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Methods for making carboxylated pulp fibers

a technology of carboxylated pulp fibers and fibers, which is applied in the multi-stage pulping process, organic chemistry, and pulping with inorganic bases. it can solve the problems of fiber strength loss, crosslinking, yellowing, and poor reproduction of the tempo system, and achieves the effect of little additional equipmen

Inactive Publication Date: 2005-02-10
WEYERHAEUSER CO
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

A carboxylation system and process for wood pulp which may be placed in an existing pulp mill bleach plant, or incorporated into a new bleach plant with little additional equipment. A carboxylation system and process for wood pulp which will allow the mill to transition from regular pulp to carboxylated pulp and back with ease.
What is needed is a process and equipment that allows pulp to be carboxylated in an existing pulp mill without large capital costs.
Additional work reduced the first stage reaction time to 30 seconds or less. Now it was possible to use the existing pulp mill equipment with only the addition of mixers and supply lines and supply storage.

Problems solved by technology

Results with the TEMPO system were poorly reproduced and equivocal.
Aldehyde substituents on cellulose are known to cause degeneration over time and under certain environmental conditions.
In addition, minor quantities of ketone may be formed at C-2 and C-3 of the anhydroglucose units and these will also lead to degradation.
Marked degree of polymerization loss, fiber strength loss, crosslinking, and yellowing are among the consequent problems.

Method used

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  • Methods for making carboxylated pulp fibers
  • Methods for making carboxylated pulp fibers
  • Methods for making carboxylated pulp fibers

Examples

Experimental program
Comparison scheme
Effect test

example 35

Never-dried partially bleached softwood pulp collected after the E2 bleach stage of the Weyerhaeuser Prince Albert SK mill pulp having an oven dry weight of 60 g, and 9.2 g sodium carbonate was added to 310 g of DI water and the mixture was heated to 70° C. 98 mL of chlorine dioxide, 6.7 g / L, and 1.2 g of ethylene glycol ketal of triacetoneamine (EGK-TAA) were mixed and added to the pulp. The pulp was mixed rapidly by hand. Samples were taken at 15, 30, 60, 120, 180 and 240 seconds after the ClO2 / EGK-TAA solution first contacted the pulp. Each of the samples were placed in a solution of 0.5 g NaBH4 in 100 mL of water and left overnight at room temperature with periodic stirring. The pulps were then tested for carboxyl content. The carboxyl content in meq / 100 g were as follows: 15 seconds-6.7, 30 seconds-6.8, 60 seconds-7.2, 120 ds-7.5, 180 seconds-7.55, 240 seconds-7.6.

example 36

Northern softwood partially bleached kraft pulp collected after the E2 stage of the Weyerhaeuser Prince Albert, SK pulp mill was dewatered to 25-30% solids with a screw press.

All percentages are weight percentages based on the oven dry weight of the pulp.

The pulp was slurried in water and fed to a twin roll press which delivered pulp at a predetermined constant rate of 3.0 kg / minute pulp solids at 8-9% consistency (weight of pulp / weight of water) to a pilot process. Just after the twin roll press, sodium hydroxide was sprayed on the pulp stream at a rate of 0.65%. The pulp slurry was then mixed and heated in a steam mixer and fed to a Seepex progressive cavity pump which provided pulp slurry flow through two high intensity mixers and an upflow tower. The upflow tower fed a downflow tower by gravity. Pulp product was mined from the bottom of the downflow tower, adjusted to pH 7-9 with sodium hydroxide and dewatered on a belt washer.

EGK-TAA was dissolved in water and metered in...

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Abstract

An apparatus for carboxylating wood pulp which utilizes the wood pulp bleach plant and the method of carboxylating the pulp which takes place in the bleach plant.

Description

FIELD OF THE INVENTION The present invention relates to incorporation of a carboxylation system into the bleach plant of a wood pulp mill to provide carboxylated cellulosic fibers. BACKGROUND OF THE INVENTION Cellulose is a carbohydrate consisting of a long chain of glucose units, all β-linked through the 1′-4 positions. Native plant cellulose molecules may have upwards of 2200 anhydroglucose units. The number of units is normally referred to as degree of polymerization (D.P.). Some loss of D.P. inevitably occurs during purification. A D.P. approaching 2000 is usually found only in purified cotton linters. Wood derived celluloses rarely exceed a D.P. of about 1700. The structure of cellulose can be represented as follows: Chemical derivatives of cellulose have been commercially important for almost a century and a half. Nitrocellulose plasticized with camphor was the first synthetic plastic and has been in use since 1868. A number of cellulose ether and ester derivatives are pre...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C07D207/46C07D265/30C08B15/04D21C9/00C07D211/92D21C9/10D21H11/20
CPCD21C9/002D21C9/1047D21C9/1026
Inventor SEVEREID, DAVID E.JEWELL, RICHARD A.KOMEN, JOSEPH L.WEERAWARNA, S. ANANDASU, BING
Owner WEYERHAEUSER CO
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