Glass-fiber-added composite absorbing material and preparation method thereof

An absorbing material and glass fiber technology, applied in the field of composite absorbing material added with glass fiber and its preparation, can solve the problems of unsuitable large-scale use, low oil-water selectivity, raw material source problems, etc., and achieve excellent oil absorption effect, excellent Mechanical oil retention effect, high absorption rate effect

Inactive Publication Date: 2017-02-08
苏州佰思科节能环保科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At first, people used porous materials such as sponge and clay to absorb oil, but the results were not satisfactory. This oil-absorbing material has obvious disadvantages: (1) the oil absorption is not large, and the oil absorption ratio is small; (2) the oil-water selectivity is not high, It often absorbs water while absorbing oil; (3) After oil absorption, the oil retention is poor, and it will leak oil again after a little pressurization
(4) The source of raw materials
[0004] However, the current high-resin oil-absorbing materials are often expensive and not suitable for large-scale use

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] Weigh 65 parts of polypropylene, 60 parts of trioctyl trimellitate, 35 parts of butyl acrylate, 20 parts of sodium carboxymethyl cellulose, 15 parts of polyoxyethylene laurate, and 12 parts of polybenzimidazole imide. Parts, 8 parts of 2-hydroxy-6-methylbenzoic acid, 7 parts of diphenylsilanediol, 6 parts of potassium persulfate, 5 parts of diatomaceous earth, 3 parts of alkali-free glass fiber, 3 parts of hydroxyaluminum distearate 2 parts, 2 parts of nano zinc oxide, 1 part of andalusite powder, 1 part of potassium salicylate, 4 parts of silane surface treatment agent, 4-6 parts of potassium carbonate.

[0023] (1) Mix and grind diatomite, alkali-free glass fiber, hydroxyaluminum distearate, nano-zinc oxide, andalusite powder for 3 hours until the particle size of all powders is less than 25 μm, and then add 10 times the mass of deionized water, stirred to obtain a mixed slurry, and then sintered into a block at a temperature of 800°C in an oxidizing atmosphere, and t...

Embodiment 2

[0029]Weigh 70 parts of polypropylene, 65 parts of trioctyl trimellitate, 40 parts of butyl acrylate, 25 parts of sodium carboxymethyl cellulose, 20 parts of polyoxyethylene laurate, and 14 parts of polybenzimidazole imide. Parts, 10 parts of 2-hydroxy-6-methylbenzoic acid, 8 parts of diphenylsilanediol, 7 parts of potassium persulfate, 7 parts of diatomaceous earth, 4 parts of alkali-free glass fiber, 4 parts of hydroxyaluminum distearate 3 parts, 3 parts of nano zinc oxide, 2 parts of andalusite powder, 2 parts of potassium salicylate, 5 parts of silane surface treatment agent, 5 parts of n-heptane.

[0030] (1) Mix and grind diatomite, alkali-free glass fiber, hydroxyaluminum distearate, nano-zinc oxide, andalusite powder for 4 hours until the particle size of all powders is less than 25 μm, and then add 10 times the mass of deionized water, stirred to obtain a mixed slurry, and then sintered into a block at a temperature of 1000 ° C in an oxidizing atmosphere, and then put...

Embodiment 3

[0036] Weigh 75 parts of polypropylene, 70 parts of trioctyl trimellitate, 45 parts of butyl acrylate, 30 parts of sodium carboxymethyl cellulose, 25 parts of polyoxyethylene laurate, and 16 parts of polybenzimidazole imide. Parts, 12 parts of 2-hydroxy-6-methylbenzoic acid, 9 parts of diphenylsilanediol, 8 parts of potassium persulfate, 9 parts of diatomaceous earth, 5 parts of alkali-free glass fiber, 5 parts of hydroxyaluminum distearate 4 parts, 4 parts of nano zinc oxide, 3 parts of andalusite powder, 3 parts of potassium salicylate, 6 parts of silane surface treatment agent, 6 parts of trichlorofluoromethane.

[0037] (1) Mix and grind diatomite, alkali-free glass fiber, hydroxyaluminum distearate, nano-zinc oxide, andalusite powder for 5 hours until the particle size of all powders is less than 25 μm, and then add 10 times the mass of deionized water, stirred to obtain a mixed slurry, and then sintered into a block at a temperature of 1200°C in an oxidizing atmosphere, ...

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PUM

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Abstract

The invention discloses a glass-fiber-added composite absorbing material and a preparation method thereof. The composite absorbing material is mainly prepared from polypropylene, trioctyl metabenzene tricarboxylate and butyl acrylate by adding sodium carboxymethyl cellulose, polyoxyethylene laurate, polybenzimidazole imide, 2-hydroxy-6-methyl benzoic acid, diphenyl silanediol, potassium persulfate, diatomite, alkali-free glass fiber, hydroxy aluminum distearate, nano zinc oxide, andalusite powder, potassium salicylate, a surface treating agent and a foaming agent. The preparation method comprises the following steps: grinding, sintering, ultrasonic treatment, polymerization, acid pickling, dry treatment, extrusion, foaming, granulation and the like. The glass-fiber-added composite absorbing material has the advantages of excellent oil absorbing effect for crude oil, excellent mechanical oil holding effect, favorable oil retaining effect and high absorption rate, can satisfy the requirements of industry, and has favorable application prospects.

Description

technical field [0001] The invention relates to the field of novel composite materials, in particular to a composite absorbent material added with glass fibers and a preparation method thereof. Background technique [0002] High oil-absorbing material is a kind of oil-absorbing material that appeared in the 1960s and developed rapidly in the past ten years. At first, due to the need of oil pollution control, researchers became interested in it. With the development of industry, the pollution caused by oily wastewater, liquid waste, and offshore oil spills can no longer be ignored. Failure to solve these problems will cause greater damage to the earth and human beings. Oil-absorbing resin is one of the important ways to help people solve this problem. The development of oil-absorbing materials has experienced a process of evolution from traditional to high-performance. At first, people used porous materials such as sponge and clay to absorb oil, but the results were not sa...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L33/08C08L79/08C08K13/04C08K7/14C08K3/34C08K5/12C08K5/13C08J9/08C08J9/14
CPCC08J9/08C08J9/141C08J9/144C08J2203/02C08J2203/14C08J2203/142C08J2323/12C08J2433/08C08L23/12C08L2203/14C08L2205/035C08L33/08C08L79/08C08K13/04C08K7/14C08K3/34C08K5/12C08K5/13
Inventor 费根华
Owner 苏州佰思科节能环保科技有限公司
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