Polypropylene material and preparation method thereof
A technology of polypropylene material and polypropylene resin, which is applied in the field of polypropylene material and its preparation, and can solve problems such as degradation of light aging resistance
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[0036] The present invention also provides a preparation method for the above-mentioned polypropylene material, comprising the following steps: mixing 100 parts by weight of polypropylene resin, 30-80 parts by weight of toughening agent, 2-4 parts by weight of vinyl polyfunctional monomer, 1.5 ~2.5 parts by weight of the hindered amine compound with the structure of formula (I) and 0.15~0.25 parts by weight of antioxidant are uniformly mixed, added to a twin-screw extruder for blending and granulation, and the extrusion temperature is 180 ° C ~ 200 ° C, preferably 190°C~200°C, polypropylene material is obtained after irradiation.
[0037] According to the present invention, the masterbatch obtained by extrusion granulation is preferably dried to a moisture content of less than 1.5‰, and then irradiated. The radiation source for the irradiation is a radiation source well known to those skilled in the art, preferably a Co-60 source. The irradiation dose rate of the irradiation ...
Embodiment 2
[0069] Under the condition of nitrogen protection, mix and stir 0.2 mol of GW-944 obtained in 1.2, 0.4 mol of di-tert-butyl dicarbonate, 0.18 mol of potassium carbonate and 120 ml of dichloromethane. After 4 hours of reaction, add 0.3 mol of allyl bromide , Continue to react for 10h. Add dilute hydrochloric acid to adjust the pH value of the reaction solution to 5.0, remove the solvent under reduced pressure, extract with ether, anhydrous Na 2 SO 4 After drying and purification by n-hexane / ethyl acetate column chromatography, the hindered amine compound with the structure of formula (I) was obtained, and its average relative molecular mass was 2960.
[0070] The hindered amine compounds of the formula (I) structure obtained in Example 2 were analyzed by nuclear magnetic resonance to obtain their hydrogen spectrum and carbon spectrum. The results are as follows:
[0071] 1 HNMR (CDCl 3 ,ppm): 5.87(-C=CH), 5.19(-C=CH), 3.73(-CH 2 ), 3.49 (-CH 2 ),2.63(-CH),2.44(-CH),2.26(-...
Embodiment 3
[0074]Dry 1000g polypropylene, 300g POE, 30g TMPTA, 15g of hindered amine compound of formula (I) structure obtained in Example 2 and 1.5g of 3,5-di-tert-butyl-4-hydroxybenzyl phosphoric acid di Ethyl ester is mixed evenly, added to the twin-screw extruder for blending and granulation, the extrusion temperature is 180°C~200°C, the head temperature is 190°C, the extruded material is cooled by running water and pelletized to obtain the masterbatch; masterbatch After the material is dried to a moisture content of less than 1.5‰, it is irradiated with a Co-60 source in a vacuum at a dose rate of 1000 rad / min, and the total absorbed dose is 5 kGy to obtain a polypropylene material.
[0075] According to GB / T 2546, the tensile strength, flexural modulus, impact strength, Vicat softening temperature and gel content of the polypropylene material obtained in Example 3 were tested, and the test results obtained are shown in Table 1.
[0076] Utilize the accelerated aging of ultraviolet ...
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