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Temporary plugging diversion agent for refracturing of oil-water well and preparation method thereof

A technology of repeated fracturing and diverting agent, applied in chemical instruments and methods, drilling compositions, etc., can solve the problems of long time for unblocking, poor fluid solubility, increased construction risk, etc., to reduce formation blockage damage, Low water-insoluble matter content and the effect of improving the dissolution effect

Active Publication Date: 2013-07-10
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] (1) There are several types of plugging balls, such as plastic balls, rubber balls, and nylon balls, which have high plugging strength and small deformation; but their disadvantages are that they are easy to fall off and the plugging effect is poor. Especially because it cannot be dissolved, it is difficult to remove the blockage, which increases the risk of construction.
[0007] (2) The wax ball is mainly a mixture of paraffin, high-pressure polyethylene, barite and other components, which is characterized by small particle size and can enter perforation holes and even near wellbore areas; however, its breakthrough pressure is low, easy to deform, and has good plugging effect Poor, resulting in a large amount of use, and because most components have poor solubility with formation fluids, it takes a long time to unblock and poor applicability
However, the temporary plugging agents involved in these two patents have many shortcomings in terms of solubility and residue content, which restrict their popularization and application. The shortcomings are:
[0009] 1. Basically insoluble in oil, if the formation fluid contains more oil but less water or the fracturing fluid reduces the gel breaking fluid due to large fluid loss, the insoluble part of the temporary plugging agent will cause new blockage to the formation and seriously weaken the repeated fracturing Due to the fracture stimulation effect, the formation fluid and fracturing fluid filtration loss must be re-evaluated in the preparation of the construction plan, which increases the difficulty of the plan design;
[0010] 2. High residue content. Since the vegetable gum used is kale powder or hydroxymethyl starch or guar gum, compared with hydroxypropyl guar gum, a common thickener for fracturing fluids, the residue content is 50%-300% higher , will bring greater residue damage to the formation;

Method used

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  • Temporary plugging diversion agent for refracturing of oil-water well and preparation method thereof

Examples

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Effect test

Embodiment 1

[0047] This embodiment provides a temporary plugging and diverting agent for repeated fracturing of oil and water wells, which is prepared by the following method:

[0048] (1), 3g carboxymethyl hydroxypropyl guar gum is dissolved in 100mL water and is prepared to obtain carboxymethyl hydroxypropyl guar gum aqueous solution;

[0049] (2), get 45g of bone glue and soak in the carboxymethyl hydroxypropyl guar gum aqueous solution prepared in step (1), and keep it at a constant temperature in a water bath at 30°C for 4 hours;

[0050] (3) After the bone glue swells completely, raise the temperature of the water bath to 50°C and keep it at a constant temperature for 1 hour;

[0051] (4) After the bone glue is completely dissolved, quickly add 13g of white oil and stir evenly;

[0052] (5), then, add 23g sulfonated pitch while stirring, form viscous liquid;

[0053] (6), add the carboxymethyl hydroxypropyl guar gum of 11g in viscous liquid while stirring, form viscous paste;

[...

Embodiment 2

[0064] This embodiment provides a temporary plugging and diverting agent for repeated fracturing of oil and water wells, which is prepared by the following method:

[0065] (1), 3g hydroxypropyl guar gum is dissolved in 100mL water, prepares the aqueous solution of hydroxypropyl guar gum;

[0066] (2), get 40.5g of bone glue and soak in the hydroxypropyl guar gum aqueous solution prepared in step (1), and keep it in a water bath at 30°C for 4 hours at a constant temperature;

[0067] (3) When the bone glue is completely swollen, raise the temperature of the water bath to 50°C and keep it at a constant temperature for 1 hour;

[0068] (4), when the bone glue is completely dissolved, quickly add 19g of white oil and stir evenly;

[0069] (5), then, add 24g sulfonated pitch while stirring, form viscous liquid;

[0070] (6), add the hydroxypropyl guar gum of 11.5g while stirring, form viscous paste;

[0071] (7) Lay the viscous paste on a horizontal surface to form a sheet with...

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Abstract

The invention relates to a temporary plugging diversion agent for refracturing of an oil-water well and a preparation method thereof. The temporary plugging diversion agent comprises the following raw materials: adhesive bonding agent 35-65%, plasticizer 15-25%, thickening agent 10-20%, and dispersant 10-20% calculated by the total weight of the temporary plugging diversion agent. The invention also provides the preparation method of the temporary plugging diversion agent, which comprises the following steps: preparing partial thickening agent into a thickening agent water solution; dissolving the adhesive bonding agent into the thickening agent water solution; holding constant temperature in a 25-35 DEG C water bath for 2-5 hours, and after the adhesive bonding agent is swollen completely, increasing the temperature to 45-55 DEG, and continuing holding constant temperature for 0.5-2 hours; after the adhesive bonding agent is completely dissolved, adding dispersant and stirring to be homogenous, and adding the plasticizer and the rest thickening agent while stirring to obtain viscous paste; and cutting the viscous paste to granules of side length 3-6 mm, and drying to obtain the temporary plugging diversion agent. The temporary plugging diversion agent provided by the invention has the advantages of good oil solubility and water solubility, low residue content, good elasticity, and on the like.

Description

technical field [0001] The invention relates to a diverting agent for oil well water plugging and a preparation method thereof, in particular to a temporary plugging diverting agent for repeated fracturing of oil-water wells and a preparation method thereof, belonging to the field of chemical products for oil and gas field development. Background technique [0002] Refracturing, as a technical measure for the comprehensive management of old oil and water wells (oil wells and water injection wells), is a major problem that oilfields face urgently to be solved. According to research and experiments at home and abroad, appropriate refracturing for such old wells can continue to achieve a relatively large increase in production or injection. [0003] Extending the original fractures was a common concept of refracturing before. However, this kind of refracturing has a short production stabilization period after fracturing and unsatisfactory production stimulation effects. The in...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K8/514
Inventor 刘伟刘建权张子明包放关伟
Owner PETROCHINA CO LTD
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