Amphoteric water soluble color-fixing agent and its application
A color-fixing agent and water-soluble technology, applied in the field of amphoteric water-soluble color-fixing agents, can solve the problems of small molecules of the color-fixing agent, inability to improve wet rubbing fastness, and poor film-forming properties, so as to improve the color fastness. degree of effect
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Embodiment 1
[0028] The synthetic example of embodiment 1 polymer:
[0029]① Synthesis of amphoteric polyacrylamide water-soluble polymers: a. Polymerization: acrylic acid (need to be refined) and acrylamide monomers are mixed into an aqueous solution according to the molar ratio of (10-40): (60-90), and the concentration of the monomer aqueous solution Control it at 5-15%, and then pass nitrogen into it for 10-30 minutes, and add ammonium persulfate-sodium bisulfite redox initiator under the protection of nitrogen, the amount of which is 0.001- 0.008 mole fraction, temperature between 60℃~80℃, copolymerization reaction for 3h~5h, to obtain anionic high polymer. b. Modification: at pH=7-9, the temperature is between 50°C and 70°C, preferably 65°C, the copolymer is subjected to Mannich reaction with formaldehyde and diethylamine hydrochloride, and modified for 2h to 4h, the aqueous solution of the amphoteric color-fixing agent can be obtained.
[0030] ②Use itaconic acid...
Embodiment 2
[0034] Embodiment 2 carries out performance test to the fabric after finishing.
[0035] ① Taking amphoteric polyacrylamide water-soluble polymer as an example, the effect after finishing is compared with the effect of fixing agent Y as follows:
[0036]
Experimental sample
Original cloth
amphoteric color fixing agent
Fixing agent Y
Direct Rosé 12B
Direct Big Red 4BS
Direct Rosé 12B
Direct Big Red 4BS
Direct Rosé 12B
Direct Big Red 4BS
Dry rubbing fastness
3-4
4-5
5
5
5
5
Wet rub fastness
2-3
2
5
4
4
2-3
Soaping fastness
2
1
4
2-3
4
3
faded
2
2-3
4
4
4
4
Perspiration fastness
sour
3
2-3
4
3
5
3
alkali
3
3 ...
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