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Novel environmental protection TPU advertising cloth

An advertising cloth and environmental protection technology, applied in the field of advertising cloth, can solve the problem of insufficient comprehensive performance, and achieve the effect of diversified design, easy processing and beautiful design.

Inactive Publication Date: 2017-12-19
安徽嘉明新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Thermoplastic polyurethane elastomer (TPU) material is a kind of odorless and easy-to-process environmental protection material. It is mainly divided into polyester type and polyether type. TPU has excellent characteristics of high tension, high tension, toughness and aging resistance. Wide hardness range (60HA-85HD), wear-resistant, oil-resistant, transparent, good elasticity, widely used in daily necessities, sporting goods, toys, decorative materials and other fields, and can also replace PVC to meet environmental protection requirements in more and more fields. Although TPU material has obvious advantages over other materials in terms of performance, its comprehensive performance still cannot meet the needs of some occasions, and further improvement is needed to meet the needs of the market.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] (1) Preparation of modified ultraviolet absorber

[0021] Put 10g of 3,5-dihydroxy-6-(2,6-dihydroxyphenol)-1,2,4-triazine, 0.3g of kaolin, and 0.3g of talc into a ball mill, using ethanol as the medium, grind and mix thoroughly for 2h, Put it in a muffle furnace at 1000°C for 3 hours, then take it out as the furnace cools to obtain a modified UV absorber;

[0022] (2) The parts by weight of TPU coating are as follows: polyester thermoplastic polyurethane elastomer 50g, hexamethylene diisocyanate 6g, sodium carboxymethyl cellulose 12g, anatase nano titanium dioxide 6g, p-methoxy cinnamon 5 g of isooctyl acid, 8 g of modified UV absorber, 3 g of butyl reclaimed rubber, 3 g of paraffin oil, 0.5 g of zinc myristate, 5.5 g of butylene acetate, and 1 g of glycerol acetate. Through the laminating machine, pour 10g TPU coating liquid on both sides of 100g polyester filament mesh cloth.

Embodiment 2

[0024] (1) Preparation of modified ultraviolet absorber

[0025] Put 10g 3-mercapto-5,6-(2,6-dihydroxyphenol)-1,2,4-triazine, 0.2g kaolin, and 0.5g talc into a ball mill, using ethanol as the medium, grind and mix well for 2h, put Put it into the muffle furnace and keep it at 1000°C for 3 hours, then take it out as the furnace cools to get the modified UV absorber;

[0026] (2) The weight parts of TPU coating are as follows: polyether polyurethane elastomer 62g, isophorone diisocyanate 5g, sodium carboxymethyl cellulose 10g, anatase nano titanium dioxide 5g, p-methoxycinnamic acid 8 g of isooctyl ester, 3 g of modified UV absorber, 2 g of butyl reclaimed rubber, 2 g of paraffin oil, 0.5 g of zinc myristate, and 2.5 g of dipropyl carbonate. Through the laminating machine, pour 15g TPU coating liquid on both sides of 100g polyester filament mesh cloth.

Embodiment 3

[0028] (1) Preparation of modified ultraviolet absorber

[0029] Put 10g 3-mercapto-5,6-(2,6-dihydroxyphenol)-1,2,4-triazine, 0.2g kaolin, and 0.3g talc into a ball mill with ethanol as the medium, grind and mix well for 2h, put Put it into the muffle furnace and keep it at 1000°C for 3 hours, then take it out as the furnace cools to get the modified UV absorber;

[0030] (2) The parts by weight of the TPU coating are as follows: polyether polyurethane elastomer 55g, hexamethylene diisocyanate 4g, isophorone diisocyanate 5g, sodium carboxymethyl cellulose 10g, anatase nano titanium dioxide 5g, 5g isooctyl p-methoxycinnamate, 6g modified UV absorber, 2g butyl reclaimed rubber, 2g paraffin oil, 0.5g zinc myristate, 5.5g dipropyl carbonate. Pour 20g TPU coating solution on both sides of 100g polyester filament mesh cloth through the laminating machine.

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Abstract

The invention discloses a novel environmental protection TPU advertising cloth, which comprises a base cloth and TPU films at two sides of the base cloth. The TPU film comprises the following components in parts by weight: 50-65% of thermoplastic polyurethane, 5-10% of aliphatic diisocyanate, 10-20% of carboxymethylcellulose sodium, 5-10% of anatase-type nano titanium dioxide, 3-8% of a modified ultraviolet ray absorber, 2-5% of a butyl reclaimed rubber, 1-4% of paraffin oil, 0.5-1.2% of a flatting agent, and the balance of an environment-friendly solvent. The employed TPU material has the advantages of no odour, easy processing, and low cost, and is 100 percent recyclable, can substitute PVC, and can effectively improve the yellowing problem of the advertising cloth due to long-term irradiation; the employed modified ultraviolet ray absorber makes the ultraviolet ray transmittance being 5%, the used butyl reclaimed rubber has the efficacy for preventing shock and reducing noise, and is obtained by processing and refining the waste and old butyl rubber, the waste is used, and the used butyl reclaimed rubber has the advantages of economic performance and environmental protection; the polyester filament gridding cloth and a TPU film solution enable on-line applying through a lamination machine, and no glue is added.

Description

Technical field [0001] The invention relates to an advertising cloth, in particular to a new type of environmental protection TPU advertising cloth. Background technique [0002] The advertising industry has risen rapidly in the information age, and advertising cloths are everywhere in the streets and alleys. Generally, the use period of outdoor advertising ranges from a few days to a year or even longer. At present, most advertising cloths use polyvinyl chloride (PVC) coating. As a digital inkjet, PVC has bright color, corrosion resistance, strong durability, but poor thermal stability and light resistance. Hydrogen chloride will be decomposed when exposed to the sun for a long time above 100°C, and the hydrogen chloride released is toxic and Corrosive, the color of the degraded PVC becomes darker and the strength decreases. In addition, polyvinyl chloride easily penetrates into the fabric, the amount of coating is large, and the fabric is easy to be hard; the coated fabric is ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06N3/14D06N3/00
CPCD06N3/0036D06N3/0059D06N3/0063D06N3/0088D06N3/144D06N3/148D06N2209/025D06N2209/0838D06N2209/101D06N2209/16D06N2209/1635D06N2209/1678
Inventor 温同民刘磊李成
Owner 安徽嘉明新材料科技有限公司
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