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Graphene polymer energy-saving environment-friendly composite coating as well as preparation technology and application thereof

A graphene and polymer technology, applied in coatings, epoxy resin coatings, anti-corrosion coatings, etc., can solve problems such as poor mechanical properties, and achieve the effects of light weight, improved material appearance, and low viscosity

Active Publication Date: 2016-06-01
田路兵
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the high content of functional groups in graphite oxide, although it is helpful for the combination between the two, its mechanical properties are worse than those of graphene.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0050] Prepare the following ingredients in parts by weight:

[0051] 40 parts of base resin, including 10 parts of phenolic resin and 30 parts of BPF;

[0052] 1 part graphene;

[0053] 30 parts of composite modifiers, including 1 part of γ-glycidyl etheroxypropyl trimethoxysilane, 1 part of defoamer, 1 part of nano-silicon, 0.5 parts of leveling agent, 0.2 parts of talc powder, hollow silicon dioxide 15 parts of balls, 5 parts of mica powder, 5 parts of PTFE powder, 0.8 parts of UV absorber, 0.5 parts of antioxidant;

[0054] 20 parts of curing agent;

[0055] 1) Heat the phenolic resin to 60°C, stir and add bisphenol F resin, and continue stirring for 10 minutes;

[0056] 2) Add defoamer and stir for 10 minutes;

[0057] 3) add graphene, stir and drop into pretreatment agent;

[0058] 4) Add PTFE powder, silica hollow spheres, mica powder, talcum powder, leveling agent, nano-silicon, and cut for 5 minutes;

[0059] 5) Add UV absorber and antioxidant in sequence and st...

Embodiment 2

[0062] Prepare the following ingredients in parts by weight:

[0063] 60 parts of base resin, including 20 parts of phenolic resin and 40 parts of BPF;

[0064] 1.5 parts of graphene;

[0065] 55 parts of composite modifiers, including 3 parts of γ-glycidyl etheroxypropyl trimethoxysilane, 1 part of defoamer, 5 parts of nano-silicon, 1 part of leveling agent, 3 parts of talc powder, hollow silicon dioxide 20 parts of balls, 10 parts of mica powder, 10 parts of PTFE powder, 1 part of UV absorber, 1 part of antioxidant;

[0066] 45 parts of curing agent;

[0067] 1) Heat the phenolic resin to 80°C, stir and add bisphenol F resin, and continue stirring for 15 minutes;

[0068] 2) Add defoamer and stir for 15 minutes;

[0069] 3) add graphene, stir and drop into pretreatment agent;

[0070] 4) Add PTFE powder, hollow silicon dioxide spheres, mica powder, talc powder, leveling agent, nano-silicon, and cut for 15 minutes;

[0071] 5) Add UV absorber and antioxidant in sequence...

Embodiment 3

[0074] Prepare the following ingredients in parts by weight:

[0075] 50 parts of base resin, including 20 parts of phenolic resin and 30 parts of BPF;

[0076] 1.5 parts of graphene;

[0077] 34 parts of composite modifiers, including 1 part of γ-glycidyl etheroxypropyl trimethoxysilane, 1 part of defoamer, 1 part of nano-silicon, 0.2 parts of leveling agent, 0.4 parts of talc powder, hollow silicon dioxide 20 parts of balls, 5 parts of mica powder, 5 parts of PTFE powder, 0.2 parts of UV absorber, 0.2 parts of antioxidant;

[0078] 40 parts of curing agent;

[0079] 1) Heat the phenolic resin to 70°C, stir and add bisphenol F resin, and continue stirring for 10 minutes;

[0080] 2) Add defoamer and stir for 10 minutes;

[0081] 3) add graphene, stir and drop into pretreatment agent;

[0082] 4) Add PTFE powder, hollow silicon dioxide spheres, mica powder, talc powder, leveling agent, nano-silicon, and cut for 15 minutes;

[0083] 5) Add UV absorber and antioxidant in s...

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Abstract

The invention provides a graphene polymer composite organic coating which is mainly prepared from the following components in parts by weight: 40-60 parts of base resin, 1-1.5 parts of graphene, 30-55 parts of composite modifier and 20-45 parts of curing agent, wherein the base resin comprises phenol-formaldehyde resin and bisphenol F in a weight ratio of (1:2)-(1:4). The invention also provides a preparation method of the composite organic coating. The preparation method comprises the following steps: heating the phenol-formaldehyde resin, stirring and adding the bisphenol F resin; adding an antifoaming agent; adding graphene, stirring and dropwise adding a pretreating agent; adding polytetrafluoroethylene powder, silicon dioxide hollow spheres, mica powder, talc powder, a leveling agent and nano silicon; adding an ultraviolet absorbent and an antioxidant while keeping the system temperature below 60 DEG C to obtain modified resin; and mixing the modified resin with the curing agent and stirring to obtain the composite organic coating. The invention also provides an application of the organic coating.

Description

technical field [0001] The invention relates to the field of chemical industry, in particular to a graphene polymer energy-saving and environment-friendly composite material coating and its preparation process and application. Background technique [0002] Pumps are general-purpose machinery that are widely used. Whether it is in the military industry, nuclear power, industry, or civilian fields, pumps are almost always working wherever there is liquid flow. The pump is also a large energy consumer. The electricity consumption of the pump is about 25-27% of the country's total power generation, and the fuel consumption is 6-8% of the country's total fuel consumption. The motor with about 45% capacity is used to drive the pump. [0003] However, in reality, due to the restriction of the pump manufacturing process level, the efficiency of the pump is generally low; at the same time, due to the influence of the use environment (such as various corrosion, cavitation, abrasion, e...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D163/00C09D161/06C09D7/12C09D5/08
CPCC08K2201/011C08K2201/014C08L2201/08C08L2205/035C09D5/08C09D5/18C09D7/61C09D7/63C09D7/65C09D7/70C09D163/00C08L61/06C08L27/18C08L83/12C08K13/04C08K3/04C08K2003/023C08K7/26C08K3/34C08K5/5435
Inventor 田路兵
Owner 田路兵
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