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Lanthanum cerium iron alloy for producing rare earth steel and preparation method thereof

A ferroalloy and lanthanum-cerium technology, which is applied in the field of lanthanum-cerium-iron alloy for producing rare earth steel and its preparation, can solve the problems of high local concentration of rare earth metals, high smelting temperature requirements, affecting product consistency, etc., and achieves broad development and market prospects. The effect of high product quality and low cost

Inactive Publication Date: 2017-06-13
BAOTOU RES INST OF RARE EARTHS +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This method is the method commonly used at present, and its process technology is simple, can make multi-element master alloy or application alloy, but also has deficiency: 1) rare earth metal easily local concentration is too high in molten iron, produces segregation; 2) this method The raw materials used are rare earth metals, especially for medium and heavy rare earth metals, the preparation process is complicated and the cost is high; 3) The melting temperature is relatively high. Since rare earth metals and pure iron are used as raw materials, the melting temperature requirements are high
This method has low production cost and simple process, but it also has the following defects: the distribution of rare earth and iron in the alloy fluctuates greatly, it is difficult to control, and the distribution error is as high as 3%-5%, which affects product consistency

Method used

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  • Lanthanum cerium iron alloy for producing rare earth steel and preparation method thereof
  • Lanthanum cerium iron alloy for producing rare earth steel and preparation method thereof
  • Lanthanum cerium iron alloy for producing rare earth steel and preparation method thereof

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preparation example Construction

[0035] The preparation technology of the ferro-lanthanum cerium alloy for producing rare earth steel comprises the following steps:

[0036] Step 1: Graphite is used as the electrolytic cell, the graphite plate is used as the anode, the iron rod is used as the self-consumable cathode, and there is a receiver containing the alloy under the cathode;

[0037] The material of the receiver can be one of iron, rare earth oxide, and boron nitride.

[0038] Step 2: In the fluoride molten salt electrolyte system of lanthanum cerium fluoride (a mixture of lanthanum fluoride and lanthanum cerium fluoride) and lithium fluoride, using lanthanum cerium oxide (a mixture of lanthanum oxide and cerium oxide) as the electrolytic raw material, Passing direct current electrolysis to obtain lanthanum-cerium-iron master alloy;

[0039] Step 3: Using the lanthanum-cerium-iron master alloy and iron as raw materials, the lanthanum-cerium-iron alloy meeting the requirements is prepared by melting.

...

Embodiment 1

[0046] A Φ650mm circular graphite electrolytic cell is used. The anode is composed of four graphite plates. The lanthanum cerium fluoride in the electrolyte is 85wt%, and the lithium fluoride is 15wt%. The cathode is a pure iron rod with a diameter of 70mm. The average current intensity is 2800A. 0.5-1.0A / cm 2 , cathode current density 7-9A / cm 2, the electrolysis temperature is maintained at 900-1000 ° C, continuous electrolysis for 150 hours, 887 kg of lanthanum cerium oxide is consumed, and 864 kg of lanthanum cerium iron master alloy is obtained, the average lanthanum cerium content is 90%, the current efficiency is 90%, and the rare earth yield is 95%. The composition results are shown in Table 1.

[0047] Table 1 Analysis results of lanthanum-cerium-iron master alloy composition / wt%

[0048] RE Fe C O P S Si mn 90.0 9.85 0.0085 0.0094 <0.01 <0.005 0.012 <0.005

[0049] Using the lanthanum-cerium-iron master alloy prepared in this exam...

Embodiment 2

[0053] A Φ650mm circular graphite electrolytic cell is used. The anode is composed of four graphite plates. The lanthanum cerium fluoride in the electrolyte is 85wt%, and the lithium fluoride is 15wt%. The cathode is a pure iron rod with a diameter of 70mm. The average current intensity is 2800A. 0.5-1.0A / cm 2 , cathode current density 8-10A / cm 2 , the electrolysis temperature is maintained at 900-1000 ° C, continuous electrolysis for 150 hours, 887 kg of lanthanum cerium oxide is consumed, and 864 kg of lanthanum cerium iron master alloy is obtained, the average lanthanum cerium content is 95%, the current efficiency is 90%, and the rare earth yield is 95%. The composition results are shown in Table 3.

[0054] Table 3 lanthanum-cerium-iron master alloy composition analysis results / wt%

[0055] RE Fe C O P S Si mn 95.0 4.85 0.0085 0.0094 <0.01 <0.005 0.012 <0.005

[0056] Using the lanthanum-cerium-iron master alloy prepared in this examp...

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Abstract

The invention discloses a lanthanum-cerium ferroalloy for producing rare earth steel. The content of lanthanum-cerium is 0 to 95wt%, and the balance is iron and unavoidable impurities with a total amount less than 0.5wt%, in which oxygen ≤ 0.01wt%. Carbon ≤ 0.01wt%, phosphorus ≤ 0.01wt%, sulfur ≤ 0.005wt%. The invention also discloses a preparation method of lanthanum-ferrocerium alloy for producing rare earth steel. The lanthanum-ferrocerium alloy prepared by the invention has uniform composition, small segregation, low impurity content, high rare earth yield, low cost and no pollution. It can be applied to rare earth steel with high rare earth yield and significant effect, and is suitable for large-scale industrial production.

Description

technical field [0001] The invention relates to a rare-earth metal material, in particular to a lanthanum-cerium-iron alloy used for producing rare-earth steel and a preparation method thereof. Background technique [0002] At present, steel is the largest metal structural material and is widely used in construction, energy, transportation, aerospace and other fields. The application and research of rare earths in steel have also developed rapidly. The addition of rare earths to molten steel can desulfurize, deoxidize, change the shape of inclusions, etc., and can improve the plasticity, stamping performance, wear resistance and welding performance of steel. Various rare earth steels such as rare earth steel plates for automobiles, die steels, rails, etc. have been widely used. [0003] The addition method of rare earth in the production process of rare earth steel has always been the focus of scientific research. The existing addition methods include wire feeding method, c...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C35/00C22C33/06C25C3/34
CPCC22C35/00C22C33/06C25C3/34
Inventor 陈国华赵二雄刘玉宝张志宏吕卫东于雅樵张先恒苗旭晨杨鹏飞
Owner BAOTOU RES INST OF RARE EARTHS
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