Waterproof concrete synergist and preparation method thereof
A concrete synergist and waterproof technology, which is applied in the field of concrete admixtures, can solve the problems of no obvious improvement in the strength of concrete in the later stage, a decrease in the value of concrete compressive strength, and an increase in the number of pores in concrete, so as to improve slump and ease of use, improved compactness, and low-cost preparation
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Embodiment 1
[0041] A preparation method of waterproof concrete synergist is realized through the following steps:
[0042] (1) Based on the percentage of the total weight of raw materials, weigh the following raw materials: polyaminated cellulose microspheres 13%, polymethyltriethoxysilane 11%, 4-methyl-1,3-phenylene 7% diisocyanate, 10% trimethylolpropane, 7% polyvinyl alcohol, 5% sodium pyrophosphate, 3% polyaluminum ferric sulfate, and the balance is water.
[0043] (2) Preparation of modified water-based polyurethane: Add organic solvent DMF and polymethyltriethoxysilane into a three-port device tank equipped with a stirrer, thermometer, and constant pressure dropping funnel, and add 4- Methyl-1,3-phenylene diisocyanate and trimethylolpropane, then slowly raise the temperature and add a certain amount of 18% NaOH solution drop by drop, when the temperature rises to 95 ° C, keep the reaction for 5 hours, so that the system has a A series of hydrolysis, block reaction. After the react...
Embodiment 2
[0048] A preparation method of waterproof concrete synergist is realized through the following steps:
[0049] (1) According to the percentage of the total weight of raw materials, weigh the following raw materials: polyaminated cellulose microspheres 16%, polymethyltriethoxysilane 9%, 2-methyl-1,3-phenylene 4% diisocyanate, 12% neopentyl glycine, 8% polyacryl alcohol, 6% sodium tripolyphosphate, 4% polyaluminum ferric sulfate, and the balance is water;
[0050] (2) Preparation of modified water-based polyurethane: Add organic solvent DMF and polymethyltriethoxysilane into a three-port device tank equipped with a stirrer, thermometer, and constant pressure dropping funnel, and add 2- Methyl-1,3-phenylene diisocyanate and neopentylglycine, then slowly increase the temperature and add a certain amount of 18% NaOH solution dropwise, when the temperature rises to 95 ° C, keep the reaction for 5 hours, so that the system undergoes a series of Hydrolysis, block reaction. After the...
Embodiment 3
[0055] A preparation method of waterproof concrete synergist is realized through the following steps:
[0056] (1) According to the percentage of the total weight of raw materials, weigh the following raw materials: polyaminated cellulose microspheres 12%, polymethyltriethoxysilane 6%, 4,4'-diphenylmethane diisocyanate 9%, cyclohexanetriol 7%, polyethylene glycol 10%, maltodextrin 4%, polyaluminum ferric sulfate 4%, the balance is water;
[0057] (2) Preparation of modified water-based polyurethane: Add organic solvent DMF and polymethyltriethoxysilane into a three-port device tank equipped with a stirrer, thermometer, and constant pressure dropping funnel, and add 4, 4'-diphenylmethane diisocyanate and cyclohexanetriol, then slowly raise the temperature and add a certain amount of 18% NaOH solution drop by drop, when the temperature rises to 95 ° C, keep it warm for 5 hours, so that the system undergoes a series of hydrolysis, block reaction. After the reaction was complete...
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