Toner, developer, and image forming method
一种调色剂、单色图像的技术,应用在调色剂领域,能够解决调色剂粘附量大等问题,达到高质量图像、防止锐度、高分辨率的效果
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Embodiment 1
[0311]
[0312] -Preparation of Fine Particle Dispersion 1-
[0313] In a reaction vessel equipped with a stirrer and a thermometer, 683 parts by mass of water, 11 parts by mass of sodium salt of methacrylate ethylene oxide adduct sulfate (ELEMINOL RS-30, manufactured by Sanyo Chemical Industries Ltd.), 83 parts by mass of styrene, 83 parts by mass of methacrylic acid, 110 parts by mass of butyl acrylate, and 1 part by mass of ammonium persulfate were stirred at 400 rpm (revolutions per minute) for 15 minutes to produce a white emulsion. The emulsion was heated and the temperature was raised to a system temperature of 75°C, and the reaction was carried out for 5 hours. Next, 30 parts by mass of a 1 mass % ammonium persulfate aqueous solution was added. The mixture was aged at 75°C for 5 hours to produce an aqueous dispersion of vinyl resin (copolymer of styrene-methacrylic acid-butyl acrylate-methacrylic acid ethylene oxide adduct sodium salt of sulfate) body [fine particl...
Embodiment 2
[0341]
[0342] Toner 2 was prepared in the same manner as in Example 1 except that the procedure for preparing the masterbatch was changed as follows.
[0343] -Preparation of masterbatch-
[0344] 1200 parts by mass of water, 405 parts by mass of C.I.PR269 (1022M, manufactured by DIC Corporation) as a colorant, 81 parts by mass of a polyurethane pigment dispersant (EFKA4080, manufactured by Chiba Specialty Chemicals, Inc.), and 1200 parts by mass of polyester resin The mixture of (1) was mixed with HENSCHELMIXER (manufactured by Mitsui Mining Co., Ltd.). After the mixture was kneaded at 150° C. for 30 minutes with a two-roll mill, the mixture was cold-rolled and pulverized in a pulverizer (manufactured by Hosokawa Micron Corporation) to prepare a masterbatch.
Embodiment 3
[0346]
[0347] Toner 3 was prepared in the same manner as in Example 1 except that the procedure for preparing the masterbatch was changed as follows.
[0348] -Preparation of masterbatch-
[0349] With 1200 parts by mass of water, 540 parts by mass of C.I.PY155 (YELLOW4G-PT VP2669, manufactured by Clariant (Japan) K.K.) as a colorant, 108 parts by mass of polyester pigment dispersant (AJISPER821, Ajinomoto Fine-Techno Co., Inc.), 16 parts by mass of builder (EFKA6750, manufactured by Chiba Specialty Chemicals, Inc.), and 1200 parts by mass of polyester resin (1) were mixed with HENSCHEL MIXER (manufactured by Mitsui Mining Co., Ltd.). After the mixture was kneaded at 150° C. for 30 minutes with a two-roll mill, the mixture was cold-rolled and pulverized in a pulverizer (manufactured by Hosokawa Micron Corporation) to prepare a masterbatch.
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