A kind of electrochemical capacitor and electroadsorption desalination electrode material
An electrode material and capacitor technology, which is used in the manufacture of hybrid capacitor electrodes and hybrid/electric double layer capacitors, can solve the problems of serious self-discharge of electrochemical capacitors, large electrode energy loss, and unfavorable industrial applications, and achieves electro-adsorption of inorganic salts. Excellent ionic performance, strong electrical conductivity, good charge-discharge repeatability
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Embodiment 1
[0020] A kind of electrochemical capacitor electrode material, its preparation steps are as follows:
[0021] 1. Preparation of nickel salt solution: add a protective agent with a concentration of 10 to 50 g / l into the nickel salt solution with a concentration of 0.5 to 2.5 mol / l;
[0022] 2. Mixing: put 10-20g / l carbon nanotubes and 75-200 g / l urea into the above-mentioned nickel salt solution, first stir at room temperature for 2 hours, then stir magnetically at 80°C for 1-6 hours;
[0023] 3. Preparation of nano-nickel oxide powder: suction filter and wash the precipitate produced in step 2 until neutral, put it in an oven and dry it at 100°C, and calcinate the obtained product at 300-500°C for 4-5 hours to obtain nano-nickel oxide powder. Carbon tube loaded nano-nickel oxide powder;
[0024] 4. Electrode preparation: uniformly mix the carbon nanotube-loaded nano-nickel oxide powder and PTFE emulsion at a mass ratio of 95:5 to 70:30, set the temperature at 100°C, and dry f...
Embodiment 2
[0029] Weigh 500g of nickel chloride hexahydrate, dissolve 400g of sodium dodecyl sulfonate in deionized water, and prepare 10L of nickel salt solution, add 2Kg of graphene at 60°C and stir for 6h, then add 30L of absolute ethanol, drop in 2mol / l sodium hydroxide solution, after suction filtration and drying, the resulting product was calcined at 500°C for 5 hours to obtain graphene-supported nano-nickel oxide. The graphene-loaded nano-nickel oxide powder and phenolic resin were evenly mixed in a mass ratio of 80:20, and pressed under a pressure of 20Mpa to form a graphene-loaded nano-nickel oxide electrode. The obtained electrode is bonded to the current collector, and the glass fiber is used as a separator. The desalination research is carried out on a sodium chloride solution with a concentration of 1000mg / L. The desalination rate can reach more than 96%, which fully meets the national drinking water concentration standard.
Embodiment 3
[0031] Weigh 10 grams of nickel nitrate hexahydrate, dissolve 10 grams of sodium dodecyl sulfonate in deionized water, and prepare 200 ml of nickel salt solution, add 5 grams of graphene and 10 grams of multi-walled carbon nanotube composite material at 50° C. and stir for 4 hours, then Add 500ml of absolute ethanol, drop in 2mol / l sodium hydroxide solution, suction filter and dry, and calcinate the obtained product at 450°C for 3h to obtain a graphene / nano-nickel oxide / carbon nanotube sample. Graphene / nano-nickel oxide / carbon nanotube powder and phenolic resin are uniformly mixed in a mass ratio of 80:20, and pressed under a pressure of 20Mpa to form a graphene / nano-nickel oxide / carbon nanotube electrode. The electrodes obtained in 10 groups were bonded to the current collector, and the glass fiber was used as a separator to conduct desalination research on a sodium chloride solution with a concentration of 800mg / L. The desalination rate can reach more than 98%, which fully me...
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