56 results about "2,2,4,4-Tetramethyl-1,3-cyclobutanediol" patented technology

Described are polyester compositions comprising at least one polyester which comprises terephthalic acid residues, 2,2,4,4-tetramethyl-1,3-cyclobutanediol, and 1,4-cyclohexanedimethanol, wherein the inherent viscosity and the Tg of the polyester provides for certain polyester properties. The polyesters may be manufactured into articles such as fibers, films, bottles or sheets.

Described are graphic art films comprising polyester compositions comprising polyesters which comprise (a) a dicarboxylicacidcomponent having terephthalic acid residues; optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues or ester residues thereof; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and 1,4-cyclohexanedimethanol residues.

Described are polyesters containing (a) a dicarboxylic acid component having from 70 to 100 mole % of terephthalic acid residues, and up to 30 mole % of aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues; and (b) a glycol component having from 40 to 65 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues, and from 35 to 60 mole % of 1,4-cyclohexanedimethanol residues; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %. The polyesters may be manufactured into articles such as fibers, films, containers, bottles or sheets.

Disclosed are aliphatic polyester resins containing 2,2,4,4-tetramethyl-1,3-cyclo-butanediol and solvent borne, thermosetting coating compositions prepared therefrom. The aliphatic polyesters exhibit good hardness and flexibility when formulated into thermosetting coatings compositions.

Described are baby bottle(s) comprising polyesters comprising (a) a dicarboxylic acid component having terephthalic acid or an ester thereof; optionally, an aromatic dicarboxylic acid or aliphatic dicarboxylic acid or esters thereof; 2,2,4,4-tetramethyl-1,3-cyclobutanediol; and 1,4-cyclohexanedimethanol.

Described are pacifiers comprising polyester compositions comprising polyesters which comprise (a) a dicarboxylic acid component having terephthalic acid residues; optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues or ester residues thereof; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and 1,4-cyclohexanedimethanol residues.

The present invention relates to a clear, semicrystalline article comprising a polyester comprising terephthalic acid residues as the dicarboxylic acid component, and 1 to 15 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues and 85 to 99 mole % of 1,4-cyclohexanedimethanol residues as the glycol component. The article may be in the form of a film or sheet, a bottle, or a fiber. The article, when produced by a process involving strain-induced crystallization, is characterized with high crystallinity.

Described as one aspect of the invention are polyesters containing (a) a dicarboxylic acid component having from 70 to 100 mole % of terephthalic acid residues and up to 30 mole % of aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues; and (b) a glycol component having from 11 to 25 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues, and 75 to 89 mole % of 1,4-cyclohexanedimethanol residues; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %. The polyesters may be manufactured into articles.

Described are retort food containers comprising polyester compositions comprising polyesters which comprise (a) a dicarboxylic acid component having terephthalic acid residues; optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues or ester residues thereof; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and 1,4-cyclohexanedimethanol residues.

The invention relates to the field of production of 2,2,4,4-tetramethyl-1,3-cyclobutanediol, and concretely relates to a catalyst, a preparation method thereof, and an apparatus and a method for preparing 2,2,4,4-tetramethyl-1,3-clobutanediol. The catalyst comprises a main active metal element, a metalloid element, a carrier and an optional coactive metal element, the main active metal element isone or more of Fe, Co and Ni, the metalloid element is B and/or P, and the coactive active metal element is one or more of Co, Ru, Pd, Rh, Ir, and Pt; and the content of the main active metal elementin the catalyst is 1-70 wt%. The catalyst, the apparatus and the preparation methods of the invention are used to realize high-efficiency conversion of ketones, improve the cis-trans isomer molar ratio of the 2,2,4,4-tetramethyl-1,3-cyclobutanediol product and reduce the wearing and consumption of the catalyst.

Described are polyester compositions comprising (a) a dicarboxylic acid component comprising terephthalic acid residues; optionally, aromatic dicarboxylic acid or aliphatic dicarboxylic acid residues; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues, wherein said 2,2,4,4-tetramethyl-1,3-cyclobutanediol contains certain cis to trans ratios; and 1,4-cyclohexanedimethanol residues.

The invention discloses a method for preparing 2,2,4,4-tetramethyl-1,3-cyclobutanediol. Iso-butyryl chloride used as a raw material is stirred evenly in ether solvent, triethylamine is added, reflux reaction is carried out for 13-16h, diluted hydrochloric acid is used for washing, pressure is reduced to remove solvent to obtain intermediate 2,2,4,4-tetramethyl-1,3-cyclobutanedione, the intermediate is dissolved in mixed solvent of methyl alcohol and water, NaOH is used for regulating pH value to be alkaline, quantitative NaBH4 is added in batches under an ice-bath condition, the reaction is performed for 3-5h at normal temperature, diluted hydrochloric acid is used for quenching, solvent is removed, absolute ethyl alcohol is used for extraction, after ethyl alcohol is removed through rotary evaporation, water is used for extraction, and finally, the water is removed to obtain 2,2,4,4-tetramethyl-1,3-cyclobutanediol. The method has simple equipment requirement, mild operation condition, low cost and high product purity, and is suitable for industrial production.