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Efficient integrated water purification equipment polymer and CNTs composite filter material for sewage treatment and preparation method of material

A polymer material, composite filtration technology, applied in water/sewage treatment, water/sludge/sewage treatment, single-component synthetic polymer rayon, etc., can solve the problem that the reverse osmosis treatment unit cannot operate normally, abnormal mechanics, Electrical and magnetic properties, dealing with the limitation of pollutant types, etc., to achieve the effects of various bonding methods, long service life and small footprint

Inactive Publication Date: 2021-02-05
鄂尔多斯市清科紫荆技术开发有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the advanced treatment of sewage often requires ultra- and microfiltration membrane technology, but the investment cost of this technology is relatively high
For reclaimed water reuse and "zero discharge" treatment, it is necessary to protect the membrane system to reduce fouling of membrane materials. Sand filter + carbon filter + ultrafiltration pretreatment units are often installed at the front end of nanofiltration and reverse osmosis. The process is long, the sand filter and carbon filter are easy to harden and difficult to clean, and the ultrafiltration membrane is easy to be fouled, which directly leads to a series of practical problems such as the failure of the subsequent nanofiltration and reverse osmosis treatment units.
[0003] CNTs is the abbreviation of carbon nanotubes (English name Carbon Nanotubes), which can be divided into single-walled carbon nanotubes (SWCNTs) and multi-walled carbon nanotubes (Multi-walled Carbonnanotubes, MWCNTs). The tube formed by curling around the central axis according to a certain helicity has many abnormal mechanical, electrical and magnetic properties, and is widely used in many fields such as nanoelectronic devices, field emission, scanning probe microscopy and chemical sensors. In recent years, although the adsorption, removal, sterilization, and catalytic effects of CNTs materials have certain advantages in the application of environmental treatment, their removal efficiency is not high, and the types of pollutants to be treated are limited; therefore, it is urgent to develop a A composite filter material with high efficiency and wide range of applications

Method used

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  • Efficient integrated water purification equipment polymer and CNTs composite filter material for sewage treatment and preparation method of material
  • Efficient integrated water purification equipment polymer and CNTs composite filter material for sewage treatment and preparation method of material
  • Efficient integrated water purification equipment polymer and CNTs composite filter material for sewage treatment and preparation method of material

Examples

Experimental program
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Effect test

Embodiment 1

[0030] Add the SWCNTs material and MWCNTs material to the mixed acid of concentrated sulfuric acid and concentrated nitric acid with a volume ratio of 3:1 according to the mass ratio of 1:1, ultrasonically oscillate for 2 hours, suck out the mixed acid liquid, add deionized water to dilute, and dry the filtered CNTs 13h. Add 10g of modified CNTs material after oxidation treatment to 8mL N-N dimethylformamide and 220mL thionyl chloride solution, CNTs (g): N-N dimethylformamide (mL): thionyl chloride (mL) =5:4:110, remove the unreacted thionyl chloride after magnetic stirring for 36 hours, then dry the CNTs for 13 hours, add the above CNTs and aliphatic polyester amine into the reaction kettle, pass nitrogen gas to prevent oxidation, and raise the temperature to 250-280 ℃, after 6 hours of polymerization reaction, the composite material is obtained, and finally the fiber filament with a diameter of 5-70um is made by melt spinning. Through the method of fiber filament constructi...

Embodiment 2

[0034]The MWCNTs material was added to a mixed acid of concentrated sulfuric acid and concentrated nitric acid with a volume ratio of 3:1, ultrasonically oscillated for 2 hours, the mixed acid liquid was sucked out, diluted with deionized water, and the filtered CNTs were dried for 13 hours. Add 10 g of oxidized CNTs to 8 mL N-N dimethylformamide and 220 mL thionyl chloride solution, remove unreacted thionyl chloride after magnetic stirring for 36 h, then dry the CNTs for 13 h, and mix the above CNTs with polyvinylidene fluoride Add ethylene into the reaction kettle, pass nitrogen to prevent oxidation, raise the temperature to 250-280°C, and polymerize for 6 hours to obtain composite materials, and finally melt-spin to make fibers with a diameter of 5-70um. Through fiber filament construction, combination and stacking methods, the ratios of polymer materials and modified CNTs materials are 97:3, 97.5:2.5, 98:2, 98.5:1.5, the pore size is 0.1um, and the porosity is 75%, polymer...

Embodiment 3

[0038] The SWCNTs material was added to the mixed acid of concentrated sulfuric acid and concentrated nitric acid with a volume ratio of 3:1, ultrasonically oscillated for 2 hours, the mixed acid liquid was sucked out, diluted with deionized water, and the filtered CNTs were dried for 13 hours. Add 10 g of oxidized CNTs to 8 mL N-N dimethylformamide and 220 mL thionyl chloride solution, remove unreacted thionyl chloride after magnetic stirring for 36 h, then dry the CNTs for 13 h, mix the above CNTs with polyether ketone Put it into the reaction kettle, blow nitrogen to prevent oxidation, raise the temperature to 250-280°C, and after 6 hours of polymerization reaction, the composite material is obtained, and finally the fiber filament with a diameter of 5-70um is made by melt spinning. Through the fiber filament construction, combination and superposition method, the ratio of polymer material and modified CNTs material is 97.5:2.5, the pore diameter is 0.05um, 0.1um, 0.2um, the...

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Abstract

The invention discloses an efficient integrated water purification equipment polymer and CNTs composite filter material for sewage treatment and a preparation method of the material, and belongs to the technical field of advanced sewage treatment. The composite filter material is prepared from fiber yarns prepared from a polymer material and a modified CNTs material, wherein the pore diameter of the composite filter material is 0.03-0.7 [mu]m, the void ratio is 40%-80%, the ratio of the polymer material to the modified CNTs material is 95:5-99.8:0.2, and the diameter of fiber yarns prepared from the polymer material and the modified CNTs material is 5-70 [mu]m. When the composite filter material is used for water treatment, the turbidity and suspended matter removal rate reaches 95% or above, the CODCr, BOD5 and ammonia nitrogen removal rate reaches 28% or above, the fecal coliform count removal rate reaches 20% or above, the filter speed is six times that of sand filtration, the effluent quality is superior to that of a microfiltration membrane, and the composite filter material has antibacterial properties and adsorption properties and has broad market application prospects.

Description

technical field [0001] The invention belongs to the technical field of advanced sewage treatment, and in particular relates to a high-efficiency integrated water purification equipment polymer and CNTs composite filter material for sewage treatment and a preparation method. Background technique [0002] With the growth of urban population and the development of industrial and agricultural production, the amount of sewage discharge is increasing day by day, and the national environmental protection supervision department has increasingly strict standards for sewage discharge. At present, the advanced treatment of sewage often requires ultra- and microfiltration membrane technology, but the investment cost of this technology is relatively high. For reclaimed water reuse and "zero discharge" treatment, it is necessary to protect the membrane system to reduce fouling of membrane materials. Sand filter + carbon filter + ultrafiltration pretreatment units are often installed at th...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D39/02D01F1/10D01F6/94D01F6/48D01F6/90C02F1/00
CPCB01D39/02D01F1/10D01F1/103D01F6/94D01F6/48D01F6/90C02F1/001B01D2239/1216B01D2239/1208B01D2239/10
Inventor 李继定易汉平李洋吴珍董布和孙丽娅
Owner 鄂尔多斯市清科紫荆技术开发有限公司
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