMENT GRP CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the high temperature of cement grinding in my country at present, the volatilization loss of traditional grinding aids is serious after use, resulting in unsatisfactory application effects of grinding aids in actual production
[0004] On December 22, 2004, the State Intellectual Property Office published an application whose publication number is CN 1556055A and whose patent name is a kind of high-efficiency cement composite grinding aid. Its components include triethanolamine, acetic acid, aluminum sulfate solution, pulp waste liquid, Low-molecular-weight fatty acid salt and water can greatly reduce the cost of the product, and the effect of grinding aid is remarkable, but it cannot improve the early strength of cement
[0005] There are also some high-efficiency grinding aids with enhanced functions that can improve the early strength of cement, but due to the use of the main raw material triethanolamine, the cost of grinding aids is relatively high

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] A kind of modified triethanolamine, its component is triethanolamine, mixed acid, sulfamic acid and dehydrating agent, and the content of each component by mass percentage is

[0043] Triethanolamine 50%

[0044] Mixed acid 48%

[0045] Sulfamic acid 1%

[0046] Silicone 1%.

[0047] The preparation process of this modified triethanolamine is: first drop into triethanolamine 50%, sulfamic acid 1% and silica gel 1% in the reaction kettle, after stirring evenly, be warming up to 80 ℃; Begin to drop 48% mixed acid (mixed acid is sulfuric acid: Phosphoric acid: oxalic acid=90:5:5), dripping is completed within 2 hours. The reaction temperature was controlled at 120°C, and then raised to 145°C after dripping, and kept for 1 hour; after cooling, the dehydrating agent was filtered off; the obtained product was modified triethanolamine.

[0048] A kind of powdery grinding aid strengthening agent, its component is above-mentioned modified triethanolamine, inorganic fine powd...

Embodiment 2

[0060] A kind of modified triethanolamine, its component is triethanolamine, mixed acid, sulfamic acid and dehydrating agent, and the content of each component by mass percentage is

[0061] Triethanolamine 60%

[0062] Mixed acid 39%

[0063] Silicone 1%.

[0064] The preparation process of this modified triethanolamine is as follows: in the reaction kettle, firstly drop 60% of triethanolamine and 1% of silica gel, stir and then heat up to 90°C; start to add 39% of mixed acid (mixed acid is sulfuric acid: phosphoric acid: oxalic acid=90: 5:5), the dripping was completed within 0.5 hours. The reaction temperature was controlled at 100°C, and after dripping, the temperature was raised to 145°C and kept for 1 hour; after cooling, the dehydrating agent was filtered off; the obtained product was modified triethanolamine.

[0065] A kind of powdery grinding aid strengthening agent, its component is above-mentioned modified triethanolamine, inorganic fine powder, aluminum sulfate...

Embodiment 3

[0077] A kind of modified triethanolamine, its component is triethanolamine, mixed acid, sulfamic acid and dehydrating agent, and the content of each component by mass percentage is

[0078] Triethanolamine 45%

[0079] Mixed acid 50%

[0080] Sulfamic acid 3%

[0081] Silicone 2%.

[0082] The preparation process of the modified triethanolamine is as follows: in the reaction kettle, press 45% of triethanolamine, 3% of sulfamic acid and 2% of silica gel, stir and then heat up to 85°C; start to drop 50% of mixed acid (mixed acid is sulfuric acid: Phosphoric acid: tartaric acid = 90: 5: 5), dripped within 2 hours. The reaction temperature was controlled at 120°C, and then raised to 145°C after dripping, and kept for 1 hour; after cooling, the dehydrating agent was filtered off; the obtained product was modified triethanolamine.

[0083] A water-based liquid grinding aid enhancer, its components are the above-mentioned modified triethanolamine, glycerin, molasses, ethylene gl...

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PUM

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Abstract

The invention discloses modified triethanolamine, a preparation method thereof and various grinding aids produced by using the modified triethanolamine. The modified triethanolamine is a cross mixed ester product produced through the chemical reaction of triethanolamine, inorganic mixed acid and catalyzer at a temperature. Grinding aid intensifier in powdered form, aqueous liquid form and nonaqueous liquid form is prepared by effectively compounding the product with other components. The triethanolamine is converted into the cross mixed ester having large molecular weight, thus reducing the cost by about 30 percent; the modified triethanolamine is applicable for powder grinding process at high temperature. The cement grinding aid intensifier prepared by compounding triethanolamine with other materials has better grinding aid effect compared with such conventional grinding aids which are used separately as triethanolamine and so on, improves the early strength of cement and reduces the consumption of wrought material; the materials used are cheap, and are stored and transported easily. The multiform products (powdered and in liquid state) are widely applicable in the cement industry.

Description

technical field [0001] The invention relates to the technical field of chemical products, in particular to a modified triethanolamine, a preparation method thereof, and a high-efficiency cement grinding aid produced by using the modified triethanolamine. The cement high-efficiency grinding aid enhancer is used in the cement grinding process to improve the grinding efficiency, increase the early strength of cement, reduce the consumption of clinker, and improve the performance of cement. It belongs to the field of chemical building materials of cement-based material admixtures. Background technique [0002] Energy saving and consumption reduction and improvement of cement quality are long-term and important tasks of my country's cement industry. In cement manufacturing, grinding is an important part and also a part with high energy consumption. When the cement clinker, admixture and gypsum are put into the mill, the materials are gradually crushed and ground under the action...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B24/12C04B7/52C04B103/52
CPCC04B2103/52C04B24/122Y02P40/10C04B20/023
Inventor 陈仲圣郑强白明科王惠忠
Owner SHANDONG SHANSHUI CEMENT GRP CO LTD
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