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Nanocarbon material-based high-performance heat conducting material and preparation method thereof

A technology of thermally conductive materials and carbon nanomaterials, which is applied in the field of high-performance thermally conductive material preparation, can solve the problems of low thermal conductivity, high filling amount of thermally conductive fillers, and high manufacturing costs, so as to improve thermal conductivity, thermal conductivity, and thermal conductivity. Effect

Inactive Publication Date: 2015-03-25
广州索润科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Traditional heat-conducting parts are usually made of metal materials such as copper, iron and other alloys, and metal parts have disadvantages such as difficulty in processing and forming, high quality, and high cost and manufacturing costs; and because polymer materials are easy to form and process, Therefore, the research of using polymer heat-conducting composite materials instead of metal to prepare heat-dissipating products has attracted more and more attention. For example, in the invention patent CN102250481A, a crystalline resin matrix is ​​used, and at the same time, it is filled with an inorganic filler whose thermal conductivity is 10 to 1000 times higher than that of the matrix resin. And the selection of appropriate particle size to achieve less filler filling and higher thermal conductivity
However, the existing polymer thermally conductive composite materials generally have disadvantages such as low thermal conductivity, high thermal conductive filler filling, high material specificity, and high price, which restricts the wide application of polymer-based high-performance thermally conductive materials.

Method used

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  • Nanocarbon material-based high-performance heat conducting material and preparation method thereof
  • Nanocarbon material-based high-performance heat conducting material and preparation method thereof
  • Nanocarbon material-based high-performance heat conducting material and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0023] (1) Surface treatment of thermally conductive fillers: use a plasma activator (plasma cleaning experimental equipment EPT-02, produced by Suzhou Opus Plasma Technology Co., Ltd.; the same below.) to activate nano-diamonds by irradiation to clean the surface and activate at the same time Its surface site; use acetone to disperse the silane coupling agent and dry process the graphene nanosheet for 1 hour;

[0024] (2) Preparation of mixed thermally conductive filler: 10g of silicon-containing esterified wax and 10g of nano-diamonds are mixed in a high-speed mixer, and then the mixture is mixed with 5g of graphene nanosheets in a high-speed mixer. Mix high thermal conductivity filler.

[0025] (3) Preparation of high thermal conductivity resin: Premix 75g of nylon-66 resin and 25g of high thermal conductivity filler prepared in the above steps, and pass through a twin-screw extruder (model SHJ-36, Nanjing Jieya Extrusion Co., Ltd.) at 260°C Equipment Co., Ltd.; the same b...

Embodiment 2

[0029] (1) Surface treatment of thermally conductive fillers: use a plasma activator (plasma cleaning experimental equipment EPT-02, produced by Suzhou Opus Plasma Technology Co., Ltd.; the same below.) to activate nano-diamonds by irradiation to clean the surface and activate at the same time Its surface site; use acetone to disperse silane coupling agent and dry process graphene nanosheet for 1.5 hours;

[0030] (2) Preparation of mixed thermally conductive filler: 10g of silicon-containing esterified wax and 9g of nano-diamonds are mixed in a high-speed mixer, and then the mixture is mixed with 6g of graphene nanosheets in a high-speed mixer. Mix high thermal conductivity filler.

[0031] (3) Preparation of high thermal conductivity resin: Premix 75g of nylon-66 resin and 25g of high thermal conductivity filler prepared in the above steps, and pass through a twin-screw extruder (model SHJ-36, Nanjing Jieya Extrusion Co., Ltd.) at 260°C Equipment Co., Ltd.; the same below.)...

Embodiment 3

[0035] (1) Surface treatment of thermally conductive fillers: use a plasma activator (plasma cleaning experimental equipment EPT-02, produced by Suzhou Opus Plasma Technology Co., Ltd.; the same below.) to activate nano-diamonds by irradiation to clean the surface and activate at the same time Its surface site; use acetone to disperse the silane coupling agent and dry process the graphene nanosheet for 2 hours;

[0036] (2) Preparation of mixed thermally conductive filler: 10g of silicon-containing esterified wax and 8g of nano-diamonds are mixed in a high-speed mixer, and then the mixture is mixed with 7g of graphene nanosheets in a high-speed mixer. Mix high thermal conductivity filler.

[0037] (3) Preparation of high thermal conductivity resin: Premix 70g of nylon-66 resin and 25g of high thermal conductivity filler prepared in the above steps, and pass through a twin-screw extruder (model SHJ-36, Nanjing Jieya Extrusion Co., Ltd.) at 260°C Equipment Co., Ltd.; the same b...

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Abstract

The invention discloses a nanocarbon material-based high-performance heat conducting material and a preparation method thereof. The preparation method comprises the following steps: mixing nanodiamond with graphine nanoply as a heat conducting filler, pretreating the heat conducting filler, constructing a filler network by utilizing the esterified nanodiamond coated graphine nanoply mixture in a polymer matrix, performing 'forced parallel connection' to form mutual contact and further form a heat conducting channel so as to realize better dispersion of the nanodiamond and graphine nanoply in a composite material. Heat conducting powder enters into the polymer matrix in a dispersing manner to forcibly form a mutually connected heat conducting channel network, heat is efficiently conducted through the shaking transfer of the heat conducting filler, the formed heat conducting network does not pass through the hollow part and is guided out directly from the heat conducting powder, so that the heat conducting efficiency is greatly improved. The prepared high heat conducting material can be used for forming heat radiation parts of various electrical appliances and automobiles, and has larger practical application values.

Description

technical field [0001] The invention belongs to the technical field of preparation of high-performance heat-conducting materials, and in particular relates to a polymer-based heat-conducting material based on nano-carbon materials and a manufacturing method thereof. Background technique [0002] Metal materials are thermally conductive materials in the traditional concept, but with the advancement of polymer science and technology, polymer materials have also become a new role in the field of thermal conductivity, which subverts the traditional concept of thermal insulation of polymer materials. Traditional heat-conducting parts are usually made of metal materials such as copper, iron and other alloys, and metal parts have disadvantages such as difficulty in processing and molding, high quality, etc., and high cost and manufacturing costs; and because polymer materials are easy to form and process, Therefore, the research of using polymer heat-conducting composite materials ...

Claims

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Application Information

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IPC IPC(8): C08L77/06C08K9/10C08K3/04C08K9/00C08K9/06B29C45/78C09K5/14
CPCC08K9/10B29C45/78C08K3/04C08K9/06C09K5/14
Inventor 林志丹徐保峰
Owner 广州索润科技股份有限公司
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