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Anti-freeze self-cleaning type plastic plate and preparation method thereof

A plastic sheet, self-cleaning technology, applied in the sheet field, can solve the problems of poor storage stability of composite materials, complex preparation process, nanoparticle agglomeration, etc., and achieve the effect of preventing soft agglomeration, improving interface structure, and good photocatalytic ability

Inactive Publication Date: 2017-05-17
ANHUI BEIMA TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] However, due to the large specific surface area and high surface energy of nano-TiO2, which is in a non-thermodynamic stable state, the prepared composite materials are prone to the disadvantages of nanoparticle agglomeration, poor storage stability of the composite material, and complicated preparation process.

Method used

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Embodiment Construction

[0019] A kind of antifreeze self-cleaning plastic plate, it is made up of the raw material of following parts by weight:

[0020] Oleic acid amide 0.4, calcium phosphate 3, dibenzothiazole disulfide 0.6, titanium tetrachloride 10, ferric chloride 3.7, 25% hydrogen peroxide 6, methyl methacrylate 7, azobisisobutyronitrile 0.1 , polyvinyl chloride 100, silane coupling agent kh5600.7, glyceryl caprylate 1, ammonium chloride 0.6, maleic anhydride 1, ethylene glycol 2, sodium fluorosilicate 2.1, octamethylcyclotetrasilicon Oxane 0.7, montmorillonite powder 3.

[0021] A preparation method of the anti-freeze self-cleaning plastic plate, comprising the following steps:

[0022] (1) Add the above-mentioned sodium fluorosilicate to 37 times its weight in deionized water, stir evenly, raise the temperature to 58°C, keep stirring for 10 minutes, add the above-mentioned maleic anhydride, stir to room temperature, and add the concentration 30% sulfuric acid, adjust the pH to 2, stir and ...

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Abstract

The invention discloses an anti-freeze self-cleaning type plastic plate. The anti-freeze self-cleaning type plastic plate is prepared from the following raw materials in parts by weight: 0.4 to 1 part of oleamide, 3 to 4 parts of calcium phosphate, 0.6 to 1 part of bisbenzothiazole disulfide, 10 to 14 parts of titanium tetrachloride, 3.7 to 4 parts of ferric chloride, 6 to 8 parts of 25 to 30 percent of hydrogen peroxide, 7 to 9 parts of methyl methacrylate, 0.1 to 0.2 part of azodiisobutyronitrile, 100 to 130 parts of polyvinyl chloride, 0.7 to 1 part of silane coupling agent kh 5600, 1 to 3 parts of glyceryl caprylate-caprate, 0.6 to 2 parts of ammonium chloride, 1 to 1.5 parts of maleic anhydride, 2 to 3 parts of ethylene glycol, 2.1 to 3 parts of sodium fluosilicate, 0.7 to 1 part of octamethyl cyclotetrasiloxane and 3 to 4 parts of montmorillonite powder. According to the anti-freeze self-cleaning type plastic plate disclosed by the invention, added iron doped titanium dioxide has very good photocatalysis ability and is capable of degrading and removing pollutants attached to the surface of the anti-freeze self-cleaning type plastic plate, so that self-cleaning performance is realized.

Description

technical field [0001] The invention relates to the technical field of plates, in particular to a frost-resistant self-cleaning plastic plate and a preparation method thereof. Background technique [0002] Titanium dioxide is a transition metal oxide and also a semiconductor material. Due to its good biocompatibility, it can resist chemical corrosion and is harmless to the human body. At the same time, the rich content of titanium sources makes titanium dioxide rich in properties. And the price is low, so it has been widely concerned by people. The application of titanium dioxide is reflected in all aspects of people's life. At present, the use of inorganic products of titanium dioxide has reached the world's leading level. Due to the characteristics of titanium dioxide, it can be used as a very important inorganic chemical material, so it has great influence and application in many fields such as national defense and aviation, industrial production, and cutting-edge technol...

Claims

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Application Information

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IPC IPC(8): C08L27/06C08L51/10C08K13/06C08K9/04C08K3/34C08K5/47C08K5/20C08K5/053C08K3/32C08K5/549C08F292/00C08F220/14
CPCC08F292/00C08L27/06C08L2201/08C08L51/10C08K13/06C08K9/04C08K3/346C08K5/47C08K5/20C08K5/053C08K2003/325C08K5/549C08F220/14
Inventor 陈篯孙维乐
Owner ANHUI BEIMA TECH CO LTD
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