Cationic dyeable copolyester
A copolyester, cationic technology, applied in the direction of single-component copolyester rayon, single-component polyester rayon, fiber chemical characteristics, etc., can solve the problem of polyester heat resistance deterioration, spinning nozzle gold Short replacement cycle, yellow color and other problems
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[0028] The preparation method of the cationic dyeable copolyester of the present invention includes esterification or transesterification reaction and polycondensation reaction.
[0029] The esterification reaction can be carried out while continuously adding the slurry of dibasic alcohol and dibasic carboxylic acid with a molar ratio of 1.1 to 2.5 in the esterification reaction tank in which the oligomer is pre-stored; It can be in the esterification reaction tank with the oligomer in advance, before the esterification reaction starts, after adding all the dibasic carboxylic acid and the dibasic alcohol, and then carrying out the esterification reaction; Acid and carboxylic acid are respectively added into the esterification tank, and the esterification reaction is carried out while stirring. The esterification reaction may not add a catalyst, or may add metal catalysts such as cobalt, magnesium, manganese, tin, and titanium.
[0030] In the transesterification reaction, the...
Embodiment 1
[0066] The slurry of 11.32kg terephthalic acid and 12.2kg 1,4-butanediol was subjected to esterification reaction in 500ppm tetrabutyl titanate and 500ppm n-butyl stannic acid catalyst, and after about 5 hours of reaction, the by-products were judged , when the esterification reaction rate reaches more than 97%, the prepared low molecular weight esterified product is moved into the polymerization kettle; the stabilizer phosphorus compound phosphoric acid 200ppm is added to the esterified product; wt% dimethyl isophthalate-5-sodium sulfonate (SIPM), bisphenol A polyoxyethylene ether (n+m=10 in formula 2) accounting for 8.0wt% of the total copolyester, catalyst titanium Acetate tetrabutyl ester (TBT) 500ppm, metal salt potassium acetate 1000ppm. Subsequently, the temperature was increased under reduced pressure at 250° C., and polymerization was carried out by conventional polyester polycondensation method to obtain a cationic dyeable copolymer. The physical properties are show...
Embodiment 2~4
[0068] Change the addition amount of dimethyl isophthalate-5-sodium sulfonate, others are the same as Example 1, and the results are shown in Table 1.
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