585results about "Hologram recording material" patented technology

A new photopolymerizable material allows single-step, fast recording of volume holograms with properties that can be electrically controlled. Polymer-dispersed liquid crystals (PDLCs) in accordance with the invention preferably comprise a homogeneous mixture of a nematic liquid crystal and a multifunctional pentaacrylate monomer in combination with photoinitiator, coinitiator and cross-linking agent. Optionally, a surfactant such as octancic acid may also be added. The PDLC material is exposed to coherent light to produce an interference pattern inside the material. Photopolymerization of the new PDLC material produces a hologram of clearly separated liquid crystal domains and cured polymer domains. Volume transmission gratings made with the new PDLC material can be electrically switched between nearly 100% diffraction efficiency and nearly 0% diffraction efficiency. By increasing the frequency of the switching voltage, switching voltages in the range of 50 Vrms can be achieved. The optional use of a surfactant allows low switching voltages at lower frequencies than without a surfactant. In an alternative embodiment, a PDLC material in accordance with the invention can be utilized to form reflection gratings, including switchable reflection gratings. In still further embodiments, a PDLC material in accordance with the invention can be used to form switchable subwavelength gratings. By further processing, static transmission, reflection, and subwavelength PDLC materials can be formed. In addition, PDLC materials in accordance with the present invention can be used to form switchable slanted transmission gratings suitable for switchable optical coupling and reconfigurable optical interconnects.

A hologram has a hologram element 3 containing a photopolymer and a cover film 22 and cover plate 21 which cover its surfaces. An adhesive 1 is used for bonding the cover film to the hologram element and the cover plate to the hologram element. The hologram has excellent humidity resistance, chemical resistance, solvent resistance and heat resistance, prevents coloration, can maintain its holographic properties and allows easy repositioning of the hologram element.

A photosensitive composition and A photosensitive medium for volume hologram recording comprises a photopolymerization reactive compound (a monomer) and any one of the following binder: (a) an organic-inorganic hybrid polymer obtainable by copolymerizing an organometallic compound of the formula 1 “R1m M1 (OR2)” and an ethylenic monomer and / or its hydrolyzed polycondensate; (b) an organic-inorganic hybrid polymer obtainable by copolymerizing an organometallic compound of the formula 3 “R4m Si (OR5)n” and an ethylenic monomer and / or its hydrolyzed polycondensate; and (c) a binder resin bonded to a metal or a combination use of a binder resin containing a hydroxyl group and / or carboxyl group and a metal chelate compound.

A holographic recording medium exhibiting a high recording sensitivity without execution of reduction treatment. A system records information on the holographic recording medium by using a gating light within a wavelength band causing less optical damage to the holographic recording medium. The holographic recording medium includes a single crystal of lithium niobate (LiNbO3) or lithium tantalate (LiTaO3) containing Mn as a dopant.

A method for the production of a holographic sensor wherein the holographic recording material forming the sensitive element is a polymer matrix, which comprises diffusing into the matrix one or more soluble salts that undergo reaction in situ to form an insoluble sensitive precipitate; and recording a holographic image. This method allows the production of a holographic sensor wherein the holographic recording material forming the sensitive element is an insoluble polymer film.

The present invention relates to a photopolymer formulation containing chemically crosslinked matrix polymers, writing monomers and a photoinitiator system, wherein the photoinitiator system contains a HABI, a dye attuned to the HABI and having an absorption maximum in the range of 400-800 nm and a hydrogen donor. The present invention further relates to a process for producing exposed holographic media with the above photopolymer formulation.

The hologram recording sheet according to the invention is made up of a base film and hologram sensitive materials sensitive to different wavelength regions formed therein in a desired pattern, or a film and at least two hologram recording sensitive materials sensitive to different wavelength regions laminated on the film with a transparent plastic spacer layer located therebetween, thereby enabling the required diffraction light wavelengths to be recorded on the required sites without producing unnecessary interference fringes. At least two hologram recording sensitive materials sensitive to different wavelength regions are formed on different sites on a film in dotted or striped configuration, the size of which is up to 200 mm or at least twice as large as the thickness of the sensitive material layers, thereby enabling regions diffracting light of different wavelengths to be formed in the form of independent sets of interference fringes.

Holographic storage media including a substrate and a dye material capable of undergoing a photo-induced change are disclosed. Data may be written into the holographic storage media using light of one wavelength and read using light of a different wavelength.

The objective of the present invention is providing a method for fabricating high quality diffractive waveplates and their arrays that exhibit high diffraction efficiency over large area, the method being capable of inexpensive large volume production. The method uses a polarization converter for converting the polarization of generally non-monochromatic and partially coherent input light beam into a pattern of periodic spatial modulation at the output of said polarization converter. A substrate carrying a photoalignment layer is exposed to said polarization modulation pattern and is coated subsequently with a liquid crystalline material. The high quality diffractive waveplates of the present invention are obtained when the exposure time of said photoalignment layer exceeds by generally an order of magnitude the time period that would be sufficient for producing homogeneous orientation of liquid crystalline materials brought in contact with said photoalignment layer. Compared to holographic techniques, the method is robust with respect to mechanical noises, ambient conditions, and allows inexpensive production via printing while also allowing to double the spatial frequency of optical axis modulation of diffractive waveplates.

Holographic and diffractive security devices and documents carrying security devices as well as system, apparatus, and method for making and using security devices. Security devices provide at least one type of security feature in form of secret, hidden, or covert security feature, not visible to a normal unaided human eye. Covert security features may be any graphic or symbolic representation. One or multiple security features may be provided on any single security device in any combination. Covert feature is revealed either when a decoder device is used with the security device, or when the security device is oriented and viewed in predetermined manner. Embodiments may provide a second overt or non-covert security device in the form of a diffractive or holographic image or graphic that is visible to the unaided eye without use of any decoder or special viewing conditions.

Transmission and reflection type holograms may be formed utilizing a novel polymer-dispersed liquid crystal (PDLC) material and its unique switching characteristics to form optical elements. Applications for these switchable holograms include communications switches and switchable transmission, and reflection red, green, and blue lenses. The PDLC material of the present invention offers all of the features of holographic photopolymers with the added advantage that the hologram can be switched on and off with the application of an electric field. The material is a mixture of a polymerizable monomer and liquid crystal, along with other ingredients, including a photoinitiator dye. Upon irradiation, the liquid crystal separates as a distinct phase of nanometer-size droplets aligned in periodic channels forming the hologram. The material is called a holographic polymer-dispersed liquid crystal (H-PDLC).

Transmission and reflection type holograms may be formed utilizing a novel polymer-dispersed liquid crystal (PDLC) material and its unique switching characteristics to form optical elements. Applications for these switchable holograms include communications switches and switchable transmission, and reflection red, green, and blue lenses. The PDLC material of the present invention offers all of the features of holographic photopolymers with the added advantage that the hologram can be switched on and off with the application of an electric field. The material is a mixture of a polymerizable monomer and liquid crystal, along with other ingredients, including a photoinitiator dye. Upon irradiation, the liquid crystal separates as a distinct phase of nanometer-size droplets aligned in periodic channels forming the hologram. The material is called a holographic polymer-dispersed liquid crystal (H-PDLC).

A hologram has a hologram element 3 containing a photopolymer and a cover film 22 and cover plate 21 which cover its surfaces. An adhesive 1 is used for bonding the cover film to the hologram element and the cover plate to the hologram element. The hologram has excellent humidity resistance, chemical resistance, solvent resistance and heat resistance, prevents coloration, can maintain its holographic properties and allows easy repositioning of the hologram element.

Systems, articles, and methods that integrate photopolymer film with eyeglass lenses are described. One or more hologram(s) may be recorded into / onto the photopolymer film to enable the lens to be used as a transparent holographic combiner in a wearable heads-up display employing an image source, such as a microdisplay or a scanning laser projector. The methods of integrating photopolymer film with eyeglass lenses include: positioning photopolymer film in a lens mold and casting the lens around the photopolymer film; sandwiching photopolymer film in between two portions of a lens; applying photopolymer film to a concave surface of a lens; and / or affixing a planar carrier (with photopolymer film thereon) to two points across a length of a concave surface of a lens. Respective lenses manufactured / adapted by each of these processes are also described.

A method for preparing electro-optical polymer-liquid crystal photonic crystals, comprising: disposing between at least two optically transparent electrode plates, a polymer-dispersed liquid crystal material that comprises, before exposure:(a) a polymerizable monomer comprising at least one acrylate;(b) a liquid crystal;(c) a chain-extending monomer;(d) a coinitiator;(e) a photoinitiator; and(f) a long chain aliphatic acid;and exposing this polymer-dispersed liquid crystal material to light in an interference pattern.

The invention relates to holographic media containing specific photopolymers, a process for the production thereof, and unsaturated glycidyl ether acrylate urethanes as writing monomers which are suitable for the preparation of photopolymers.

The present invention is directed to a transmission type laminated hologram optical element constituting an image display apparatus, wherein plural transmission type hologram optical elements (13), (14), (15) where diffraction acceptance incident angles are different from each other are laminated. The respective transmission type hologram optical elements are adapted so that outgoing angles with respect to center incident angles of respective diffraction acceptance incident angles at an arbitrary wavelength of the visible region are different from each other, whereby a diffraction acceptance angle of incident light can be broadened, light utilization efficiency is permitted to be high, and distance with respect to color pixels of the spatial light modulation element can be optimally set from viewpoints of light utilization efficiency.

A holographic direct-view display system uses holographic integral imaging techniques that is an auto stereoscopic way to reproduce parallax and occlusion. The display is not resolution limited and is scalable to display life size images if desired. The system can be used to transmit 3D depictions of a scene at video and sub-video rates as well as other information, such as images of documents or computer generated images. The images may be captured, transmitted and displayed in real-time (or near real-time) for telepresence or stored for time-shifted display. The system combines integral holography, a pulsed laser to record the hologram at high speed and a dynamic refreshable holographic material such as a photorefractive polymer as a recording media. The system uses techniques to write, read and erase the updateable hologram that allow the holographic material, hence direct-view display to remain stationary throughout each of the processes for continuous presentation of the hologram to the audience. The system may write, read and erase at the same time and continuously to increase throughput. This system may also use additional novel techniques to improve brightness, efficiently implement a full-parallax display and to implement a full-color display in a transmission geometry.

A holographic recording apparatus having a source of illumination, a master hologram containing at least one hologram lamina overlaying, a copy substrate containing a holographic recording medium, and a voltage generator for applied a voltage across at least one of the master hologram and the copy substrate. The master hologram diffracts the illumination light into zero order light and diffracted light which interfere in the copy substrate to form a copy of the master hologram. The source of illumination is applied for a predefined exposure time during which the voltage varies the refractive index modulation of at least one of the master hologram and the copy hologram.

A dynamic hologram is formed in anisotropic liquid crystal (LC) gel materials. By applying an electric field, the orientation of part of the liquid crystals can be altered and the hologram can be turned on and off. Using LC gels allows for holographic elements with no diffraction in the voltage off state so that the hologram appears only during application of an electric field. Also, the anisotropic LC gels maintain polarization dependence. The dynamic holograms are suitable in e.g. dynamic holographic optical components whereby an optical function can be included / excluded in a beam path without introducing or removing elements.

A method of producing a hologram element is disclosed that is able to prevent spread of a polymerization reaction and light leakage during exposure with interference light, and improve productivity in mass production. The hologram element is for transmitting, reflecting, diffracting, or scattering incident light, and includes a pair of substrates, an isolation member between the substrates that forms an isolated region, and a photo-sensitive recording material sealed in the isolated region. The hologram element includes a periodic structure formed by exposing the recording material to interference light. The interference light is generated by two or more light beams, or by using a master hologram. The recording material is formed from a composite material including a polymerized polymer or a polymerized liquid crystal. The periodic structure is formed by exposing the recording material to the interference light to induce the polymerization reaction and phase separation in the composite material.

A new photopolymerizable material allows single-step, fast recording of volume holograms with properties that can be electrically controlled. Polymer-dispersed liquid crystals (PDLCs) in accordance with the invention preferably comprise a homogeneous mixture of a nematic liquid crystal and a multifunctional pentaacrylate monomer, in combination with photoinitiator, coinitiator and cross-linking agent. Optionally, a surfactant such as octanoic acid may also be added. The PDLC material is exposed to coherent light to produce an interference pattern inside the material. Photopolymerization of the new PDLC material produces a hologram of clearly separated liquid crystal domains and cured polymer domains. Volume transmission gratings made with the new PDLC material can be electrically switched between nearly 100% diffraction efficiency and nearly 0% diffraction efficiency. By increasing the frequency of the switching voltage, switching voltages in the range of 50 Vrms can be achieved. The optional use of surfactant allows low switching voltages at lower frequencies than without surfactant. In an alternative embodiment, a PDLC material in accordance with the invention can be utilized to form reflection gratings, including switchable reflection gratings. In still further embodiments, a PDLC material in accordance with the invention can be used to form switchable subwavelength gratings. By further processing, static transmission reflection, and subwavelength PDLC materials can be formed.

The present invention relates to a system, as well as articles and holographic recording medium comprising the system, where the system comprises: a polymerizable component comprising at least one photoactive polymerizable material; and a photoinitiator component comprising at least one photoinitiator for causing the polymerizable component to polymerize to thereby form a plurality of holographic gratings when activated by exposure to a photoinitiating light source; wherein when a portion of the polymerizable component has been polymerized to form at least one holographic grating, the unpolymerized portion of the polymerizable component is resistant to further polymerization when not exposed to the photoinitiating light source. The present invention also provides methods for forming at least one holographic grating in a holographic recording medium having such a photopolymerizable system.

Iterating an optical phase conjugation of ultrasonically-modulated diffuse light emitted by a scattering medium includes illuminating the scattering medium with a light beam from a coherent light source, modulating the diffuse light transmitted through the scattering medium with an ultrasonic wave focused on a region of interest within the scattering medium, fixing a hologram, retro-reflectively illuminating the scattering medium using a phase-conjugated copy of the diffuse light that was ultrasonically modulated, moving the ultrasonic focus, and iterating until light is focused on the final target.

The present invention relates to a counterfeit-proof volume hologram multilayer structure capable of securely preventing a counterfeiter from replicating a volume hologram recorded therein. The multilayer structure comprises a transparent surface protective layer, a volume hologram layer, and an adhesive layer which are sequentially laminated and is characterized in that particles having particle diameter of 350 nm or more are dispersed in at least one of the transparent surface protective layer, the volume hologram layer, and the adhesive layer and that the refractive index ratio (nF / nB) is set to be not less than 1.05 or not greater than 0.95, wherein nF is the refractive index of the particles and nB is the refractive index of the medium in which the particles are dispersed, or characterized in that at least either the refractive index ratio (nP / nH) between the transparent surface protective layer and the volume hologram layer or the refractive index ratio (nH / nA) between the volume hologram layer and the adhesive layer is set to be not less than 1.08, wherein nP is the refractive index of the transparent surface protective layer, nH is the refractive index of the volume hologram layer, and nA is the refractive index of the adhesive layer.

A photosensitive composition and A photosensitive medium for volume hologram recording comprises a photopolymerization reactive compound (a monomer) and any one of the following binder: (a) an organic-inorganic hybrid polymer obtainable by copolymerizing an organometallic compound of the formula 1 "R1m M1 (OR2)" and an ethylenic monomer and / or its hydrolyzed polycondensate; (b) an organic-inorganic hybrid polymer obtainable by copolymerizing an organometallic compound of the formula 3 "R4m Si (OR5)n" and an ethylenic monomer and / or its hydrolyzed polycondensate; and (c) a binder resin bonded to a metal or a combination use of a binder resin containing a hydroxyl group and / or carboxyl group and a metal chelate compound.