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Catalyst raw material for coal catalytic gasification and application method thereof

A technology of coal catalytic gasification and application method, applied in the field of coal chemical industry, can solve the problems of low catalyst cost, large thermal energy consumption, secondary pollution, etc., and achieve the effects of improving gasification reaction rate, increasing gas production, and reducing energy consumption

Active Publication Date: 2017-12-29
杨秋良
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

It mainly includes potassium-containing biomass ash, industrial waste lye, industrial waste solid alkali, pyrite slag, converter red mud, etc. The cost of disposable catalyst is low, but due to the large amount of consumption and large heat energy consumption, the ash is alkaline and easy to cause Secondary pollution
[0006] At present, the difficulty of coal catalytic technology lies in the development of high-efficiency catalysts for coal gasification, the price and recovery of catalysts, and the problems that the currently developed catalysts are prone to secondary pollution, which has always restricted the industrialization process of coal catalytic gasification.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] Use a φ50cm×80cm seamless steel pipe to weld the test device (equivalent to the conventional first section), heat it with silicon carbide rods, add refractory bricks to the outer wall to keep it warm, and use temperature controllers to measure and control the temperature in the furnace and the test device respectively. , control the furnace temperature at 800°C, the bottom of the device is welded and closed with an iron plate, the upper part of the device is connected and closed with an iron plate and a flange, the upper iron plate is installed with a thermocouple for temperature measurement, and a pressure gauge is installed on the upper electric plate to control the reaction pressure. CO 2 The bottom of the pipe insert is connected with the gas distributor, the gas external pipe is connected with the industrial CO 2 connected to the cylinder, with CO 2 Pressure gauges and gauges control its dosage. The CO discharge pipe is connected to the water cooler. After coolin...

Embodiment 2

[0032] Use pulverized coal with a water content of 8.5%, fixed carbon of 72.32%, volatile value of 14.88%, ash content of 12.8%, and sulfur of 1.80%. Add 1.9kg of vanadium pentoxide and 0.85kg of industrial lime. 5% on a dry basis, mixed evenly with pulverized coal, pressed into φ20mm pellets, and added to a φ50cm×80cm test device, including 50kg of pulverized coal, CO 2 The supply volume is 20L / min, and the CO concentration is monitored with a CO monitor. Start supplying CO 2 +O 2 , with O 2 The gas supply controls the furnace temperature. When the temperature in the test device rises to 400°C, the CO concentration is 600PPm, which can be ignited. The main component of the gas is volatile gas of coal; when the temperature rises to 500°C, the CO concentration is 2000PPm. It can be ignited, and the main component of its gas is volatile gas of coal; when the temperature is 600°C, the concentration of CO is 4000PPm, and there is no volatile gas of coal; when the temperature is...

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Abstract

The invention relates to a catalyst raw material for coal catalytic gasification and its application method. Reaction Quantitative Mixing Configuration. The effects of the present invention are as follows: 1. Coal gasification can be completed under low temperature conditions, and there are no strict requirements on the manufacturing materials of the equipment. It can be made of ordinary steel, which reduces the manufacturing cost of the equipment; 2. Improves the gasification reaction rate and increases the unit time. 3. Using carbon dioxide + oxygen as a gasification agent to catalyze the conversion of carbon dioxide into combustible gas carbon monoxide can save more than 35% of coal and reduce carbon dioxide emissions by more than 35% under the same thermal energy conditions; 4. Carbon dioxide + oxygen + water vapor can be used as the gasification agent to produce synthesis gas containing hydrogen and methane according to the requirements of the gas composition in the subsequent process, and carbon dioxide + oxygen can also be used to produce high-concentration carbon monoxide gas.

Description

technical field [0001] The invention belongs to the field of coal chemical industry, and in particular relates to a catalyst raw material for coal catalytic gasification and an application method thereof. Background technique [0002] The catalytic gasification of coal is carried out in the solid state of coal. The catalyst and coal powder are uniformly mixed together according to a certain proportion. Good contact and speed up the reaction rate, compared with the traditional coal gasification, the catalytic gasification of coal can significantly reduce the reaction temperature, increase the reaction rate, and improve the gas composition. The coal gasification catalysts currently researched and developed include: [0003] 1) Monomer metal salt or oxide catalyst: K 2 CO 3 It is the only coal catalytic gasification catalyst for industrial application at present, with K 2 CO 3 As a catalyst, the preparation method is simple and the stability is good, but K 2 CO 3 As a ca...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J23/22B01J23/847B01J23/34C10J3/46C10J3/54
CPCY02P20/52
Inventor 杨秋良
Owner 杨秋良
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