Method for comprehensive recovery and utilization of fluorine-containing alkali waste water and saponification of extracting agent
A technology of waste alkaline water and extractant, which is applied in the treatment of waste alkaline water containing fluorine, the saponification of extractant, and the comprehensive recycling and utilization of waste alkaline water containing fluorine. It can solve problems such as simple conditions, pollution, and effective treatment of ions, and achieve The working conditions are stable, the production cost is reduced, and the effect of saving the three wastes treatment process and cost
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Embodiment 1
[0031] Detect that the alkalinity in the waste alkaline water is 1.5mol / L, and the 1m 3 The waste alkaline water and 2.8m 3 The P507 organic phase (used after being diluted with kerosene, sulfonated kerosene, etc., this technology is a well-known technology in the art) was mixed and stirred in the reactor for 1 minute, and the reaction temperature was 25 ° C, and the saponification of the organic phase was completed, and the saponification value was 0.54mol / L. OH- enters the organic phase, and the aqueous phase is NaF solution. The organic phase is saponified for extraction, and the aqueous phase is concentrated to obtain a NaF product with a purity of 98%.
Embodiment 2
[0033] Detect that the alkalinity in the waste alkaline water is 0.8mol / L, control the water phase and the naphthenic acid / isomeric acid organic phase according to the volume ratio of 1:2, mix and stir in the reactor for 5 minutes, and the reaction temperature is 40°C. The saponification of the organic phase is completed, and the saponification value is 0.4mol / L. Oh - Enter the organic phase, and the aqueous phase is NaF solution. The organic phase is saponified for extraction, and the aqueous phase is concentrated to obtain a NaF product with a purity of 99.1%. In this example, the naphthenic acid organic phase and the isomeric acid are mixed at a volume ratio of 1:1 (thinners such as kerosene and octanol need to be added during use, which is also a well-known technology in the art).
Embodiment 3
[0035] Detect that the alkalinity in the waste alkaline water is 1.0mol / L, and the 1m 3 waste alkaline water with 2.5m 3 The organic phase (P204 and P507 are mixed in a volume ratio of 1:1) was mixed and stirred in the reactor for 6 minutes, and the reaction temperature was 30° C., and the saponification of the organic phase was completed, and the saponification value was 0.4mol / L. The organic phase is saponified for extraction, and the water phase is then added with inorganic salts of Al and Na to accurately control the molar ratio of the added ions to form cryolite (Na 3 AlF 6 ) crystallization to transfer and recover F.
[0036] By adopting the method of the invention, compared with the existing ammonia water and sodium hydroxide saponification method, the cost can be reduced by half, and the discharge of fluorine-containing waste water is only 10% of the existing method, and the economic benefit and environmental protection effect are remarkable.
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