Paper-plastic compound adhesive and preparation method thereof

A paper-plastic compounding and adhesive technology, applied in the direction of adhesive types, ester copolymer adhesives, etc., can solve the problems of poor stability, restrict the development of the packaging industry, low bonding strength, etc., achieve high stability, The effect of non-toxic triggering efficiency and bonding strength improvement

Active Publication Date: 2017-03-08
东莞市冠力胶业有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

With the continuous development of polymer synthetic materials, various paper-plastic composite glues continue to emerge, but most of these composite glues are thermal packaging glues, which often need to be heated when used, and there are toxic solvent residues, and the bonding strength is not high. The strength of paper-plastic composite packaging material is not enough
[0004] At present, the paper-plastic composite adhesives sold in the market have low bonding strength and poor stability, which seriously restricts the development of my country's packaging industry.

Method used

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  • Paper-plastic compound adhesive and preparation method thereof
  • Paper-plastic compound adhesive and preparation method thereof
  • Paper-plastic compound adhesive and preparation method thereof

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Effect test

Embodiment 1~3

[0035] Prepare paper-plastic composite adhesive, see Table 1 for specific components and contents, and the preparation method is as follows:

[0036] Step 1, pre-emulsification: add butyl acrylate, vinyl acetate, methyl methacrylate, acrylamide, methylene succinic acid, and deionized water to the pre-emulsification device to react to form a mixed solution according to the above mass percentage, and then Distill the mixed solution under reduced pressure and wash it with sodium hydroxide, and finally stir for 25-45 minutes to make the mixed solution appear uniform milky white to obtain a pre-emulsion; the pressure range of the reduced-pressure distillation is -0.04~-0.01MPa , The temperature range of vacuum distillation is 60~68℃.

[0037] Step 2, seed emulsion polymerization: add deionized water, emulsifier, protective colloid, neutralizer, buffer, cosolvent, and initiator accounting for 50% of the total amount of initiator in the reaction kettle in sequence, heat and stir, Wh...

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Abstract

The invention belongs to the technical field of adhesives and particularly relates to a paper-plastic compound adhesive. The paper-plastic compound adhesive is prepared from the following components in percentage by weight: 15%-35% of butyl acrylate, 10%-20% of vinyl acetate, 5%-10% of methyl methacrylate, 4%-10% of acrylamide, 1%-5% of methylene succinic acid, 0.1%-1% of sodium hydroxide, 20%-50% of deionized water, 0.2%-2% of an emulsifier, 0.5%-2% of an initiator, 1%-3% of a neutralizing agent and 0.05%-0.2% of aqueous ammonia. The invention further provides a preparation method of the paper-plastic compound adhesive. Compared with the prior art, on the one hand, the added initiator is non-toxic and high in initiation efficiency, and the added neutralizing agent has a relatively small effect on the system stability, so that the prepared adhesive has relatively high stability; on the other hand, the components in the adhesive cooperate with one another, and the adhesive strength of the adhesive is improved.

Description

technical field [0001] The invention belongs to the technical field of adhesives, in particular to a paper-plastic composite adhesive and a preparation method thereof. Background technique [0002] Paper-plastic composite is a layer of plastic film on the surface of paper-based printed matter. It is a commonly used composite material in the printing industry. It combines the advantages of paper and plastic. It is waterproof, durable and highly decorative, so that the text and patterns are effectively protected. . [0003] Adhesives are mainly made of bonding substances, and are formulated with various curing agents, plasticizers, fillers, solvents, preservatives, stabilizers and coupling agents. With the continuous development of polymer synthetic materials, various paper-plastic composite glues continue to emerge, but most of these composite glues are thermal packaging glues, which often need to be heated when used, and there are toxic solvent residues, and the bonding str...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J133/08C08F220/18C08F218/08C08F220/14C08F220/56
CPCC08F220/18C09J133/08C08F220/1804C08F218/08C08F220/14C08F220/56
Inventor 赵建国
Owner 东莞市冠力胶业有限公司
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