Polyester chip for producing automotive interior fiber and preparation method thereof
A technology for polyester chips and automotive interiors, applied in the field of polyester chips and its preparation, can solve the problems of low strength, crystallinity, low cleanliness, high melting point of polyester chips, etc., and achieve excellent flexibility and strength , the appearance size is easier to grasp, and the effect of high reliability of the finished product
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[0024] The preparation method of polyester chips for producing automotive interior fiber of the present invention comprises the following steps:
[0025] (1) Synthesis of polyester chip bottom material
[0026] ① Put the mixture of isophthalic acid and terephthalic acid into the ethylene glycol solution, in which isophthalic acid accounts for 5%-15% of the total acid mole fraction, and the ratio of the total ethylene glycol moles to the total acid moles 1.20-1.35, uniformly pump the mixed slurry into the esterification reaction kettle to obtain a uniform slurry of BHET and its derivative intermediates;
[0027] ②When the temperature of the slurry in step ① is stabilized to 245-265°C, pour the slurry obtained in step ① into the polycondensation reactor;
[0028] ③After the mixed slurry enters the polycondensation tank, add reactive antimony catalysts and stabilizers, control the reaction temperature at 270-290°C, and carry out negative pressure polymerization reaction. The vac...
Embodiment 1
[0045] ①Esterification reaction stage: Add 8% isophthalic acid and 92% terephthalic acid (percentages are mole fractions, the same below) to the slurry mixing tank, totaling 2 tons, and then according to the acid-alcohol molar ratio of 1 : 1.20 Dosing ethylene glycol, after mixing evenly, pump it into an esterification reaction kettle at a constant speed through a pipeline pump, and carry out esterification reaction at 250-255°C to obtain a homogeneous mixed slurry of BHET and its derivatives.
[0046] ②Use nitrogen to press the mixed slurry obtained in step ① into the polycondensation reactor through a 25μm stainless steel filter for polymerization reaction, add 1300g of ethylene glycol antimony and 500mL of trimethyl phosphate, control the internal temperature to 270°C, and the vacuum degree to be ≤30pa , After 4.0 hours of reaction, the intrinsic viscosity is reached and the material is discharged.
[0047] ③Put 2.3 tons of polyester chips obtained in step ② into the solid-...
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