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Soft magnetic composite with glass xerogel serving as coating layer and method for preparing soft magnetic composite

A technology of soft magnetic composite materials and xerogels, applied in the direction of magnetism of inorganic materials, can solve problems such as low temperature resistance, serious environmental pollution, and insufficient insulation of the cladding layer, so as to improve magnetic properties and eliminate internal The effect of stress

Active Publication Date: 2014-11-12
HARBIN INST OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For the existing organic-coated soft magnetic composite materials, a pressure greater than 800 MPa needs to be applied during its preparation to achieve the required compaction density, but at the same time it must satisfy good saturation magnetic induction and magnetic permeability. rate, it is necessary to anneal the soft magnetic composite material containing the organic coating layer to remove the residual stress of the material, because the organic coating layer is usually not resistant to high temperature, so it is difficult to effectively remove the residual stress
For the soft magnetic composite material of the existing inorganic cladding layer, the insulation of the cladding layer cannot meet the requirements, and the existing cladding layer containing P or S is serious to the environmental pollution, so the use of SiO 2 , MgO, SiO 2 Mixture with water, Al 2 o 3 mixed with water, ZrO 2 The inorganic insulating layer prepared by mixing with water, mica powder and water is used as the inorganic coating layer, and the inorganic insulating layer is generally stable at high temperature, which overcomes the disadvantage that the organic coating layer is usually not resistant to high temperature
However, the existing inorganic insulating layer also has disadvantages. The thermal expansion coefficient of the inorganic insulating layer and the magnetic powder differ greatly, and the thermal expansion coefficient of the inorganic insulating layer itself cannot be changed. In an environment with a large temperature difference or during long-term use, the magnetic powder will Thermal stress is generated inside, which leads to the failure of the soft magnetic composite material coated with inorganic materials to have excellent magnetic properties.
These problems restrict the development and application of soft magnetic composite materials.

Method used

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  • Soft magnetic composite with glass xerogel serving as coating layer and method for preparing soft magnetic composite
  • Soft magnetic composite with glass xerogel serving as coating layer and method for preparing soft magnetic composite
  • Soft magnetic composite with glass xerogel serving as coating layer and method for preparing soft magnetic composite

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specific Embodiment approach 1

[0030] Embodiment 1: A soft magnetic composite material coated with glass xerogel provided in this embodiment is composed of magnetic powder, a silicon dioxide layer coated with magnetic powder, and a glass dry gel coated outside the silicon dioxide layer. The composition of the gel layer; wherein, the magnetic powder is one or a combination of magnetic metal powder, magnetic metal alloy powder and magnetic metal compound powder.

[0031] The present embodiment provides a soft magnetic composite material coated with glass xerogel, which can adjust the composition and ratio of the glass xerogel layer according to the coefficient of thermal expansion. The thermal expansion coefficients of the two substances in one material do not match, and internal stress is easily generated inside the material when the temperature changes, which in turn reduces the magnetic properties of the soft magnetic composite material. Therefore, in the selection of the cladding layer, the thermal expans...

specific Embodiment approach 2

[0034] Specific embodiment two: the difference between this embodiment and specific embodiment one is: the magnetic powder is Fe powder, Ni powder, Co powder, iron alloy powder, nickel alloy powder, cobalt alloy powder, iron-containing oxide powder, nickel-containing oxide One or a combination of powders and cobalt oxide powders are magnetic. Others are the same as in the first embodiment.

[0035] The iron alloy powder described in this embodiment is an alloy powder composed of iron element and one or more elements, and the mass fraction of iron is the largest, wherein the iron alloy powder can be Fe-Si-Al powder, Fe-Ni-Mo powder, Fe-Ni powder, Fe-Cu-Nb-Si-B powder, Fe-Pt powder, Fe-Ni-Cr powder, Fe-Zn powder, La-Co-Fe powder, Pb-Fe powder, W-Ni-Fe powder Powder and Zr-Ni-Sn-Fe powder or a combination of several of them.

[0036] The nickel alloy powder described in this embodiment is an alloy powder composed of nickel element and one or more elements, and the mass fraction...

specific Embodiment approach 3

[0038] Specific Embodiment Three: The preparation method of a soft magnetic composite material with glass xerogel as the coating provided in this embodiment is specifically completed according to the following steps:

[0039] 1. Put the magnetic powder into the cleaning agent and ultrasonicate at a frequency of 24KHz to 35KHz for 10min to 20min, filter to obtain clean magnetic powder, add ethanol and oleic acid to the clean magnetic powder, and use ammonia water with a concentration of 20% to 30% by mass to dissolve the solution Adjust the pH value to 8.5-9.5, ultrasonically disperse at a frequency of 24KHz-35KHz for 1-2 hours or stir at a speed of 600r / min-1200r / min for 1-2 hours to obtain a solid-liquid mixture;

[0040] Among them, the mass ratio of oleic acid and magnetic powder is (0.03-0.2): 1, the volume ratio of oleic acid and ethanol is 1: (40-75), and the magnetic powder is magnetic metal powder, magnetic metal alloy powder and One or a combination of several magneti...

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Abstract

The invention relates to a soft magnetic material and a method for preparing the same, in particular to a soft magnetic composite with glass xerogel serving as a coating layer and a method for preparing the soft magnetic composite. The soft magnetic composite with glass xerogel serving as the coating layer and the method for preparing the soft magnetic composite solve the problems that coefficients of thermal expansion of an inorganic insulating layer and magnetic powder are large in difference and the intrinsic coefficient of thermal expansion of the inorganic insulating layer is unchangeable. The soft magnetic composite with glass xerogel serving as the coating layer is composed of the magnetic powder, a silicon dioxide layer coating the magnetic powder and a glass xerogel layer coating the silicon dioxide layer. The preparation method includes: firstly, preprocessing the magnetic powder; secondly, coating the silicon dioxide layer on the surface of the magnetic powder; thirdly, preparing the glass xerogel; fourthly, coating the glass xerogel layer outside the silicon dioxide layer; fifthly, preparing blanks of the soft magnetic material; and sixthly, preparing the soft magnetic material. The soft magnetic composite with glass xerogel serving as the coating layer and the method for preparing the soft magnetic composite are applicable to the field of switch magnetic resistors, resonance inductors, anti-lock brake sensors, electromagnetic driving devices, brushless direct-current motors, rotary machinery and low-frequency filters.

Description

technical field [0001] The invention relates to a preparation method of a soft magnetic material. Background technique [0002] Soft magnetic composite material refers to a type of soft magnetic material in which magnetic powders are independent of each other and connected by insulating layer materials. The outstanding advantages of this soft magnetic composite material are low iron loss and three-dimensional isotropic properties under AC magnetic field. Therefore, many components that are difficult to realize with conventional soft magnetic materials can be prepared, and have been used in switched reluctance, resonant inductors, anti-lock brake sensors, electromagnetic drives, brushless DC motors, rotating machinery, low-frequency filters and other fields. The preparation process of soft magnetic composite materials is usually to coat the surface of metal or alloy magnetic powder with an insulating layer of inorganic and organic matter, or to form a composite soft magnetic...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01F1/20H01F1/24B22F1/02
Inventor 武高辉丁伟姜龙涛
Owner HARBIN INST OF TECH
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