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Waterborne polyurethane emulsion, waterborne polyurethane cooling coating and preparation method

A water-based polyurethane and emulsion technology, applied in polyurea/polyurethane coatings, reflective/signal coatings, coatings, etc., can solve problems affecting performance, poor compressive strength, and polluting the environment, achieving low cost and excellent durability , good toughness

Pending Publication Date: 2019-06-28
CHONGQING JIAOTONG UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Acrylic adhesives have good acid resistance, water resistance and adhesion, but it is difficult to control the residual monomers of the reaction. Usually there will be some residual monomers. The residual monomers not only affect the performance but also pollute the environment, and the compressive strength is poor, which belongs to the brittle hard type. ;Epoxy coatings usually need to use diluent and curing agent. Commonly used diluents include hydrocarbons, aromatic hydrocarbons and esters, etc., and curing agents such as organic acids and fatty amines. Therefore, after 2-3 years of general use, a large area will fall off

Method used

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  • Waterborne polyurethane emulsion, waterborne polyurethane cooling coating and preparation method
  • Waterborne polyurethane emulsion, waterborne polyurethane cooling coating and preparation method
  • Waterborne polyurethane emulsion, waterborne polyurethane cooling coating and preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] Embodiment 1 synthetic aqueous polyurethane emulsion

[0017] Synthetic water-based polyurethane emulsion, the raw materials used and the proportion (by weight and number) are: 0.1-0.2 parts of dibutyltin dilaurate, 10-15 parts of polypropylene glycol, poly-1,4-butylene adipate 5-8 parts, 1.3-2 parts of 2,2-dimethylolpropionic acid, 10-15 parts of isophorone diisocyanate, 0.5-0.85 parts of pentaerythritol, 6-8 parts of acetone, 1,4-butanediol 1.5-2 parts, 0.8-1.2 parts of triethylamine, 1-2 parts of γ-aminopropyltriethoxysilane, 55-60 parts of water (deionized water).

[0018] The synthesis steps are as follows:

[0019] ① 2,2-Dimethylolpropionic acid and pentaerythritol were dehydrated under reduced pressure at 80°C for 2 hours.

[0020] ② Dry polypropylene glycol, dibutyltin dilaurate and poly-1,4-butylene adipate under reduced pressure at 120°C for 2 hours, cool down to 85°C, and add 2,2-dimethylol propionic acid , pentaerythritol and isophorone diisocyanate react...

Embodiment 2

[0036] Embodiment 2 prepares waterborne polyurethane cooling coating

[0037] Preparation of water-based polyurethane cooling coating, raw materials and proportioning (ratio by weight): 90-95 parts of water-based polyurethane emulsion prepared in Example 1, 0.1-0.5 part of ammonia water, 0-2 part of color paste, 0.1-0.5 part of dispersant, 4-6 parts of cooling reflective filler (obtained by mixing nano-titanium dioxide, matting powder, and silicon dioxide at a weight ratio of 8-13:4.5-7:3-5), 0.5-0.8 parts of defoamer, and 0.2 parts of thickener -0.4 parts, 0.5-1.5 parts of leveling agent, 5-10 parts of dipropylene glycol methyl ether.

[0038] The preparation steps are as follows:

[0039] 1) Add dispersant and part of defoamer to the water-based polyurethane emulsion prepared in Example 1 (when the total parts by weight of defoamer is 0.5-0.8 part, add 0.1-0.2 part of defoamer at this time), add ammonia, Adjust pH=7-8, stir at 400r / min for 20-30min;

[0040] 2) Increase t...

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PUM

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Abstract

The invention discloses a waterborne polyurethane emulsion and a preparation method. The waterborne polyurethane emulsion is prepared from the following components in parts by weight: 0.1-0.2 part ofdibutyltin dilaurate, 10-15 parts of polypropylene glycol 2000, 5-8 parts of polyadipic acid-1,4-butanediol ester, 1.3-2 parts of 2,2-dimethylolpropionic acid, 10-15 parts of isophorone diisocyanate,0.5-0.85 part of pentaerythritol, 6-8 parts of acetone, 1.5-2 parts of 1,4-butanediol, 0.8-1.2 parts of triethylamine, 1-2 parts of gamma- aminopropyltriethoxysilane and 55-60 parts of water. The invention also discloses a waterborne polyurethane cooling coating and a preparation method. The waterborne polyurethane cooling coating is prepared from the following components in parts by weight: 90-95parts of waterborne polyurethane emulsion, 0.1-0.5 part of ammonia water, 0-2 parts of color paste, 0.1-0.5 part of a dispersant, 4-6 parts of cooling reflective filler, 0.5-0.8 part of a defoamer, 0.2-0.4 part of a thickener, 0.5-1.5 parts of a flatting agent and 5-10 parts of dipropylene glycol monomethyl ether.

Description

technical field [0001] The invention relates to the technical field of road engineering, in particular to a water-based polyurethane emulsion, a water-based polyurethane cooling paint and a preparation method. Background technique [0002] With the acceleration of the urbanization process, the construction of urban road traffic has been continuously improved. However, a series of urban eco-environmental problems also appear in the process of urbanization, among which the urban heat island effect has become one of the most obvious urban eco-environmental problems. At present, extensive and massive research has been conducted on how to mitigate the urban heat island effect. In recent years, the research and development of cooling materials has also received more and more attention. Solar heat reflective coatings were first successfully developed by developed countries in western science and technology. In the late 1970s, some developed countries such as Japan, Western Europe...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G18/66C08G18/08C08G18/28C08G18/34C08G18/40C08G18/42C08G18/48C08G18/32C09D175/04C09D5/33
Inventor 曹雪娟伍燕唐伯明苗成成丁勇杰
Owner CHONGQING JIAOTONG UNIVERSITY
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