Soft magnetic composite with glass xerogel serving as coating layer and method for preparing soft magnetic composite
A technology of soft magnetic composite materials and xerogels, applied in the direction of magnetism of inorganic materials, can solve problems such as low temperature resistance, serious environmental pollution, and insufficient insulation of the cladding layer, so as to improve magnetic properties and eliminate internal The effect of stress
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specific Embodiment approach 1
[0030] Embodiment 1: A soft magnetic composite material coated with glass xerogel provided in this embodiment is composed of magnetic powder, a silicon dioxide layer coated with magnetic powder, and a glass dry gel coated outside the silicon dioxide layer. The composition of the gel layer; wherein, the magnetic powder is one or a combination of magnetic metal powder, magnetic metal alloy powder and magnetic metal compound powder.
[0031] The present embodiment provides a soft magnetic composite material coated with glass xerogel, which can adjust the composition and ratio of the glass xerogel layer according to the coefficient of thermal expansion. The thermal expansion coefficients of the two substances in one material do not match, and internal stress is easily generated inside the material when the temperature changes, which in turn reduces the magnetic properties of the soft magnetic composite material. Therefore, in the selection of the cladding layer, the thermal expans...
specific Embodiment approach 2
[0034] Specific embodiment two: the difference between this embodiment and specific embodiment one is: the magnetic powder is Fe powder, Ni powder, Co powder, iron alloy powder, nickel alloy powder, cobalt alloy powder, iron-containing oxide powder, nickel-containing oxide One or a combination of powders and cobalt oxide powders are magnetic. Others are the same as in the first embodiment.
[0035] The iron alloy powder described in this embodiment is an alloy powder composed of iron element and one or more elements, and the mass fraction of iron is the largest, wherein the iron alloy powder can be Fe-Si-Al powder, Fe-Ni-Mo powder, Fe-Ni powder, Fe-Cu-Nb-Si-B powder, Fe-Pt powder, Fe-Ni-Cr powder, Fe-Zn powder, La-Co-Fe powder, Pb-Fe powder, W-Ni-Fe powder Powder and Zr-Ni-Sn-Fe powder or a combination of several of them.
[0036] The nickel alloy powder described in this embodiment is an alloy powder composed of nickel element and one or more elements, and the mass fraction...
specific Embodiment approach 3
[0038] Specific Embodiment Three: The preparation method of a soft magnetic composite material with glass xerogel as the coating provided in this embodiment is specifically completed according to the following steps:
[0039] 1. Put the magnetic powder into the cleaning agent and ultrasonicate at a frequency of 24KHz to 35KHz for 10min to 20min, filter to obtain clean magnetic powder, add ethanol and oleic acid to the clean magnetic powder, and use ammonia water with a concentration of 20% to 30% by mass to dissolve the solution Adjust the pH value to 8.5-9.5, ultrasonically disperse at a frequency of 24KHz-35KHz for 1-2 hours or stir at a speed of 600r / min-1200r / min for 1-2 hours to obtain a solid-liquid mixture;
[0040] Among them, the mass ratio of oleic acid and magnetic powder is (0.03-0.2): 1, the volume ratio of oleic acid and ethanol is 1: (40-75), and the magnetic powder is magnetic metal powder, magnetic metal alloy powder and One or a combination of several magneti...
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