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Low/high-heat-resistant ABS resin and preparation method thereof

An ABS resin, heat-resistant technology, applied in the field of preparation of modified ABS resin, can solve the problems of not meeting the application requirements of heat-resistant ABS resin, unsatisfactory thermal deformation temperature, and reduced impact strength, and achieves outstanding heat-resistant effect and fluidity. The effect of better sexuality and maintenance of physical properties

Inactive Publication Date: 2015-07-01
NANJING JINSHAN AUTOMOBILE ENG PLASTIC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The following two modification methods are usually used to improve the heat resistance of ABS resin. One is to add inorganic rigid thermal fillers to ABS resin by filling modification method, which can improve the heat resistance of ABS resin. The commonly used fillers are mica powder, Talc powder, glass fiber, and glass microspheres, etc., filled with modified ABS resin have the disadvantages of decreased impact strength and rough surface while increasing the heat distortion temperature, which cannot meet the application requirements of heat-resistant ABS resin.
[0005] The other is the blending modification of SA nitrogen resin to achieve the purpose of improving the heat resistance of ABS resin. This method is to increase the content of acrylonitrile in the resin system to improve the heat resistance of the resin, although the mechanical properties of the resin are guaranteed. , but the increased heat deflection temperature is not ideal

Method used

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  • Low/high-heat-resistant ABS resin and preparation method thereof
  • Low/high-heat-resistant ABS resin and preparation method thereof
  • Low/high-heat-resistant ABS resin and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] (1) Process formula

[0024]

[0025] (2) Processing technology

[0026] Mix 85 parts by mass of ABS resin, 5 parts by mass of SBS thermoplastic elastomer, 10 parts by mass of styrene-nitrogen-phenylmaleimide copolymer, and 0.3 parts by mass of antioxidant in a high-speed mixer at 80-90°C 5 minutes, and then extrude and granulate on the twin-screw extruder. The temperature of the extruder is: 220°C for the first interval, 225°C for the second and third intervals, 230°C for the fourth, fifth, sixth, seventh, and eighth intervals, and 225°C for the ninth interval. ℃, extruded and made into strips, according to GB / T9341-2000 to test bending properties, GB / T1843-1996 to test impact properties, GB1040-92 to test tensile properties, GB / T3682-2000 to test melt flow rate, GB / T1633-2000 test heat distortion temperature.

[0027] According to this process, high heat-resistant ABS resin is obtained. Its performance is shown in Table 3.

Embodiment 2

[0029] Process recipe

[0030]

[0031] The above formula is molded according to the processing technology of Example 1 to obtain high heat-resistant ABS resin. Its performance is shown in Table 1, 2, 3.

Embodiment 3

[0033] Process recipe

[0034]

[0035] The above formula is molded according to the processing technology of Example 1 to obtain high heat-resistant ABS resin. Its performance is shown in Table 3.

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Abstract

The invention relates to low / high-heat-resistant ABS resin and a preparation method thereof and belongs to a high molecular material modification processing technology. The invention provides the preparation method of the low / high-heat-resistant ABS resin, which enables ABS resin to have high heat resistance and simultaneously keeps favorable mechanical properties. The low / high-heat-resistant ABS resin comprises the following components in parts by mass: 50-85 parts of ABS resin, 5-20 parts of SBS thermoplastic elastomer, 10-45 parts of a styrene-nitrogen-phenyl maleimide copolymer and 0.2-0.4 part of an antioxidant. The components are blended and extruded to prepare the modified ABS resin which has high heat resistance and favorable mechanical properties and can be widely used as a material for automobiles and electric products.

Description

1. Technical field: [0001] The invention relates to a preparation method of a modified ABS resin, in particular to a low-high heat-resistant ABS resin. 2. Background technology: [0002] ABS resin (acrylonitrile-styrene-butadiene copolymer) is currently the largest and most widely used polymer, with excellent comprehensive properties, excellent impact strength, good dimensional stability, electrical properties, wear resistance It is widely used in auto parts (dashboards, tool hatches, wheel covers, mirror boxes, etc.), high-strength tools (vacuum cleaners, hair dryers, etc.) , mixers, lawn mowers, etc.), typewriter keyboards, recreational vehicles such as golf carts and jet skis, etc., with the increase in the scope of application, not only ABS resin is required to have good mechanical properties, but also to have certain Some excellent properties, such as: high heat resistance, flame retardancy, transparency, high elastic modulus and other characteristics. [0003] Due to...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L55/02C08L53/02C08L25/08
Inventor 牛建勋沈玉海于翠翠吴锡忠
Owner NANJING JINSHAN AUTOMOBILE ENG PLASTIC
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