Super-hydrophobic electroactive anti-pitting coating capable of being solidified under normal temperature and preparation method thereof
A room temperature curing, super-hydrophobic technology, applied in coatings, conductive coatings, anti-corrosion coatings, etc., to achieve the effects of improving mechanical properties and mechanical properties, high effective specific surface area, and high aspect ratio
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Embodiment 1
[0050] FEVE selects chlorotrifluoroethylene-alkyl vinyl ester, TDI is selected as the curing agent, and a super-hydrophobic electroactive coating with anti-pitting performance is prepared on the iron plate. The hydrophobicity of the coating is tested during the friction process. Anti-corrosion performance of coatings in alkali and high-concentration saline environments.
[0051] (1) Preparation of polyaniline / halloysite conductive composite
[0052] The halloysite nanotubes were ultrasonically dispersed in 0.5 mol / L sulfuric acid, and aniline monomer and ammonium persulfate initiator were added sequentially, in which the concentrations of aniline, ammonium persulfate and halloysite nanotubes were 1.86 g / L and 4.65 g / L, respectively. g / L and 0.4 g / L; after the mixed solution was stirred ultrasonically for 30 min, the chemical oxidation polymerization was carried out at 0-3 °C for 24 h.
[0053] Wash with deionized water and ethanol to remove unreacted aniline monomer and forme...
Embodiment 2
[0069] FEVE uses tetrafluoroethylene-alkyl vinyl ether copolymer, HDI trimer is used as the curing agent, and the super-hydrophobic electroactive anti-pitting corrosion coating is prepared on the aluminum plate.
[0070] Prepare coating according to the step of embodiment 1 and carry out performance test, and the difference with embodiment 1 is:
[0071] In step (1), the inorganic acid was phosphoric acid with a concentration of 0.4 mol / L, and the concentrations of aniline, ammonium persulfate and halloysite nanotubes were 2.79 g / L, 6.98 g / L and 1.12 g / L, respectively.
[0072] In step (2), the mass of halloysite nanotubes was 1.5 g, the amount of tetraethylorthosilicate was 18 mL, and the amount of perfluorodecyltriethoxysilicon was 2 mL.
[0073] In step (3), an 8 cm × 8 cm aluminum plate was selected and polished to the St3 standard with 360-mesh, 600-mesh and 1000-mesh sandpaper, respectively. After polishing, the samples were ultrasonicated with deionized water and ethan...
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