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Method and device for decomposing dioxin in incineration flue gas by low-temperature plasma coupling catalysis

A technology of low-temperature plasma and incineration of flue gas, applied in separation methods, chemical instruments and methods, gas treatment, etc., can solve the problems of not reducing the total amount of dioxins, high catalytic light-off temperature, and lack of engineering demonstrations, etc., to achieve High difficulty in removal, improved oxygen storage performance, and the effect of avoiding secondary pollution

Active Publication Date: 2020-03-31
HEBEI UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, the use of activated carbon to adsorb dioxins in flue gas only transfers dioxins from flue gas to activated carbon, and does not reduce the total amount of dioxins, and the activated carbon after adsorbing dioxins is hazardous waste and requires special treatment
In addition, due to the lack of engineering demonstrations, only a few manufacturers use catalytic degradation technology to deal with dioxins. Using catalysts alone has the problem of high catalytic light-off temperature, and the catalytic reaction temperature is above 200 °C
Ultraviolet photolysis, plasma decomposition and other technologies to treat dioxin are currently in the primary research stage, and the energy consumption of the plasma reactor is relatively high, and there is a relatively high concentration of residual ozone at the outlet

Method used

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  • Method and device for decomposing dioxin in incineration flue gas by low-temperature plasma coupling catalysis
  • Method and device for decomposing dioxin in incineration flue gas by low-temperature plasma coupling catalysis
  • Method and device for decomposing dioxin in incineration flue gas by low-temperature plasma coupling catalysis

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Experimental program
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Embodiment 1

[0060] Such as figure 1 As shown, this embodiment provides a device for removing dioxins in waste incineration flue gas by using the coupling effect of low-temperature plasma and catalyst, including an air inlet pipe 1, an air inlet 2, a low-temperature plasma reaction unit 3, a catalytic Reaction unit 4, gas outlet 5, gas outlet pipe 6, clean gas / regeneration gas inlet pipe 7 and high voltage power supply 8. waste incineration flue gas from figure 1 The air inlet pipe 1 and air inlet 2 on the middle left enter the purification device and enter the low-temperature plasma reaction unit 3. Under the action of a high-voltage electric field, the strong oxidizing particles produced by the high-voltage discharge of the low-temperature plasma reaction unit will partially oxidize dioxins. The voltage waveform of the high-voltage power supply 8 is a DC high-voltage power supply or a DC superimposed high-frequency pulse power supply. The positive DC voltage is adjustable within the ran...

Embodiment 2

[0064] The discharge electrode 302 of the low-temperature plasma reaction unit of this embodiment adopts a stainless steel sawtooth wire, and the high-voltage power supply 8 is connected to a positive DC high-voltage power supply, and the discharge voltage is +11kV. The clean gas intake pipe 7 is not opened during the discharge process. Catalyst 402 uses γ-alumina and titanium dioxide as carriers, vanadium pentoxide, platinum oxide, and tungsten oxide as active components, and a mixture of iron oxide, manganese oxide, and cerium oxide as active additives; wherein: the carrier contains γ - the proportion of alumina is 40wt%, the proportion of titanium dioxide is 60wt%, the loading of vanadium in the active component is 1.5wt%, the loading of platinum is 0.5wt%, and the loading of tungsten is 2wt%; The loading amount of the agent is 0.5wt%. Based on this configuration, the flue gas of a domestic waste incinerator is introduced for treatment, and the volume of flue gas to be tre...

Embodiment 3

[0067] The discharge electrode 302 of the low-temperature plasma reaction unit of this embodiment adopts a stainless steel barbed wire, and the high-voltage power supply 8 is connected to a negative DC high-voltage power supply, and the discharge voltage is -13kV. The clean gas intake pipe 7 is not opened during the discharge process. Catalyst 402 uses γ-alumina and titanium dioxide as carriers, vanadium pentoxide, platinum oxide, and tungsten oxide as active components, and a mixture of iron oxide, manganese oxide, and cerium oxide as active additives; wherein: the carrier contains γ - the proportion of alumina is 50wt%, the proportion of titanium dioxide is 50wt%, the loading of vanadium in the active component is 1.5wt%, the loading of platinum is 0.5wt%, and the loading of tungsten is 2wt%; The loading amount of the agent is 0.5wt%. Based on this configuration, the flue gas of a domestic waste incinerator is introduced for treatment, and the volume of flue gas to be treat...

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Abstract

The invention relates to a method and a device for decomposing dioxin in incineration flue gas by low-temperature plasma coupling catalysis. According to the method, a low-temperature plasma reactionunit and a catalytic reaction unit are connected in series, so that waste incineration flue gas firstly passes through the low-temperature plasma reaction unit, and dioxin in the flue gas is partiallyoxidized by strong oxidizing particles such as ozone generated by high-voltage discharge; and the dioxin enters the catalytic reaction unit, and on the surface of the catalyst, the dioxin can be thoroughly catalyzed and oxidized into small molecular substances such as carbon dioxide, water and hydrogen chloride under the condition of lower smoke temperature by virtue of strong oxidizing particlesgenerated in the low-temperature plasma reaction unit. The advantages of the low-temperature plasma and the catalyst are synergistically utilized, the treatment effect is good, secondary pollution ofozone is avoided, and industrial popularization can be carried out.

Description

technical field [0001] The invention relates to a method for purifying flue gas from a garbage incinerator, and belongs to the technical field of environmental protection. More specifically, it relates to a method that combines low-temperature plasma oxidation and catalysis generated by high-voltage discharge to efficiently decompose dioxins in waste incineration flue gas and effectively avoid secondary pollution of ozone. Background technique [0002] With the rapid development of my country's economy, the level of urbanization and the continuous improvement of people's living standards, the amount of garbage generated is increasing day by day, and the resulting pollution problems are becoming more and more serious. The harmless disposal of garbage has become an urgent problem to be solved in the field of ecological environment. At present, the main ways to deal with garbage are: landfill, incineration and composting. According to the data of the National Bureau of Statis...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D53/75B01D53/86B01D53/32B01D53/70B01D53/64B01D53/56
CPCB01D53/75B01D53/8662B01D53/323B01D53/64B01D53/56B01D2258/0291B01D2259/818B01D2257/2064B01D2257/404B01D2257/60B01D2255/20707B01D2255/2092B01D2255/20776B01D2255/20723B01D2255/1021B01D2255/20738B01D2255/2073B01D2255/2065
Inventor 王美艳沈伯雄黄超张长平孙优善柳洋刘国超
Owner HEBEI UNIV OF TECH
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