Cleaning method for semiconductor material
A semiconductor and post-cleaning technology, used in semiconductor/solid-state device manufacturing, chemical instruments and methods, detergent compositions, etc., which can solve the problem of fast ineffectiveness of solution cleaning ability, environmentally unfriendly chemical reagents, and increasing the surface roughness of silicon wafers. and other problems, to achieve the effect of effectively removing metal ions, reducing environmental pollution and promoting saponification reaction
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Embodiment 1
[0043] Alkaline degreasing lotion for silicon, quartz, ceramic semiconductor materials:
[0044] Potassium Hydroxide 3%, Potassium Carbonate 3.6%, Dipotassium Dihydrogen Pyrophosphate 2.1%, Potassium Tripolyphosphate 2%, Acetone Glycerol 4.5%, Sodium Dodecyl Diphenyl Ether Disulfonate 1.8%, H-662.5 % (Dow Chemical TRITON H-66), fatty amine polyoxyethylene ether 2%, and the balance is water; all percentages are calculated by mass volume percentage, and the following are the same. Immerse several samples of silicon products (etched quartz wafers, silicon wafers, polished silicon wafers, silicon processing surfaces, quartz processing surfaces, respectively P-type monocrystalline silicon, polycrystalline silicon, etc.) into the above-mentioned alkaline degreasing lotion, and use Ultrasonic immersion cleaning, the temperature is controlled at 35-50°C, and the cleaning is about 15-20 minutes. After cleaning, rinse with deionized water. After cleaning, there is no grease residue fro...
Embodiment 2
[0048] Alkaline degreasing lotion for silicon, quartz, ceramic semiconductor materials:
[0049] Potassium hydroxide 3%, potassium carbonate 4%, dipotassium dihydrogen pyrophosphate 3%, potassium tripolyphosphate 2.8%, acetonide 5.2%, sodium dodecyl diphenyl ether disulfonate 1.6%, H-662 %, aliphatic amine polyoxyethylene ether 1.6%, and the balance is deionized water; several silicon product samples (same as Example 1) are immersed in the above-mentioned alkaline degreasing lotion, soaked and cleaned with ultrasonic waves, and the temperature is controlled at 35-50°C , Clean for about 15-20 minutes, rinse with deionized water after cleaning.
[0050] The sample after embodiment 1 and embodiment 2 degreasing treatment is detected, figure 1 It is the appearance picture of two silicon wafer samples before and after degreasing and cleaning, and the third row is the comparison picture of cleaning under the same conditions of a certain degreasing liquid on the market. It can be se...
Embodiment 3
[0053] Metal ion cleaning solution suitable for silicon, quartz, and ceramic semiconductor materials, including acidic A cleaning solution, neutral cleaning solution, and acidic B cleaning solution, which can treat the metal elements on the surface of the sample, and the metal elements include 30 elements required by the semiconductor industry Metal elements, specifically Al, Sb, As, Ba, Be, Bi, B, Cd, Ca, Cr, Co, Cu, Ga, Ge, Fe, Pb, Li, Mg, Mn, Mo, Ni, K, Na , Sr, Sn, Ti, W, V, Zn, Zr.
[0054] The sample is first soaked and cleaned with acid A lotion at room temperature. The cleaning time is about 15-20 minutes. After cleaning, it is rinsed with deionized water; Wash for about 15-20 minutes, rinse with deionized water after cleaning; finally soak in acid B lotion for cleaning, keep the temperature at room temperature, wash for about 15-20 minutes, rinse with deionized water after cleaning. Among them, the acid A lotion is: ammonium fluoride 3.9%, fluosilicic acid 2%, H-951....
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