High-performance lithium ion battery and preparation process thereof
A lithium-ion battery, high-performance technology, applied in battery electrodes, secondary batteries, battery pack components, etc., can solve problems such as poor mechanical strength of electrolytes, unreported related technologies, and easy loss of protective functions, to prevent The effect of short circuit of lithium ion electrodes, ensuring safety performance, and excellent lithium ion mobility
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Embodiment 1
[0027] Add 8 g of lithium nickelate to 2 L of graphene aqueous solution with a concentration of 0.1 g / L, and perform emulsification treatment at 10° C. for 2 h to obtain an aqueous dispersion of electrode materials composited with graphene. Then, add 8 g of aniline and 400 g of polystyrenesulfonic acid to the obtained aqueous dispersion, stir evenly, and slowly drop 85.7 mL of ammonium persulfate aqueous solution with a concentration of 280 g / L at a reaction temperature of 50° C., keep stirring, and react for 1 h Afterwards, it was suction filtered and washed until the filtrate was colorless, and the filter cake was dried at 60° C. and crushed to obtain the positive electrode material. Replace the lithium nickelate with natural graphite, and repeat the above steps to obtain the negative electrode material.
[0028] Lithium tetrafluoroborate and propylene carbonate were formulated into a liquid electrolyte with a conductive salt concentration of 20 g / L. Adding nano silicon oxi...
Embodiment 2
[0033] Add 8 g of lithium manganate to 160 mL of graphene oxide aqueous dispersion with a concentration of 10 g / L, and perform ultrasonic treatment at 80° C. for 24 hours to obtain an aqueous dispersion of electrode materials composited with graphene oxide. Then add 2.4g aniline, 0.4g concentrated hydrochloric acid and 9.8g p-toluenesulfonic acid respectively in the obtained aqueous dispersion liquid, stir well, slowly drip into 20mL concentration be the ammonium persulfate aqueous solution of 180g / L at reaction temperature at 0 ℃, Stir continuously, after reacting for 24 hours, filter with suction and wash until the filtrate is colorless, dry the filter cake at 100°C, and pulverize to obtain the positive electrode material. Lithium manganate was replaced by MCMB, and the above operation steps were repeated to obtain the negative electrode material.
[0034] Lithium bisoxalate borate and propylene carbonate were formulated into a liquid electrolyte with a conductive salt conce...
Embodiment 3
[0039] Add 8 g of lithium cobaltate to 500 mL of graphene aqueous solution with a concentration of 1.5 g / L, and perform emulsification treatment at 25 ° C for 2 h, and then ultrasonic treatment for 2 h to obtain an aqueous dispersion of electrode materials composited with graphene. Then add 2.4g aniline and 5g sulfosalicylic acid respectively in the obtained aqueous dispersion liquid, stir well, slowly drop into 25.8mL concentration be the ammonium persulfate aqueous solution of 228g / L under reaction temperature 20 ℃, constantly stir, react After 4 hours, it was filtered with suction and washed until the filtrate was colorless. The filter cake was dried at 80° C. and crushed to obtain the positive electrode material. Replace the lithium cobaltate with carbon nanotubes, repeat the above operation steps, and obtain the negative electrode material.
[0040] Lithium hexafluorophosphate, dimethyl carbonate, diethyl carbonate, and ethylene carbonate were formulated into a liquid ele...
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