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Composite molybdenum wire used for linear cutting and manufacturing method

A manufacturing method and technology for compounding molybdenum, which are applied in electrode manufacturing, manufacturing tools, electric processing equipment, etc., can solve the problems of abnormal wire breakage of wire cutting molybdenum wire, uneven use effect, low strength of pure molybdenum wire, etc. Abnormal wire breakage, improved A rate, good diameter uniformity

Active Publication Date: 2016-07-20
XIAMEN HONGLU TUNGSTEN MOLYBDENUM IND CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, most of the grades of wire cutting molybdenum wire in the domestic market are pure molybdenum metal, and the use effect in wire cutting processing is uneven. , broken wire and other problems; some manufacturers add rare earth oxide 2500ppm ~ 5000ppm La in molybdenum 2 o 3 , Y 2 o 3 etc., by adding La 2 o 3 , Y 2 o 3 The strength of molybdenum wire can be improved by achieving dispersion strengthening; in order to reduce costs and improve production efficiency, our company has introduced large rolling mill technology, which has a large deformation rate and rolls molybdenum billets from Φ50mm-Φ75mm to Φ4mm-Φ8mm Molybdenum wire rod, but with La 2 o 3 , Y 2 o 3 When the content of rare earth oxides increases to more than 5000ppm, the crack rate will continue to rise, resulting in a low A material rate, and a high crack rate will easily lead to abnormal broken wires during the use of wire-cut molybdenum wire, and short cutting life.

Method used

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  • Composite molybdenum wire used for linear cutting and manufacturing method
  • Composite molybdenum wire used for linear cutting and manufacturing method
  • Composite molybdenum wire used for linear cutting and manufacturing method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] Embodiment 1: Doping 0-3000ppm La in molybdenum powder 2 o 3 .

[0034] Solid-liquid doping is carried out in the molybdenum dioxide stage, doped with 0-3000ppm La 2 o 3 . The raw material ammonium molybdate is calcined at 400°C to obtain molybdenum trioxide, the molybdenum trioxide is reduced by hydrogen to obtain molybdenum dioxide, and the solid-liquid doping is carried out by solid molybdenum dioxide and liquid lanthanum nitrate to obtain a compound containing La 2 o 3 The doped molybdenum dioxide is then reduced by hydrogen to obtain the doped molybdenum powder containing lanthanum oxide. Finally, the doped molybdenum powder is mixed with a three-dimensional mixer and mixed uniformly; the particle size of the doped molybdenum powder is controlled at 3.0μm; put the doped molybdenum powder into the rubber sleeve, press it into a Φ50mm molybdenum billet by isostatic pressing, the molding pressure is 150MPa, the pressure holding time is 120 seconds, and then sinte...

Embodiment 2

[0035] Embodiment 2: Doping 100ppm~3000ppm Co and 1200ppm La in molybdenum powder 2 o 3 .

[0036] Solid-liquid doping in molybdenum dioxide stage, doping 100ppm ~ 3000ppm Co and 1200ppm La 2 o 3 . The raw material ammonium molybdate is calcined at 400°C to obtain molybdenum trioxide, the molybdenum trioxide is reduced by hydrogen to obtain molybdenum dioxide, and solid-liquid doping is carried out by solid molybdenum dioxide and liquid lanthanum nitrate to obtain a 2 o 3 Doped molybdenum dioxide, which is then reduced by hydrogen to obtain doped molybdenum powder containing lanthanum oxide, solid-liquid doping is performed again by using solid molybdenum powder doped with lanthanum oxide and liquid cobalt nitrate to dope cobalt, Then, the molybdenum powder that has been mixed with lanthanum oxide and cobalt is reduced by hydrogen again to obtain molybdenum powder doped with lanthanum oxide and cobalt. Finally, the molybdenum powder is mixed by a three-dimensional mixer t...

Embodiment 3

[0039] Embodiment three: Doping 200ppm, 800ppm Co and 2000ppm La in molybdenum powder 2 o 3 .

[0040] The difference between the third embodiment and the second embodiment is: doping 200ppm, 800ppm Co and 2000ppm La 2 o 3 , and the rest of the steps are the same to serve as a comparison example. La 2 o 3 The contents of Co and Co are shown in the test plans 11 and 12 of the attached table 1, and the evaluation effect of the molybdenum wire is shown in the comprehensive evaluation table of the doping test of the test plans 11 and 12 of the attached table 2.

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Abstract

The invention discloses a composite molybdenum wire used for linear cutting and a manufacturing method. The composite molybdenum wire is made of molybdenum powder containing solid solution metal elements and rare earth oxide. The solid solution metal elements are selected from at least one of Co, W, Ni, Hf or Re, and the weight content of the solid solution metal elements is 0.01%-0.30%. The rare earth oxide is selected from at least one of La2O3 or Y2O3, and the weight content of the rare earth oxide is 0.005%-0.20%. The manufacturing method comprises the following steps that secondary solid-liquid mixing is conducted, and uniform mixed molybdenum powder is obtained; then a molybdenum rod billet is obtained through pressing; the sintered molybdenum rod billet is rolled into a molybdenum coil rod; then the composite molybdenum wire used for linear cutting is obtained through drawing by repeatedly conducting a hot draw technique and a cold draw technique; and annealing is conducted repeatedly in the process, and the composite molybdenum wire is obtained. According to the composite molybdenum wire used for linear cutting, the abrasion resistance can be substantially improved, the service life is longer during cutting, the cutting speed is higher, and the rate of finished products is larger.

Description

technical field [0001] The invention relates to a molybdenum wire for wire-cutting used for fast wire-running and intermediate wire-running, in particular to a molybdenum wire for wire-cutting with doping and composite strengthening and a manufacturing method thereof. Background technique [0002] The electrode wire for wire electric discharge cutting is mainly molybdenum wire. Molybdenum wire is an ideal electrode wire for wire electric discharge cutting machine tools. It can cut various steel materials and hard alloys, and process parts with extremely complicated shapes. To improve the precision of the mold. It is usually selected as an ideal electrode tool for high-speed WEDM processing due to its advantages of low price, good toughness, high strength, good electrical conductivity and low elongation. [0003] At present, most of the grades of wire cutting molybdenum wire in the domestic market are pure molybdenum metal, and the use effect in wire cutting processing is un...

Claims

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Application Information

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IPC IPC(8): B23H1/06B23H1/04B23H7/22B23H7/24
CPCB23H1/04B23H1/06B23H7/22B23H7/24
Inventor 彭福生凌诚育蔡协勇兰康升宋久鹏潘小峰杨天明林志华李凤金庄骏张国钦王平张龙水曾飞
Owner XIAMEN HONGLU TUNGSTEN MOLYBDENUM IND CO LTD
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