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Material of polyethylene in super high molecular weight for obstruction guard of highway, and fabricating method

A technology of ultra-high molecular weight and manufacturing method, which is applied in the field of anti-collision highway guardrail materials and its manufacturing field, can solve the problems of reduced toughness of products, easy stress concentration of products, economical pressure, etc., and achieves large elastic-plastic deformation area and deformation amount. , long deformation relaxation time, good safety effect

Inactive Publication Date: 2007-05-09
肖久梅 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the continuous production of pure UHMWPE products has been realized by adopting the improved screw and barrel structure, the production speed and the apparent quality of the products are still problems due to the low critical shear rate of pure UHMWPE.
[0014] In order to improve the processing problems and production efficiency of UHMWPE, Tsinghua University, Institute of Chemistry, Chinese Academy of Sciences, Shanghai Research Institute of Chemical Industry, Beijing Dongfang Chemical Factory and other units have also done a lot of significant improvement work on the blending and modification formula of UHMWPE materials, such as the Chinese patent Application 98100960 reported the use of liquid crystal polymers and UHMWPE blending modification, which improved the disadvantage of poor fluidity of UHMWPE melt alone; but the cost of liquid crystal polymer materials is too high, and there is pressure on the economy
[0015] Chinese patent application 01100016 reports that the blending modification of layered silicate and UHMWPE can be improved, although the processing characteristics of UHMWPE can be improved, and the cost of modified additives is also advantageous, but it is difficult to achieve microscopic mixing at the molecular level. The product is prone to stress concentration, and compared with pure UHMWPE, the toughness of the product decreases
[0025] Highway guardrail products manufactured based on existing materials and technologies have disadvantages such as low safety, heavy installation, inconvenient installation, and high production cost, while UHMWPE has not been reported for the manufacture of highway guardrail structural materials.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] 35 parts of ultra-high molecular weight polyethylene with a weight-average molecular weight of 2.5 million are selected as the main material; latent solvents are selected: 40 parts of solid fully refined paraffin wax with a melting point of 72 ° C, 20 parts of chlorinated paraffin, diisodecyl phthalate (DIDP) 5 parts; flame retardant selection: superfine antimony trioxide 5 parts, carbon black 10 parts, triphenyl phosphite 10 parts; antioxidant 1010, 0.2 parts; polyolefin selection m-LLDPE EXCEED1018, 10 parts; PIB 2000, 10 parts; thermoplastic elastomer EVA, 5 parts.

[0044] First, add 20 parts of chlorinated paraffin, 5 parts of diisodecyl phthalate (DIDP), 10 parts of triphenyl phosphite, 10 parts of PIB 2000, and then add 40 parts of solid paraffin into the mixer. First melt and stir evenly, then add 35 parts of UHMWPE powder, 5 parts of superfine antimony trioxide, and 10 parts of carbon black, heat together and stir for 20 hours. The fully swollen UHMWPE slurry ...

Embodiment 2

[0048] 30 parts of ultra-high molecular weight polyethylene with a weight-average molecular weight of 3.5 million are selected as the main material; latent solvents are selected: 60 parts of solid fully refined paraffin wax with a melting point of 72 ° C, 10 parts of diisodecyl phthalate (DIDP); flame retardant Selection: 10 parts of superfine magnesium hydroxide, 15 parts of carbon black; 1010, 0.5 parts of antioxidant; LLDPE 7042, 5 parts of polyolefin; 10 parts of thermoplastic elastomer EVA.

[0049] First add 10 parts of diisodecyl phthalate (DIDP) into the mixer, then add 60 parts of solid fully refined paraffin wax with a melting point of 72°C, melt at 115°C, stir evenly, then add 30 parts of UHMWPE powder, super 10 parts of fine magnesium hydroxide and 15 parts of carbon black were heated together and stirred for 24 hours. The fully swelled UHMWPE slurry premix is ​​quantitatively and continuously conveyed into the parallel co-rotating twin-screw extruder (length-to-di...

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Abstract

An anticollision protecting fence material for highway is prepared from ultrahigh molecular weight polyethene (UHMWPE) through pre-swelling, dissolving and pugging in dual-screw extruder, extruding out for shaping, and stretching for strengthening. It has high longitudinal tension strength (100-180 MPa) and large longitudinal elongation rate at break (50-350%).

Description

technical field [0001] The invention relates to the technical field of road guardrails, in particular to an anti-collision road guardrail material and a manufacturing method thereof. Background technique [0002] The guardrails installed on both sides of the roadbed and the central isolation belt have the protective effect of preventing high-speed vehicles that deviate from the normal direction of travel from rushing out of the road, reducing impact damage to vehicles and occupants, and redirecting vehicles that deviate from the road direction. [0003] Modern high-speed road guardrails have two relatively contradictory requirements. One is that the guardrail material has a sufficiently high tensile strength in the longitudinal or road direction and relatively small deformation to prevent the vehicle from deviating too much from the normal track; When the guardrail material hits, the guardrail material can undergo relatively large elastic-plastic deformation to absorb the im...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B29C69/02B29C47/40B29C47/78B29C55/12B29C55/26B29K23/00B29L31/00B29C48/793B29C48/875
CPCB29C48/875B29C48/865B29C48/793B29C48/873
Inventor 肖久梅邓新建
Owner 肖久梅
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