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Antibacterial stain-resistant wood-plastic packaging material and preparation method thereof

A packaging material and wood-plastic technology, applied in the field of antibacterial and antifouling wood-plastic packaging materials and their preparation, can solve the problems of the beautiful appearance of the wood-plastic packaging material, the unreported antibacterial and antifouling ability, the poor antibacterial and antifouling ability, and the impact on product quality and performance, etc. problems, to achieve the effect of improving antibacterial and antifouling properties, improving mechanical properties, and closely fitting and falling off.

Inactive Publication Date: 2017-12-29
苏州卫刚木包装制品有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Wood-plastic packaging materials have been rapidly applied as new packaging materials, but nowadays wood-plastic packaging materials have not yet been reported in terms of aesthetics, antibacterial and antifouling, etc. Products that have been packaged for a long time will suffer if the packaging materials have poor antibacterial and antifouling capabilities. Affect the quality performance of the product, so it is necessary to develop a new type of wood-plastic packaging material

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] (1) Mix 50 parts of wood fiber, 35 parts of polypropylene PP, 5 parts of titanate coupling agent and 10 parts of ethyl acrylate, grind to 50 μm, then preheat to 110 ° C, and stir for 15 minutes;

[0022] (2) Then add 4 parts of attapulgite and 8 parts of nano-zirconia, and disperse ultrasonically for 20 minutes at a power of 3000W; then add 8 parts of octamethylcyclotetrasiloxane, preheat at 200°C, and press mold at 0.8MPa;

[0023] (3) In step (2), soak the surface of the molding material into 10% methanol solution of ethylene glycol dimethacrylate for 10 minutes; take it out and irradiate it under a UV lamp for 3 minutes; after the irradiation is completed, rinse it with methanol solution for 5 times to form material surface;

[0024] (4) Add the molding material obtained in step (3) into the solution with PH=3.2, add 5 parts of methyl methanesulfonate for reaction, and then wash it repeatedly with deionized water and methanol for 8 times;

[0025] (5) Crush the drie...

Embodiment 2

[0027] (1) Mix 60 parts of wood fiber, 40 parts of polypropylene PP, 10 parts of titanate coupling agent and 15 parts of ethyl acrylate, grind to 30 μm, then preheat to 130 ° C, and stir for 10 minutes;

[0028] (2) Then add 6 parts of attapulgite and 5 parts of nano-zirconia, and disperse ultrasonically for 20 minutes at a power of 3000W; then add 10 parts of octamethylcyclotetrasiloxane, preheat at 150°C, and press mold at 0.5MPa;

[0029] (3) In step (2), soak the surface of the molding material into 20% methanol solution of ethylene glycol dimethacrylate for 5 minutes; take it out and irradiate it under a UV lamp for 6 minutes; rinse it with methanol solution for 5 times to form material surface;

[0030] (4) Add the molding material obtained in step (3) into the solution of PH=4.5, add 10 parts of methyl methanesulfonate for reaction, and then wash it repeatedly with deionized water and methanol for 8 times;

[0031] (5) Crush the dried material into 150 mesh particles, ...

Embodiment 3

[0033] (1) Mix 55 parts of wood fiber, 38 parts of polypropylene PP, 10 parts of titanate coupling agent and 12 parts of ethyl acrylate, grind to 35 μm, then preheat to 115 ° C, and stir for 12 minutes;

[0034] (2) Then add 5 parts of attapulgite and 6 parts of nano-zirconia, and disperse ultrasonically for 20 minutes at a power of 3000W; then add 9 parts of octamethylcyclotetrasiloxane, preheat at 170°C, and press mold at 0.58MPa;

[0035] (3) In step (2), soak the surface of the molding material into a 13% methanol solution of ethylene glycol dimethacrylate for 6 minutes; take it out and irradiate it under a UV lamp for 4 minutes; rinse it with methanol solution for 5 times to form material surface;

[0036] (4) Add the molding material obtained in step (3) into the solution of PH=3.5, add 7 parts of methyl methanesulfonate for reaction, and then wash it repeatedly with deionized water and methanol for 8 times;

[0037] (5) Crush the dried material into 120 mesh particles,...

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Abstract

The invention discloses a preparation method of an antibacterial stain-resistant wood-plastic packaging material. The preparation method comprises the following steps: mixing wood fibers, polypropylene PP, a titanate coupling agent and ethyl acrylate, performing grinding, then pre-heating to 110-130 DEG C, and performing stirring for a reaction for 10-15 min; adding attapulgite and nano-zirconia, and performing ultrasonic dispersion; after that, adding octamethylcyclotetrasiloxane, performing preheating at 150-200 DEG C, and performing compression molding at 0.5-0.8 MPa; soaking the surface of the molded material in a methanol solution with 10-20% of ethylene glycol dimethacrylate for 5-10 min; taking out the molded material, and placing the molded material in an ultraviolet lamp to be irradiated for 3-6 min; after finish of irradiation, flushing and cleaning the surface of the molded material with a methanol water solution; adding the obtained molded material into a solution with the pH of 3.2-4.5, adding methyl methanesulfonate for a reaction, and performing repeated cleaning with deionized water and methanol; and crushing the dried material into particles, soaking the particles in the 10-15% methanol water solution for ultrasonic treatment, and performing pre-heating and mold pressing to obtain the antibacterial stain-resistant wood-plastic packaging material.

Description

technical field [0001] The invention belongs to the field of wood-plastic packaging materials, in particular to an antibacterial and anti-fouling wood-plastic packaging material and a preparation method thereof. Background technique [0002] Wood-plastic composite (WPC) is a new type of composite material that has been booming at home and abroad in recent years. It refers to the use of polyethylene (PE), polypropylene (PP) and polyvinyl chloride (PVC) to replace the usual resin adhesive, and more than More than 50% of wood flour, rice husk, straw and other waste plant fibers are mixed into new wood materials, and then processed by extrusion, molding, injection molding and other plastic processing techniques to produce boards or profiles. Mainly used in building materials, furniture, logistics packaging and other industries. The plastic and wood powder are mixed in a certain proportion and then extruded to form a board, which is called an extruded wood-plastic composite boar...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L97/02C08L23/12C08K13/02C08K5/10C08K5/101C08K3/34C08K3/22C08J7/12C08J7/18
CPCC08L97/02C08J7/12C08J7/18C08J2397/02C08J2423/12C08K2003/2244C08K2201/011C08L23/12C08K13/02C08K5/10C08K5/101C08K3/346C08K3/22
Inventor 张勤
Owner 苏州卫刚木包装制品有限公司
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