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Waste pyrolysis system with adjustable oil, gas and carbon and method

A waste and pyrolysis technology, applied in the field of waste resource treatment, can solve problems such as low calorific value, inability to effectively control quality, and inability to improve the quality of recovered oil, so as to achieve the effect of improving quality

Active Publication Date: 2014-10-08
上海济德能源环保技术有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the existing technology can neither effectively control the quality of the three products of oil, gas, and charcoal (that is, residual coke) at a certain pyrolysis temperature, that is, under the condition of a fixed pyrolysis temperature; Conditions to improve the quality of the recovered oil, such as the application of the invention "a pyrolysis gasification device for polymer waste (CN201320126288)" uses a catalyst to improve the quality of the oil, but the catalyst life and regeneration involved are important issues, not only affecting Economy, also affects the continuity and stability of operation
When the pyrolysis temperature is changed, the output and quality of oil, gas, and charcoal are linked according to a certain rule, and cannot be adjusted according to needs. The calorific value in charcoal is transferred to oil or gas. The invention patent "High and Low Temperature Coupling Pyrolysis Method for Sludge or Organic Garbage" (CN200910198391) provides a way to send partially carbonized materials produced by low temperature cracking in the first step into A system and method for carbonizing in a medium-temperature carbonization furnace, and further sending a mixture of part of the medium-temperature carbonized material and other wastes into a high-temperature pyrolysis furnace for gasification to obtain various solid carbonization products and gas, but the system and method cannot produce high quality oil
[0003] In view of the fact that the existing pyrolysis technology and system cannot meet the requirements of adjusting product quality economically and efficiently, in order to realize the adjustable quality of oil, gas and charcoal more economically, safely and efficiently; the present invention proposes an efficient, economical and scalable Steady operation, catalyst-free waste pyrolysis system and method to ensure recovery of high-quality oil and gas from different wastes, while charcoal remains low in calorific value, but can still be used as a raw material for building materials

Method used

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Embodiment 1

[0060] figure 2 A specific optimized implementation of the system and method provided by the present invention is shown. The system of this specific embodiment includes waste feed 1, feeder 2, pre-reaction section 3, pre-reacted material 4, main reactor 5, residual coke 6, conditioner 7, volatile matter 8, after conditioning Volatile matter 9, particle separator 10, residual coke after conditioning 11, clean volatile matter 12, gas scrubber 13, circulating gas 14, inert gas 15, combustion furnace 16, flue gas 17, circulating gas heater 18 and Combustible gas19.

[0061] In the system of this specific embodiment, by setting up corresponding pipeline connections, the purpose of quality adjustment of waste pyrolysis products oil, gas, and carbon can be realized in the following operation mode:

[0062] The waste 1 has a moisture content of 0-42% after preliminary pretreatment, and is fed to the pre-reaction section 3 by the feeder 2; then the pre-reacted material 4 is sent to ...

Embodiment 2

[0065] After the domestic waste in a county-level city is separated from wet components and sand by drum sieving1, the moisture content is 30%, the dry plastic content is 28%, and other components are waste paper, cloth, vegetation and branches, as shown in Table 1 :

[0066] Table 1 Composition of dry waste after dry and wet separation of waste in a certain city through a drum sieve

[0067] components percentage moisture content waste plastic 40% 30% the fabric 12% 32% Coarse food waste and vegetation 13% 35% paper 20% 30.02% Other residue 15% 24.00% total 100% 30% Chlorine content 1.6% Low calorific value on dry basis 15.664KJ / kg

[0068] When using the existing technology for processing, the garbage 1 in Table 1 is preheated or directly enters the main reactor 5 without preheating. When the working temperature of the main reactor 5 is 500 ° C, the volatile matter coming out of the main reactor 5...

Embodiment 3

[0072] A project deals with waste plastics separated from domestic waste and paper waste, hoping to recover oil from waste plastics. Waste plastics contain 60% polyethylene and polypropylene, 5.0% polyvinyl chloride (PVC), 18% impurities, and 17% comprehensive moisture content.

[0073] When using the existing technology to process, the waste plastic garbage 1 first melts or directly enters the main reactor 5 without melting. After condensation, 54% of oil and water (including 12% of water and 42% of anhydrous oil), 19% of gas, and 27% of carbon (residual coke) 6 were obtained. After testing, the calorific value of oil is 39MJ / kg, the calorific value of gas is 26.78MJ / kg, the calorific value of residual coke is 10.3MJ / kg, and the kinematic viscosity of oil is 506mm 2 / s. The oil contains 1.08% chlorine, which has a serious impact on subsequent utilization.

[0074] Implemented by the system and method of the present invention, the waste plastic 1 has a moisture content of 1...

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Abstract

The invention relates to a waste pyrolysis system with adjustable oil, gas and carbon and a method. The system comprises a pre-reaction section, a main reactor, a conditioner and a particle separator. The front of the pre-reaction section is connected to a feeder and the tail of the pre-reaction section is connected to the main reactor. The conditioner is connected after the main reactor. The particle separator is connected after the conditioner. In specific, waste having a water content not more than 60% is fed into the pre-reaction section through the feeder, reacted waste is fed to the main reactor, residue coke generated after the reaction is finished is fed into the conditioner and a generated volatile material is discharged in a forced manner into the conditioner to be contacted, reacted and conditioned with the residue coke at the same time. The conditioner achieves conditioning of the residue coke and the volatile material at the same time. The volatile material after being conditioned is fed into the particle separator to output a clean volatile material. The residue coke after conditioning has a calorific value of 3.37-6.74 MJ / kg, and can be used as building raw materials or is conveyed to a sanitary landfill. The working temperature of the pre-reaction section is 105-298 DEG C and an inert gas or flue gas is fed into the pre-reaction section. The working temperature of the main reactor is 450-650 DEG C. The working temperature of the conditioner is 700-900 DEG C. The system and the method can obtain oil with better quality and more combustible gases and are adapt to changes of the water content of the waste.

Description

Technical field [0001] The invention is the field of waste resource treatment.Specifically, the present invention involves a system and method of heat solution of oil, gas, and charcoal adjustable waste. Background technique [0002] At present, there are more and more urban and rural waste in my country.The existing techniques for handling garbage include incineration, landfilling and composting, and anaerobic fermentation methods. Among them, only the incineration method can maximize the reduction of tolerance.However, due to the potential secondary pollution caused by incineration caused strong opposition from the public, it is difficult for incineration projects to build.Other thermal treatment techniques include gasification and thermal solution. They have obvious reducing effects (70%~ 80%) similar to incineration, but the gas thermal value produced by gasification is low, and the purification requirements are high.There are few cases, usually the gas is directly burned to ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10J3/00C10G1/00C02F11/10B09B3/00C10B53/00
CPCY02P20/52Y02W10/40
Inventor 陈德珍王娜张旭王中慧
Owner 上海济德能源环保技术有限公司
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