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Making method of artificial red coral bead string

A coral and artificial technology, applied in the field of preparation of red coral beads, can solve the problems of complicated preparation process, high cost, and slag drop, and achieve the effects of simple preparation process, long service life and short production cycle

Inactive Publication Date: 2015-02-25
YANSHAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] First, it is prone to fading and slag when used for a long time
[0007] Second, the mechanical mixing in the production process is uneven, and it is easy to agglomerate, resulting in uneven color of the final product
[0008] Third, the preparation process is complicated, the equipment requirements are high, the cost is high, and it is not suitable for large-scale production

Method used

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  • Making method of artificial red coral bead string
  • Making method of artificial red coral bead string
  • Making method of artificial red coral bead string

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] 10mM CaCl 2 1000L and 1M MgCl 2 40L was poured into the reactor, then 208g of polyacrylic acid with a molecular weight of 20k was added, the reactor was covered and reacted at room temperature for 3 days, then centrifugally dried to obtain pure high-magnesium calcite powder. Weigh again 15g of strontium carbonate powder and 1260g of the high-magnesium calcite powder prepared above are added to 40L of industrial water together, 60g of FeCl 2 Dissolve in 20L of industrial water, mechanically stir for 1 hour respectively, then mix and stir the above two solutions for 2 hours, add 100ml of ammonia water, mix and sonicate for 20 minutes, pour into a 100L autoclave and react at 200°C for 12 hours, then centrifuge and dry. Get Red Coral Powder (eg figure 1 shown); Stir 150g of unsaturated polyester crystal resin, 1350g of the above-mentioned red coral powder, 12g of cyclohexanone peroxide and 12g of cobalt naphthenate at a stirring speed of 500r / min for 4h; pour the mixed ...

Embodiment 2

[0030] 10mM CaCl 2 1000L and 1M MgCl 2 50L was poured into the reactor, then 144g of polyaspartic acid with a molecular weight of 13.7k was added, the reactor was covered and reacted at room temperature for 3 days, and then centrifuged and dried to obtain pure high-magnesium calcite powder. Then weigh 22.5g of strontium carbonate powder and 555g of the above-mentioned high-magnesium calcite powder and add them to 40L of industrial water, 60g of FeCl 2 Dissolve in 20L of industrial water, mechanically stir for 1 hour, then mix and stir the two solutions for 3 hours, add 100ml of ammonia water, mix and sonicate for 20 minutes, pour into a 100L autoclave and react at 180°C for 18 hours, then centrifuge and dry. Get Red Coral Powder (eg figure 2 shown); Stir 97.5g of unsaturated polyester crystal resin, 652.5g of the above-mentioned red coral powder, 4.5g of cyclohexanone peroxide and 4.5g of cobalt naphthenate at a stirring speed of 800r / min for 5h; The slurry is poured int...

Embodiment 3

[0032] 10mM CaCl 2 1000L and 1M MgCl 2 50L was poured into the reactor, then 210g of polyacrylic acid with a molecular weight of 20k was added, the reactor was covered and reacted at room temperature for 4 days, then centrifugally dried to obtain pure high-magnesium calcite powder. Weigh again 18.75g of strontium carbonate powder and 225g of the above-prepared high-magnesium calcite powder are added to 40L of industrial water, 60g of FeCl 2 Dissolve in 20L of industrial water, mechanically stir for 2 hours respectively, then mix and stir the two solutions for 4 hours, add 100ml of ammonia water, mix and sonicate for 20 minutes, pour into a 100L autoclave and react at 200°C for 24 hours, and then centrifuge and dry to obtain red Coral powder; Stir 56.25g of unsaturated polyester crystal resin, 318.75g of red coral powder, 2.6g of cyclohexanone peroxide and 2.6g of cobalt naphthenate at a stirring speed of 1000r / min for 6h; put the mixed slurry Pour into bead-shaped fibergla...

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Abstract

An artificial red coral bead string mainly comprises 5-20wt% of iron oxide red, 1-5wt% of strontium carbonate, 10-15wt% of unsaturated polyester crystal resin, and the balance of high magnesian calcite. A making method of the artificial red coral bead string comprises the following steps: carrying out a reaction on CaCl2, MgCl2, polyacrylic acid or polyaspartic acid in a reactor for 3-4d, centrifuging, and drying to obtain high magnesian calcite powder; respectively stirring strontium carbonate powder, the high magnesian calcite powder and FeCl2 in water, mixing the above obtained solutions for 2-4h, adding ammonia water, carrying out ultrasonic treatment for 20min, reacting in an autoclave at 160-200DEG C for 12-24h, and centrifuging to obtain red coral powder; mixing the unsaturated polyester crystal resin with the red coral powder, a curing agent and an accelerant for 4-6h; and casting, grinding, polishing, and oiling to obtain the artificial red coral bead string. The making method has the advantages of simplicity, simple equipment, short production period and easy mass production, and the artificial red coral bead string made in the invention has the characteristics of uniform color, brilliant shining and fine texture.

Description

technical field [0001] The invention belongs to the field of handicrafts, in particular to a preparation method of red coral beads. Background technique [0002] In 1988, the red coral was listed as one of the first-level national key protected wild animals. Red coral grows in the deep sea of ​​100 to 2000 meters away from humans. Natural red coral is formed by the accumulation of coral polyps. It grows extremely slowly (one inch takes 20 to 30 years, and one kilogram takes three hundred years) and cannot be regenerated. The growth conditions of red coral are extremely harsh, and they can only survive in clean seawater with stable ocean currents and moderate sunshine between south and north latitudes of 30 degrees. It requires deep water, slow water, no disturbance of wind and waves, no difference between cold and heat, and the annual temperature is almost constant at 10°C, so red corals are extremely rare. Red corals in the world are mainly distributed in the Mediterranea...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B26/18C04B14/28
CPCC04B26/18C04B2111/542C04B14/28C04B14/26C04B14/308C04B24/008C04B24/04
Inventor 彭秋明吴文诗李慧
Owner YANSHAN UNIV
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