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A kind of preparation method of silver metal oxide flake electric contact

An electrical contact and oxide technology, applied in metal material coating process, contacts, circuits, etc., can solve the problems of easy occurrence of holes in the silver layer, limit of the minimum thickness of the silver layer, uneven speed, etc., to save welding Thickness of silver layer, saving precious metal resources, obvious effect

Active Publication Date: 2021-12-10
ZHEJIANG FUDA ALLOY MATERIALS TECH CO LTD
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  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This preparation method has the advantages of high material utilization rate and good silver layer consistency, but in order to ensure the fluidity of the silver paste, a certain amount of organic matter must be added, and there are special requirements for the particle size distribution and morphology of the raw material silver powder. The manufacturing cost of the paste itself is high; defects such as holes are prone to appear in the silver layer after sintering, which affects the soldering performance of the contacts; limited by the fluidity of the silver paste, there is a certain limit on the minimum thickness of the silver layer
Patent No. 94193439.X discloses a preparation process for the connection layer of silver metal oxide contact materials based on a single-sided reduction method, using the reduced silver alloy layer as the connection layer. It has been verified by practice that this method is difficult to obtain a neat The distribution of the connection layer, under the condition of no pressure, the diffusion of the reducing atmosphere in the silver metal oxide material is not synchronous, there is a phenomenon of local uneven speed, and the distribution uniformity of the prepared contact silver layer is poor; after After the reduction treatment, the structure of the silver alloy layer is loose, and it is easy to seal the gas during the welding process, resulting in low shear strength after welding

Method used

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  • A kind of preparation method of silver metal oxide flake electric contact
  • A kind of preparation method of silver metal oxide flake electric contact
  • A kind of preparation method of silver metal oxide flake electric contact

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preparation example Construction

[0048] Further, when the AgMeO substrate is round or square, the preparation method includes the following steps:

[0049] ①AgMeO wire preparation: AgMeO wire is prepared by conventional internal oxidation process, pre-oxidation process or powder metallurgy process, and processed to the required specifications and state after drawing and annealing;

[0050] ②Cold heading forming: AgMeO wire is prepared by cold heading forming equipment to prepare AgMeO sheet blanks, and the welding surface of AgMeO sheet blanks has logo patterns during cold heading forming;

[0051] ③Surface treatment: AgMeO flakes are cleaned and degreased by ultrasonic cleaning equipment to obtain AgMeO flakes with a clean surface and no organic residues;

[0052] ④Magnetron sputtering silver plating: Arrange the AgMeO flakes with the pattern facing up in the tray, place the tray in the magnetron sputtering equipment, install the pure silver target, close the coating chamber and pre-evacuate to ≤5× 10 -4 P...

Embodiment 1

[0073] Embodiment 1: The AgMeO substrate is silver tin oxide indium oxide:

[0074] a) Melt 22kg of silver, 2kg of tin and 1kg of indium in the graphite crucible of an intermediate frequency melting furnace to form a silver-tin-indium alloy melt, which is prepared into silver-tin-indium alloy powder by high-pressure water atomization equipment; the silver-tin-indium alloy powder is baked Drying, sieving, and powder oxidation to prepare silver tin oxide indium oxide powder with a silver content of 85%;

[0075] b) Silver tin oxide indium oxide powder is pressed into a φ105mm ingot by cold isostatic pressing equipment. After sintering at 850°C for 4 hours, it is extruded into a strip with a size of 50×4mm, rolled to a size of 50×2.25mm, and the surface treatment is removed. Impurities and oil stains on the surface are obtained to obtain semi-finished strips of silver tin oxide and indium oxide;

[0076] c) Silver tin oxide and indium oxide semi-finished strips are closely packe...

Embodiment 2

[0081] Embodiment two: the AgMeO substrate is silver tin oxide:

[0082] a) Mix 19.5kg of silver powder, 2.73kg of tin oxide powder and 0.5kg of additive powder in a plow-shovel mixer for 4 hours, wherein the silver powder is -200 mesh, the average particle size of tin oxide powder is 5 μm, and the average particle size of additive powder is 2 μm. Prepared as silver tin oxide powder with a silver content of 88%;

[0083] b) Silver tin oxide powder is pressed into a φ88mm ingot by cold isostatic pressing equipment. After sintering at 900°C for 6 hours, it is extruded into a 40×4mm strip, rolled to a 40×2.45mm size, and the surface is treated to remove the surface Impurities and oil stains are removed to obtain silver tin oxide semi-finished strips;

[0084] c) Silver tin oxide semi-finished strips are closely packed on the barrel of the magnetron sputtering equipment, put the barrel into the magnetron sputtering silver plating equipment, install the pure silver target, close t...

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Abstract

The disclosure relates to a preparation method of a silver metal oxide flake electric contact, which adopts a magnetron sputtering process to plate silver on an AgMeO substrate; During controlled sputtering silver plating, the AgMeO substrate is heated and kept to 30%-65% of the melting point of the AgMeO substrate. This disclosure uses magnetron sputtering technology, combined with the actual situation of electric contacts and the respective advantages of several conventional preparation processes, to form an independent, efficient and stable electric contact preparation method, and to a certain extent avoid the shortcomings of the above-mentioned processes. On the premise of ensuring the bonding strength of the working layer and the soldered silver layer, the distribution uniformity of the silver layer is improved, and the cost of contact materials in the switching device is reduced.

Description

technical field [0001] The disclosure belongs to the field of electrical alloy materials, in particular to a method for preparing a silver metal oxide flake electrical contact applied in the fields of contactors, circuit breakers, relays and the like. Background technique [0002] In the low-voltage electrical appliance industry, the most widely used electrical contact material is silver-based electrical contact material, and among them, silver metal oxide electrical contact material has excellent arc erosion resistance, welding resistance and low and stable contact resistance, etc. Comprehensive advantages occupy an important position in the entire electrical contact material system. When silver metal oxide materials are used in the field of contactors with relatively large current levels, they are usually processed into the form of sheet contacts, which are assembled after welding with copper contact bridges. Due to the poor wettability between the silver metal oxide mate...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01H11/04C23C14/35C23C14/16
CPCH01H11/04H01H11/048C23C14/35C23C14/165H01H1/023H01H1/0237
Inventor 万岱宋振阳缪仁梁郑泽成张明江刘映飞魏庆红夏宗斌陈开松宋林云王达武
Owner ZHEJIANG FUDA ALLOY MATERIALS TECH CO LTD
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