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Preparation technology of low-smoke and halogen-free ceramic polyolefin refractory insulation material

A ceramic polyolefin, refractory insulation technology, applied in the direction of insulators, organic insulators, plastic/resin/wax insulators, etc., can solve the problems of limited application range, unfavorable scale-up production, low production efficiency, etc., and achieve excellent mechanical properties, development The effect of low smoke volume and high bending strength

Inactive Publication Date: 2019-07-05
中广核高新核材科技(苏州)有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

At present, ceramic silicone rubber is more researched in ceramic polymer refractory materials, but the disadvantage of ceramic silicone rubber cable material is that when it is used, it needs to be extruded by a special rubber extruder, and it is also It needs to be vulcanized through the vulcanization process, so the process is relatively complicated and the scope of application is limited; if the cable material is made into a silicone rubber tape and wrapped outside the cable core during the wire and cable processing process, the production efficiency is low and the cost is high , not conducive to industrial scale-up production

Method used

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  • Preparation technology of low-smoke and halogen-free ceramic polyolefin refractory insulation material
  • Preparation technology of low-smoke and halogen-free ceramic polyolefin refractory insulation material

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Embodiment 1~4

[0021] Embodiments 1-4: A preparation process for low-smoke and halogen-free ceramic polyolefin refractory insulating material, comprising the following steps:

[0022] Step 1: 30-50 parts of metallocene polyethylene, 30-50 parts of ethylene-α-octene copolymer, 10-20 parts of high-density polyethylene resin, 5-10 parts of amorphous polyolefin grafted with maleic anhydride, Pentaerythritol 10~20 parts, boron carbide 6~13 parts, silicon carbide 16~23 parts, nano aluminum hydroxide 60~80 parts, brucite 20~30 parts, talcum powder 10~20 parts, antioxidant 0.5~2 0.5-2 parts of silane coupling agent, 2-4 parts of sodium dodecylbenzene sulfonate, 2-6 parts of lubricant silicone masterbatch, all put into the internal mixer for mixing at one time, and the temperature of the mixing material is Discharge at 140~145°C;

[0023] Step 2. Feed the material obtained in step 1 into the conical feeding hopper, and then pass through the twin-screw extruder unit for plasticizing and extruding. Se...

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Abstract

The invention discloses a preparation technology of a low-smoke and halogen-free ceramic polyolefin refractory insulation material. The technology includes the steps of: 1. putting metallocene polyethylene, an ethylene-alpha-octene copolymer, high density polyethylene resin, maleic anhydride grafted amorphous polyolefin, pentaerythritol, boron carbide, silicon carbide, nano-aluminum hydroxide, brucite, talcum powder, an antioxidant, a silane coupling agent, sodium dodecylbenzene sulfonate and lubricant silicone masterbatch all into an internal mixer at one time for mixing, and performing discharging when the temperature of the mixed materials reaches 140-145DEG C; and 2. sending the material obtained in step 1 into a tapered feeding hopper, and conducting plasticizing extrusion by a twin-screw extrusion set. The polyolefin refractory insulation material obtained by the technology provided by the invention has good ceramic performance, the sintered ceramic shell has high bending strength, the crust is very hard and dense, no secondary fire is caused, and the refractory insulation material can be fired into a hard ceramic armor to reach very good heat insulation, cooling and refractory effects, has low smoke during combustion, is halogen-free, non-toxic and odorless, and passes the ROHS inspection standards.

Description

technical field [0001] The invention relates to the technical field of polyolefin refractory insulating materials, in particular to a preparation process for low-smoke and halogen-free ceramic polyolefin refractory insulating materials. Background technique [0002] Ceramic polymer refractory material is a new type of composite material with refractory function made of polymer as the matrix and adding a certain proportion of ceramic powder, flux and other additives. The material has good softness and mechanical properties at normal temperature, and after being fired at high temperature, it will be transformed into a hard ceramic protective layer after being fired at high temperature, and the protective layer has certain mechanical strength. [0003] Although the research on this aspect at home and abroad can be traced back to the 1930s, it has been developing slowly. It was not until recent years that the research on ceramic refractory cables increased, and ceramic refractor...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/08C08L23/06C08L51/06C08L83/04C08K13/02C08K3/38C08K3/34C08K5/053C08K3/22C08K5/42H01B3/44
CPCC08K2003/222C08K2003/2227C08K2201/011C08L23/06C08L23/0815C08L2201/02C08L2201/22C08L2205/025C08L2205/035C08L2207/062H01B3/441C08L51/06C08L83/04C08K13/02C08K3/38C08K3/34C08K5/053C08K3/22C08K5/42
Inventor 张家宏单永东
Owner 中广核高新核材科技(苏州)有限公司
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