Graphene three-dimensional printing material with high bending strength
A bending strength, 3D printing technology, applied in the direction of additive processing, can solve the problems of tensile strength, bending strength, notched impact strength, low heat distortion temperature and melt index, etc., and achieve high bending strength and notched impact strength, The effect of high heat distortion temperature and melt index and low price
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[0076] The preparation method of the described graphene 3D printing material with high bending strength comprises the following steps:
[0077] S1: Purchase two-dimensional graphene raw materials on the market, and prepare primary graphene powder through special treatment;
[0078] S2: Use a hard plastic crusher to initially crush waste plastics, and then use an intermittent stirring plastic washing machine to thoroughly clean the crushed waste plastics to remove surface dirt. After natural drying and selection, selected plastics are obtained;
[0079] S3: Put the selected plastic prepared in step S2 in a nitrogen or dry ice low-temperature pulverizer, pulverize the plastic at a temperature of -90--110°C for 2-3 hours, and obtain 400-600 mesh plastic fine particles after sieving ;
[0080] S4: Add polylactic acid, potassium tripolyphosphate, ethylene glycol butyl ether acetate, and specific synthetic agents to the primary graphene powder prepared in step S1 and the plastic fi...
Embodiment 1
[0093] A graphene 3D printing material with high bending strength, in parts by weight, comprising the following raw materials: 6.6 parts of graphene, 28 parts of waste plastics, 38 parts of polylactic acid, 20 parts of potassium tripolyphosphate, ethylene glycol 24 parts of butyl ether acetate, 16 parts of specific synthetic agent, 8 parts of starch synthetic agent;
[0094] The specific synthetic agent is in parts by weight, including the following raw materials: 18 parts of regulator, 15 parts of generating agent, 13 parts of coupling agent a, 14 parts of compatibilizer, 10 parts of plasticizer, 8 parts of antioxidant, polymer 7 parts of coagulant, 4 parts of terminator, 3 parts of stabilizer a;
[0095] The regulator is ACR;
[0096] The generating agent is an aerosol generating agent;
[0097] The coupling agent a is a silane coupling agent KH550;
[0098] Described compatibilizer is maleic anhydride graft compatibilizer;
[0099] Described plasticizer is two (2-ethylh...
Embodiment 2
[0131] A graphene 3D printing material with high bending strength, in parts by weight, comprising the following raw materials: 5.3 parts of graphene, 26 parts of waste plastics, 34 parts of polylactic acid, 16 parts of potassium tripolyphosphate, ethylene glycol 21 parts of butyl ether acetate, 12 parts of specific synthetic agent, 6 parts of starch synthetic agent;
[0132] The specific synthetic agent is in parts by weight, including the following raw materials: 15 parts of regulator, 12 parts of generating agent, 10 parts of coupling agent a, 12 parts of compatibilizer, 9 parts of plasticizer, 6 parts of antioxidant, polymer 5 parts of coagulant, 3 parts of terminator, 2 parts of stabilizer a;
[0133] The regulator is ACR;
[0134] The generating agent is an aerosol generating agent;
[0135] The coupling agent a is a silane coupling agent KH550;
[0136] Described compatibilizer is maleic anhydride graft compatibilizer;
[0137] Described plasticizer is two (2-ethylhe...
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