Preparation method of hydrofining catalyst composition

Abstract

The invention discloses a preparation method of a hydrofining catalyst composition. The catalyst composition is a bulk phase hydrofining catalyst composition, and comprises hydrogenation active metal components W, Ni and MO, and alumina. The preparation method of the catalyst composition comprises the following steps: preparing a nickel and aluminum mixed precipitate through an ammonia distillation and precipitation technology in the presence of an organic compound, preparing a tungsten, molybdenum and aluminum mixed precipitate through a parallel flow precipitation technology, mixing the nickel and aluminum mixed precipitate with the tungsten, molybdenum and aluminum mixed precipitate, ageing the obtained mixture, carrying out hydrothermal treatment and adding urea, and molding the finally obtained mixture to prepare the catalyst composition. The catalyst composition prepared through the method is especially suitable for being applied to ultra deep hydrodesulfurization and nitrogen removal reactions of diesel oil fractions, and has high hydrodesulfurization and hydrodenitrogenation reaction performances.

Description

technical field [0001] The invention relates to a method for preparing a hydrorefining catalyst composition, in particular to a method for preparing a high-activity bulk phase hydrotreating catalyst composition. Background technique [0002] At present, in the world, crude oil is becoming increasingly heavy and inferior, coupled with the continuous development of the world economy and increasingly stringent environmental protection regulations, it is necessary to produce a large amount of light clean fuel. The development and use of ultra-low sulfur or even sulfur-free gasoline and diesel is the trend of clean fuel development in the world today. The use of traditional hydrodesulfurization catalysts can also achieve deep desulfurization or even ultra-deep desulfurization of diesel oil by increasing the severity of the reaction, such as increasing the reaction temperature, hydrogen partial pressure or reducing the reaction space velocity, but the increase in the reaction temp...

AI Technical Summary

Problems solved by technology

[0010] The bulk phase hydrogenation catalyst disclosed by CN102049265A adds ammonium bicarbonate during the coprecipitation process, and the bulk phase hydrogenation catalyst disclosed by CN102451703A adds carbon dioxide during the coprecipitation process to generate carbonate or bicarbonate. It releases a certain amount of gas during the roasting process. Under the impact of the gas, the pore volume and specific surface area of ​​the catalyst are increased, so that more metal active sites are exposed on the surface of the catalyst, but this method will cause some pores to collapse. , the pore distribution is dispersed, the mechanical strength is reduced, and the active metal is locally aggregated, and the exposed metal active sites are limited

The co-precipitation method adopted above will make the distribution of different hydrogenation active metals difficult to control, thereby affecting the distribution of different hydrogenation active metals and reducing the interaction between active metals. At the same time, the content of surface active metals in the catalyst is relatively low. Small and low active center density, which ultimately affects the ultra-deep hydrodesulfurization performance of the catalyst