Super-high thermal conductivity and low thermal expansivity diamond composite material and preparation method thereof
A low thermal expansion coefficient, composite material technology, applied in the field of high-performance electronic packaging functional materials, can solve problems such as poor surface finish, surface finish requirements require plating or polishing, etc., to achieve weight reduction, good heat dissipation, and improved thermal conductivity Effect
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Embodiment 1
[0023] Raw materials: diamond powder particles with a particle size of 50-60 μm and pure copper blocks (industrial pure copper, purity > 99.5%).
[0024] Put the diamond powder of the above particle size into a metal cup, and put a pure copper sheet on the diamond powder. The metal cup filled with materials is then put on two metal cups in opposite directions. Then put the assembled kit into a vacuum furnace at 550°C, 5×10 -2 Vacuum treatment was carried out under vacuum for 2 hours. Then put the assembly kit into the equipment for high-pressure synthesis, and carry out ultra-high-pressure infiltration sintering. The sintering process is as follows: the temperature is raised to about 1100°C and a pressure of 5.3GPa is applied, and the temperature is kept for 10 minutes, and the sintering is completed. After cooling, take out the sample, remove the mold, cut off the remaining copper infiltrated, and process the sample into the required size (φ10×3mm), that is, the diamond / Cu ...
Embodiment 2
[0026] Raw materials: diamond particles and pure copper blocks with a particle size of 180-212 μm.
[0027] The diamond raw material powder with the above-mentioned particle size and the copper sheet are assembled into a kit for ultra-high pressure infiltration sintering. The specific process is the same as that of Experiment 1. The prepared diamond / Cu composite has a thermal conductivity of 683W / mK and a density of 3.96g / cm 3 , The coefficient of thermal expansion is 2.31ppm / K.
Embodiment 3
[0029] Raw materials: diamond particles and pure copper blocks with a particle size of 500-600 μm.
[0030] The diamond raw material powder with the above-mentioned particle size and pure copper sheet were assembled into a kit for ultra-high pressure infiltration and sintering. The specific process was the same as that in Experiment 1. The prepared diamond / Cu composite has a thermal conductivity of 717W / mK and a density of 3.91g / cm 3 , The coefficient of thermal expansion is 2.16ppm / K.
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