Nanowire intermediate band solar cell structure based on butterfly-shaped plasmon antenna enhancement

A technology of solar cells and plasmons, applied in the field of solar cells, can solve the problems of low absorption efficiency and low density of solar cells in the middle band, etc., and achieve enhanced light absorption efficiency, improved photoelectric conversion efficiency, and improved absorption and overall photoelectric conversion. The effect of efficiency

Inactive Publication Date: 2016-05-11
NANJING UNIV
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Problems solved by technology

[0005] The object of the present invention is to propose a nanowire mid-band solar cell structure based on a butterfly plasmon enhanced antenna, which solves the problem that the mid-band solar cell has a low density of states in the mid-band and low absorption efficiency. The development of high-efficiency solar cells has laid a solid foundation, and it is expected to realize the development of next-generation solar cells in the direction of high efficiency and low cost

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Embodiment Construction

[0025] The present invention proposes a nanowire mid-band solar cell structure based on a butterfly plasmon enhanced antenna. The present invention is further described below through specific process steps and accompanying drawings:

[0026] (1) Oxygen-doped ZnTe / ZnO core-shell nanowire structure is prepared by physical vapor deposition method, and transferred by mechanical method to make it lie flat on a silicon dioxide or quartz substrate. The nanowire length of p-type oxygen-doped zinc telluride / n-type zinc oxide core-shell structure is 1-10um, the diameter of zinc telluride nanowire is 200-400nm, and the oxygen diffusion doping concentration in zinc telluride is 1-5 %, the thickness of zinc oxide is 5-40nm;

[0027] (2) Spin-coat photoresist on the substrate surface containing nanowires, the photoresist adopts positive resist;

[0028] (3) Utilize electron beam exposure and development to form a pattern of symmetrical tip-to-tip triangular pyramid periodic arrays on both ...

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Abstract

The invention discloses a nanowire intermediate band solar cell structure based on a butterfly-shaped plasmon enhancement antenna. A flat oxygen doped zinc telluride / zinc oxide core shell structure nanowire is arranged on a silicon dioxide or quartz substrate. The zinc oxide is arranged on an outer layer. A nanowire length of the oxygen doped zinc telluride / zinc oxide core shell structure is 1-10 micron. A diameter of the core shell structure nanowire is 200-400 nm. A thickness of the zinc oxide is 5-40 nm. Two sides of the core shell structure nanowire are provided with several pairs of metal-aluminum butterfly-shaped antennas. Each pair of the metal-aluminum butterfly-shaped antennas is a tip-to-tip triangular pyramid structure. In each pair of the butterfly-shaped antennas, the two tip-to-tip triangular pyramids can be centrosymmetric relative to the nanowire and can be non-centrosymmetrical. Problems that a state density of an intermediate band of an intermediate band solar cell absorption layer is small and absorption efficiency is low are mainly solved, sunlight full spectrum absorption is enhanced and overall photoelectric conversion efficiency of a device is increased.

Description

technical field [0001] The invention specifically relates to a nanowire solar cell structure and a preparation method thereof, belonging to the technical field of solar cells. Background technique [0002] Solar cells are photoelectric devices that convert solar energy into electrical energy by using the photovoltaic effect of photovoltaic semiconductor materials, and have been widely used in production and life. Existing solar cells are generally made of ultra-pure monocrystalline silicon wafers, and the thickness of this very expensive material is required to be about 200um to absorb as much sunlight as possible, which makes the manufacturing process of silicon-based flat-panel solar cells very difficult. It is complicated, consumes a lot of energy, and costs high. Compared with traditional solar cells, nanowire concentrating solar cells have several advantages: they are more capable of separating and focusing charges, and they can be made of abundant and cheap materials....

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L31/04H01L31/0236B82Y30/00
CPCY02E10/50H01L31/04B82Y30/00H01L31/0236
Inventor 叶建东聂奎营任芳芳李靖刘松民朱顺明汤琨顾书林
Owner NANJING UNIV
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