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A kind of medium electrolyte, lithium ion battery and preparation method thereof

A lithium-ion battery and electrolyte technology, which is applied in the direction of solid electrolyte, non-aqueous electrolyte, electrolyte immobilization/gelation, etc., can solve the problems of insignificant improvement in charge and discharge efficiency, growth of lithium dendrites, and easy combustion of electrolyte, etc. Achieve the effects of unaffected cycle and rate performance, high room temperature conductivity and temperature resistance, and good chemical stability

Active Publication Date: 2021-09-03
南通赛得能源有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Lithium dendrites may appear in liquid lithium-ion batteries working at high currents, which can pierce the diaphragm and cause short-circuit damage; the electrolyte is an organic liquid, which will intensify the tendency of side reactions, oxidative decomposition, gas generation, and combustion at high temperatures
When the liquid lithium-ion battery is subjected to severe impact or the battery temperature is too high, the electrolyte is very easy to burn, causing the battery to catch fire and more serious safety accidents
[0005] Liquid batteries are eagerly changing to solid-state batteries, but the conductivity of all-solid-state electrolytes is not ideal now, so it will slowly transition from quasi-solid-state batteries to all-solid-state batteries
For solid-state batteries, metal lithium is the most ideal negative electrode material, but side reactions between the liquid electrolyte and lithium metal are prone to occur, resulting in the growth of lithium dendrites and reducing the Coulombic efficiency of the battery. It is currently the development of quasi-solid-state batteries. bottleneck
[0006] The publication number is CN103855427A invention patent application discloses a solid electrolyte, the main technical problem to be solved is to provide a modified polymethyl methacrylate electrolyte with high mechanical strength and electrical conductivity, and its specification records the prepared lithium ion battery The charge and discharge efficiency of the 0.1C charge and discharge test does not improve significantly, and the application effect of high energy density lithium batteries needs further research

Method used

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  • A kind of medium electrolyte, lithium ion battery and preparation method thereof
  • A kind of medium electrolyte, lithium ion battery and preparation method thereof

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Embodiment 1

[0039] In order to further explain the technical solution of the present invention, the present invention will be described in detail below through specific examples. In this embodiment, the high-nickel material 811 is used for the positive electrode, which can be replaced by other materials. Different material systems have different energy densities, but this does not affect the experimental rules. Lithium metal is used for the negative electrode.

[0040] The electrolyte formula adopts the conventional formula: the solvent component of the electrolyte is 0.2 mol / L of fluorinated diether, EC: EMC = 1:1, the amount of additive is 0.1-0.3 mol / L; the lithium salt is LiPF 6 , the addition amount is 1-1.5mol / L; the choice of electrolyte only affects the conductivity of the liquid system, and has no effect on the performance of the medium electrolyte;

[0041] The quasi-solid electrolyte uses methyl methacrylate-LAGP-ZMS-5, and the specific preparation method is as follows:

[004...

Embodiment 2

[0053] The main difference between this embodiment and embodiment 1 is:

[0054] Polyethylene oxide is selected as the polymer electrolyte matrix; ethylene carbonate is selected as the plasticizer; the raw material ratio of the dielectric electrolyte is: polyethylene oxide 80%, LAGP 15%, propylene carbonate 5%; 4 times.

Embodiment 3

[0056] The main difference between this embodiment and embodiment 1 is:

[0057] Polymethyl methacrylate is selected as the polymer electrolyte matrix; ethyl methyl carbonate is selected as the plasticizer; the raw material ratio of the dielectric electrolyte: 90% polymethyl methacrylate, 6% LAGP, 4% propylene carbonate; the thickness of the dielectric electrolyte layer is 4um , Acetonitrile consumption is 4 times of raw material quality.

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Abstract

The invention discloses a medium electrolyte, which includes the following substances according to the mass fraction: 6% to 24% conductive lithium salt; 70% to 90% polymer electrolyte matrix; 3% to 6% plasticizer; the invention also discloses the use of the The lithium-ion battery of medium electrolyte, comprises the positive pole piece that the surface is coated with quasi-solid electrolyte and lithium negative pole piece, and lithium negative pole piece surface is coated with described medium electrolyte; Preferably described quasi-solid state electrolyte comprises methyl methacrylate, Li 1.5 Al 0.5 Ge 1.5 (PO 4 ) 3 and mesoporous molecular sieve; the present invention also discloses the preparation method of the medium electrolyte; the present invention utilizes the state of the medium electrolyte semi-solid gel to have good chemical stability to lithium metal, suppresses the growth of lithium dendrites, and thus obtains lithium metal with excellent performance ion battery.

Description

technical field [0001] The invention relates to the technical field of lithium ion batteries, in particular to a medium electrolyte, a lithium ion battery using the medium electrolyte and a preparation method of the medium electrolyte. Background technique [0002] With the popularization of electric vehicles, the safety issues of high energy density lithium batteries are becoming increasingly severe. Especially in recent years, the electric vehicle fire incidents reported internationally and domestically have become more and more frequent, which highlights the challenge of designing batteries with both safety and energy density. [0003] In order to further improve the energy density and safety performance of lithium-ion batteries, solid-state batteries have become the only way. The conductivity of all-solid-state batteries cannot meet the requirements, and more exploration is needed to achieve mass production. Industrialized lithium-ion batteries, including global power b...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M10/056H01M10/0565H01M10/0525
CPCH01M10/0525H01M10/056H01M10/0565H01M2300/0082H01M2300/0085Y02E60/10
Inventor 孙晓玉李炳江王立群郑浪易祖良刘奕凯叶鑫
Owner 南通赛得能源有限公司
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