An environment-friendly iminodisuccinic acid chelated metal salt
一种亚氨基二琥珀酸、天冬氨酸盐的技术,应用在化肥,绿色化肥领域,能够解决氯离子腐蚀作用、有效成分含量降低、土壤板结等问题,达到有效成分含量高、原料利用率提高、生产工艺简单的效果
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[0028] The preparation method of metal chelate salt comprises the steps:
[0029] Add 0.8-1.2 molar parts of raw material A and 0.8-1.2 molar parts of raw material B into 20-25 molar parts of solvent, then slowly add 1-2 molar parts of raw material C and stir, and heat to 80-110 ℃, heating and reflux reaction under normal pressure for 25-40 hours, and cooling down to room temperature after the reaction, to prepare iminodisuccinic acid chelated metal salt.
[0030]The dissolving solvent is water, and auxiliary agents can be added when raw materials are added to the solvent, and the auxiliary agent types are any one of ammonia water, polysorbates, polyoxyethylene fatty acid esters, salicylic acid, cresol, and fatty acids. The mixture of one or more kinds promotes the dissolution of raw materials in the solvent, and the added amount of the auxiliary agent is 0.5-1.5% in mass fraction in the solvent.
Embodiment 1
[0032] An environment-friendly iminodisuccinic acid chelated metal salt, comprising the product of raw material A, raw material B and raw material C reaction, raw material A is maleic acid, raw material B is L-aspartic acid, raw material C is copper hydroxide.
[0033] The preparation method of metal chelate salt comprises the steps:
[0034] The raw material A of 0.8 molar part, the raw material B of 0.8 molar part are added in the water of 20 molar parts, then add ammoniacal liquor, the add-on of ammoniacal liquor is 0.5% of the mass fraction of water, then slowly add the copper hydroxide of 1 molar part and Stir, heat to 80°C after the raw materials are completely dissolved, heat and reflux under normal pressure for 25 hours, cool down to room temperature after the reaction, and prepare iminodisuccinic acid chelated metal salt.
[0035] The content of iminodisuccinic acid in the chelated metal salt of iminodisuccinic acid is 70%, and the content of copper ions is 15%.
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