A new photopolymerizable material allows single-step, fast recording of volume holograms with properties that can be electrically controlled.
Polymer-dispersed liquid crystals (PDLCs) in accordance with the invention preferably comprise a homogeneous mixture of a nematic
liquid crystal and a multifunctional pentaacrylate
monomer in combination with
photoinitiator, coinitiator and cross-linking agent. Optionally, a surfactant such as octancic acid may also be added. The PDLC material is exposed to coherent light to produce an interference pattern inside the material. Photopolymerization of the new PDLC material produces a hologram of clearly separated
liquid crystal domains and cured
polymer domains. Volume transmission gratings made with the new PDLC material can be electrically switched between nearly 100%
diffraction efficiency and nearly 0%
diffraction efficiency. By increasing the frequency of the switching
voltage, switching voltages in the range of 50 Vrms can be achieved. The optional use of a surfactant allows low switching voltages at lower frequencies than without a surfactant. In an alternative embodiment, a PDLC material in accordance with the invention can be utilized to form reflection gratings, including switchable reflection gratings. In still further embodiments, a PDLC material in accordance with the invention can be used to form switchable subwavelength gratings. By further
processing, static transmission, reflection, and subwavelength PDLC materials can be formed. In addition, PDLC materials in accordance with the present invention can be used to form switchable slanted transmission gratings suitable for switchable
optical coupling and reconfigurable optical interconnects.