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Inorganic flame retardant waterborne polyester coating and preparation method thereof

A flame retardant water-based polyester coating technology, used in polyurea/polyurethane coatings, antifouling/underwater coatings, fire-retardant coatings, etc. Significantly improve product performance and other issues, and achieve the effects of enhanced interaction force, improved heat resistance, and good gloss

Inactive Publication Date: 2016-11-09
ANHUI HEHAN OPTOELECTRONICS TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

As one of the important forestry biomass resources in my country, rosin has been studied by scholars to add it to the synthesis of polyurethane to improve the gloss and adhesion of polyurethane products, but they all directly add rosin to polyurethane, while Rosin is a mixture of various resin acids and its functionality is not high, so it cannot be added to the main chain of polyurethane, and the performance of the product cannot be significantly improved, and the characteristics of rosin cannot be fully utilized; rosin has high hardness, good heat resistance and insulation , anti-corrosion and other excellent properties, if it is introduced into polyurethane, it can overcome the shortcomings of conventional water-based polyurethane such as low hardness, poor heat resistance and water resistance
However, most of the predecessors directly used the mixture of rosin, and the structure of rosin can only be used as an end-capping agent to connect to the end of the molecular chain, so that the performance of rosin cannot be fully reflected;

Method used

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Embodiment Construction

[0018] A kind of inorganic flame-retardant water-based polyester coating, it is made up of the raw material of following weight part:

[0019] Zinc borate hydrate 2, rosin 35, fumaric acid 8, 20% sodium hydroxide solution 6, ethylene glycol 20, antimony trioxide 0.1, sodium polyacrylate 2, zinc chloride 13, polyether glycol 80, toluene Diisocyanate 100, 2,2 dimethylol propionic acid 2, diethylene glycol 4, triethylamine 1, 2-mercaptobenzimidazole 0.2, talcum powder 1, ammonium polyphosphate 3, triisopropanolamine 1, epoxy Octyl stearate 0.1, lauryl dimethyl amine oxide 0.3, calcium stearate 1, polyvinyl butyral 1.7.

[0020] A kind of preparation method of described inorganic flame retardant water-based polyester paint, comprises the following steps;

[0021] (1) Add the above-mentioned calcium stearate to 70% ethanol solution 20 times its weight, raise the temperature to 87°C, add 20% of the above-mentioned rosin weight, keep stirring for 10 minutes, add the above-mentioned ...

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Abstract

The invention discloses an inorganic flame retardant waterborne polyester coating, which comprises the following raw materials in parts by weight: 2-3 parts of hydrated zinc borate, 35-40 parts of rosin, 8-10 parts of fumaric acid, 6-7 parts of 20-30% of sodium hydroxide solution, 20-34 parts of ethylene glycol, 0.1-0.2 part of antimony trioxide, 2-3 parts of sodium polyacrylate, 13-20 parts of zinc chloride, 80-90 parts of polyether diol, 100-130 parts of toluene diisocyanate, 2-3 parts of 2,2-dimethylol propionic acid, 4-5 parts of diethylene glycol, 1-2 parts of triethylamine, 0.2-0.4 parts of 2-mercaptobenzimidazole, 1-2 parts of talcum powder, 3-4 parts of ammonium polyphosphate, 1-2 parts of triisopropanolamine, 0.1-0.4 parts of 2-ethylhexyl epoxystearate, 0.3-1 part of lauryl dimethyl amine oxide, 1-2 parts of calcium stearate, and 1.7-2 parts of polyvinyl butyral. The hydrated zinc borate and the like are added, so that the flame retardant property of the finished coating film product can be effectively improved.

Description

technical field [0001] The invention relates to the technical field of polyester coatings, in particular to an inorganic flame-retardant water-based polyester coating and a preparation method thereof. Background technique [0002] At present, although the commonly used water-based polyurethane materials are widely used in coatings, adhesives and other industries due to their environmental friendliness, conventional water-based polyurethane materials still have shortcomings such as poor heat resistance, weather resistance, and poor antistatic properties, which affect In order to better improve the overall performance of water-based polyurethane coatings, overcome its own shortcomings such as poor water resistance and low solid content, and expand its application range, the modification of water-based polyurethane has become a major research topic in recent years. Hotspots, the depth and breadth of discussions have also been expanded. The modification of waterborne polyuretha...

Claims

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Application Information

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IPC IPC(8): C09D175/14C09D5/14C09D5/18C09D7/12C08G18/68C08G18/66C08G18/48C08G18/32C08G18/34C08G18/12C08G63/553
CPCC09D175/14C08G18/0823C08G18/12C08G18/3206C08G18/348C08G18/4825C08G18/6692C08G18/686C08G63/553C08K2201/011C08L2201/08C08L2205/03C09D5/14C09D5/18C09D7/61C09D7/65
Inventor 夏云
Owner ANHUI HEHAN OPTOELECTRONICS TECH
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