Waterborne polyurethane emulsion, waterborne polyurethane cooling coating and preparation method
A water-based polyurethane and emulsion technology, applied in polyurea/polyurethane coatings, reflective/signal coatings, coatings, etc., can solve problems affecting performance, poor compressive strength, and polluting the environment, achieving low cost and excellent durability , good toughness
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Embodiment 1
[0016] Embodiment 1 synthetic aqueous polyurethane emulsion
[0017] Synthetic water-based polyurethane emulsion, the raw materials used and the proportion (by weight and number) are: 0.1-0.2 parts of dibutyltin dilaurate, 10-15 parts of polypropylene glycol, poly-1,4-butylene adipate 5-8 parts, 1.3-2 parts of 2,2-dimethylolpropionic acid, 10-15 parts of isophorone diisocyanate, 0.5-0.85 parts of pentaerythritol, 6-8 parts of acetone, 1,4-butanediol 1.5-2 parts, 0.8-1.2 parts of triethylamine, 1-2 parts of γ-aminopropyltriethoxysilane, 55-60 parts of water (deionized water).
[0018] The synthesis steps are as follows:
[0019] ① 2,2-Dimethylolpropionic acid and pentaerythritol were dehydrated under reduced pressure at 80°C for 2 hours.
[0020] ② Dry polypropylene glycol, dibutyltin dilaurate and poly-1,4-butylene adipate under reduced pressure at 120°C for 2 hours, cool down to 85°C, and add 2,2-dimethylol propionic acid , pentaerythritol and isophorone diisocyanate react...
Embodiment 2
[0036] Embodiment 2 prepares waterborne polyurethane cooling coating
[0037] Preparation of water-based polyurethane cooling coating, raw materials and proportioning (ratio by weight): 90-95 parts of water-based polyurethane emulsion prepared in Example 1, 0.1-0.5 part of ammonia water, 0-2 part of color paste, 0.1-0.5 part of dispersant, 4-6 parts of cooling reflective filler (obtained by mixing nano-titanium dioxide, matting powder, and silicon dioxide at a weight ratio of 8-13:4.5-7:3-5), 0.5-0.8 parts of defoamer, and 0.2 parts of thickener -0.4 parts, 0.5-1.5 parts of leveling agent, 5-10 parts of dipropylene glycol methyl ether.
[0038] The preparation steps are as follows:
[0039] 1) Add dispersant and part of defoamer to the water-based polyurethane emulsion prepared in Example 1 (when the total parts by weight of defoamer is 0.5-0.8 part, add 0.1-0.2 part of defoamer at this time), add ammonia, Adjust pH=7-8, stir at 400r / min for 20-30min;
[0040] 2) Increase t...
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